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DG Exit Exam
Answer Key

CHEMCO exit exam questions and answers — Advanced Training for Chemical Tanker Cargo Operations

All 663 questions from the Advanced Training for Chemical Tanker Cargo Operations (CHEMCO) exit exam bank, with the correct option marked and a one-line explanation for every one. Read it end to end, jump to a single set, or search it — then sit the same bank as a timed paper. The real DG Shipping exit exam is 30 marks with 15 to pass.

These are the bank's original groupings. Practising deals the whole bank out again every time you reshuffle, so a practice “Set 3” is a different 30 questions each time — the set numbers below are the source file's, and are only used here so the key stays navigable. Options are listed in their original order with fixed letters; when you practise, those move too.

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Set 1 — 30 CHEMCO exit exam questions with answers

1. Which IMO Code regulates the carriage of dangerous chemicals in bulk on chemical tankers?

  • A. IMSBC Code
  • B. IGC Code
  • C. IBC Code
  • D. IMDG Code
Answer: C — IBC Code
The International Bulk Chemical Code (IBC Code) establishes safety standards for design, equipment, and operation of chemical tankers.

2. Under MARPOL Annex II, which pollution category presents the major hazard to human health or marine resources?

  • A. Category Y
  • B. OS (Other Substances)
  • C. Category Z
  • D. Category X
Answer: D — Category X
Category X substances pose the highest risk; discharge into the sea of Category X tank washings is strictly prohibited.

3. What test is performed on tank bulkhead surfaces to detect microscopic hydrocarbon residues before loading sensitive chemical cargoes?

  • A. Hydrostatic pressure test
  • B. Magnetic particle test
  • C. Ultrasonic thickness test
  • D. Wall Wash Test (WWT)
Answer: D — Wall Wash Test (WWT)
Wall Wash Testing uses solvents (methanol/acetone) to check tank cleanliness parameters such as Permanganate Time, Purity, and Chloride content.

4. What type of chemical tanker skin/tank construction is required for carrying high-hazard cargoes like Isocyanates?

  • A. Type 2 chemical tanker
  • B. Single hull barge
  • C. Type 3 chemical tanker
  • D. Open deck vessel
Answer: A — Type 2 chemical tanker
IBC Code Chapter 17 assigns isocyanates such as TDI and MDI to Ship Type 2: products with significantly severe environmental and safety hazards that need significant preventive measures against escape.

5. What material is widely used for cargo tanks carrying aggressive acids such as Nitric or Phosphoric acid?

  • A. Stainless Steel (e.g. 316L, Duplex 2205)
  • B. Aluminum alloy
  • C. Zinc silicate coating
  • D. Mild carbon steel
Answer: A — Stainless Steel (e.g. 316L, Duplex 2205)
Stainless steel offers superior corrosion resistance and versatility for acid and high-purity chemical cargoes.

6. What is the key limitation of Zinc Silicate tank coatings in chemical tankers?

  • A. Highly flammable surface coating
  • B. Incompatible with acids and strong alkalis (pH limits usually 6 to 10)
  • C. Cannot handle aromatic solvents like Benzene
  • D. Melts at room temperature
Answer: B — Incompatible with acids and strong alkalis (pH limits usually 6 to 10)
Zinc silicate reacts with acidic or strongly alkaline solutions, destroying the coating matrix.

7. What document must be maintained on board detailing all chemical cargo loading, discharging, tank washing, and slop handling?

  • A. Radio Log Book
  • B. Cargo Record Book (CRB)
  • C. Bell Book
  • D. Engine Log Book
Answer: B — Cargo Record Book (CRB)
MARPOL Annex II mandates a Cargo Record Book to log every chemical cargo operation and tank wash discharge.

8. What is self-polymerization in chemical cargoes?

  • A. Dissolving of cargo into seawater
  • B. Freezing of liquid into crystal ice
  • C. Evaporation of cargo into atmosphere
  • D. Chemical reaction where monomer molecules join to form long polymers, generating intense heat
Answer: D — Chemical reaction where monomer molecules join to form long polymers, generating intense heat
Cargoes like Styrene monomer or Vinyl Acetate can spontaneously polymerize, producing dangerous heat and pressure building if uninhibited.

9. What mandatory document provides chemical property, health hazard, reactivity, and emergency response data for a chemical cargo?

  • A. Material Safety Data Sheet (MSDS)
  • B. Tonnage Certificate
  • C. Crew List
  • D. Customs Manifest
Answer: A — Material Safety Data Sheet (MSDS)
MSDS (or SDS) provides vital chemical handling data and first-aid instructions before loading any chemical product.

10. What system is used to purge chemical lines and maintain an inert nitrogen cushion over moisture-sensitive cargoes?

  • A. Steam lance system
  • B. Seawater flushing system
  • C. Nitrogen padding / inerting system
  • D. Compressed air blower
Answer: C — Nitrogen padding / inerting system
Nitrogen padding isolates air/moisture reactive cargoes (like Isocyanates) from atmospheric humidity and oxygen.

11. What is Threshold Limit Value - Time Weighted Average (TLV-TWA)?

  • A. Safe airborne exposure concentration for normal 8-hour workday and 40-hour workweek
  • B. Maximum limit for 1 minute
  • C. Pressure limit
  • D. Temperature limit
Answer: A — Safe airborne exposure concentration for normal 8-hour workday and 40-hour workweek
TLV-TWA defines the safe average exposure concentration over a standard work shift.

12. What chemical cargo reaction occurs when two incompatible cargoes contact each other?

  • A. Sublimation
  • B. Condensation
  • C. Incompatible chemical reactivity producing toxic fumes, heat, or explosion
  • D. Freezing
Answer: C — Incompatible chemical reactivity producing toxic fumes, heat, or explosion
Incompatible cargoes (e.g. Acids and Caustic Soda) react violently if mixed.

13. What is mandatory prior to personnel entering a chemical cargo tank for inspection?

  • A. Washing with seawater
  • B. Verbal permission from cook
  • C. Tank gas-freeing, atmospheric testing for O2 (20.9%), toxic gas (0 ppm), LEL (0%), and Enclosed Space Entry Permit
  • D. Opening main valve
Answer: C — Tank gas-freeing, atmospheric testing for O2 (20.9%), toxic gas (0 ppm), LEL (0%), and Enclosed Space Entry Permit
Rigorous enclosed space entry safety testing is legally required before tank entry.

14. What personal protective equipment is required during chemical cargo sampling of toxic substances?

  • A. Leather apron
  • B. Chemical suit, boots, face shield/goggles, chemical resistant gloves, and organic vapor mask or SCBA
  • C. Short sleeves
  • D. Standard coveralls
Answer: B — Chemical suit, boots, face shield/goggles, chemical resistant gloves, and organic vapor mask or SCBA
Sampling toxic or corrosive chemicals requires full chemical protective equipment.

15. What equipment must be available near chemical cargo manifolds during transfer operations?

  • A. Steam boiler
  • B. Radio receiver
  • C. Paint spray machine
  • D. Emergency safety shower and eye-wash station
Answer: D — Emergency safety shower and eye-wash station
Safety showers and eyewash stations provide immediate decontamination for accidental spills.

16. What is the P&A Manual on a chemical tanker?

  • A. Pump manual
  • B. Procedures and Arrangements Manual approved by Flag State Administration
  • C. Port anchorage guide
  • D. Personnel manual
Answer: B — Procedures and Arrangements Manual approved by Flag State Administration
The P&A Manual details specific procedures for tank washing, stripping, and slop handling under MARPOL Annex II.

17. What device is installed on chemical tank venting systems to prevent over-pressure or vacuum?

  • A. Check valve
  • B. High-velocity Pressure/Vacuum (P/V) valve
  • C. Globe valve
  • D. Needle valve
Answer: B — High-velocity Pressure/Vacuum (P/V) valve
High-velocity P/V valves vent tank vapors high above deck and protect tanks from pressure damage.

18. What cargo stripping result is required for modern Type 2 chemical tankers built after May 2007 carrying Category X, Y, Z cargoes?

  • A. Maximum residue remaining per tank must not exceed 75 liters
  • B. 1000 liters
  • C. 5 cubic meters
  • D. No limit
Answer: A — Maximum residue remaining per tank must not exceed 75 liters
Under MARPOL Annex II, modern chemical tankers must strip residue down to no more than 75 liters per tank.

19. What is the function of a toxic gas detector tube system (e.g. Dräger tube)?

  • A. Test battery
  • B. Measure oil viscosity
  • C. Measure specific chemical vapor concentrations in ppm by colorimetric reaction
  • D. Measure salinity
Answer: C — Measure specific chemical vapor concentrations in ppm by colorimetric reaction
Indicator tubes measure exact parts-per-million concentrations of specific toxic gases.

20. Why are efficient stripping systems essential on chemical tankers?

  • A. Increase ship speed
  • B. Minimize cargo residue left in tanks prior to mandatory pre-wash or commercial cleaning
  • C. Cool engine room
  • D. Fill ballast tanks
Answer: B — Minimize cargo residue left in tanks prior to mandatory pre-wash or commercial cleaning
Thorough stripping maximizes cargo delivery and minimizes slop washing quantities.

21. What is the purpose of a mandatory pre-wash under MARPOL Annex II?

  • A. Clean windows
  • B. Polish steel
  • C. Remove high-viscosity or solidifying Category X / Y residues to shore reception
  • D. Wash deck
Answer: C — Remove high-viscosity or solidifying Category X / Y residues to shore reception
Mandatory pre-washes transfer persistent chemical slops to shore reception facilities before departure.

22. What is the Permanganate Time Test used for in chemical tank cleaning?

  • A. Test oxygen concentration
  • B. Test fuel sulfur
  • C. Test water temp
  • D. Detect trace presence of oxidizable organic impurities after cleaning for high-purity alcohol cargoes
Answer: D — Detect trace presence of oxidizable organic impurities after cleaning for high-purity alcohol cargoes
Permanganate time measures how long potassium permanganate retains its pink color in wall wash samples.

23. What code specifies medical emergency response steps for chemical accidents on ships?

  • A. SOLAS Chapter V
  • B. STCW Reg I/9
  • C. MARPOL Annex VI
  • D. Medical First Aid Guide (MFAG)
Answer: D — Medical First Aid Guide (MFAG)
MFAG provides standardized medical response guidelines for chemical spills and exposures.

24. What type of cargo pump is fitted inside individual stainless steel chemical cargo tanks?

  • A. Deepwell centrifugal pump
  • B. Steam duplex pump
  • C. Hand pump
  • D. Gear pump
Answer: A — Deepwell centrifugal pump
Deepwell pumps eliminate cargo pump rooms and isolate individual cargo parcels.

25. Why is water prohibited for cleaning tanks after carrying Concentrated Sulfuric Acid?

  • A. Water freezes
  • B. Water turns steel into wood
  • C. Water reacts exothermically generating extreme heat and corrosive splattering
  • D. Water turns acid into rock
Answer: C — Water reacts exothermically generating extreme heat and corrosive splattering
Adding water to concentrated acid causes violent heat release and severe corrosive boiling.

26. What is a Certificate of Fitness for the Carriage of Dangerous Chemicals in Bulk?

  • A. Crew medical fitness
  • B. Engine overhaul certificate
  • C. Statutory certificate listing all specific chemical products approved for carriage
  • D. Pilot license
Answer: C — Statutory certificate listing all specific chemical products approved for carriage
Certificates of Fitness verify tank coatings, containment types, and allowed chemical lists.

27. What is the function of inert gas on chemical tankers carrying cargoes with flashpoints below 60°C?

  • A. Change color
  • B. Dissolve fumes
  • C. Maintain oxygen concentration below 8% to prevent flammability
  • D. Heat cargo
Answer: C — Maintain oxygen concentration below 8% to prevent flammability
Inerting reduces oxygen below 8%, eliminating explosion hazards in flammable chemical tanks.

28. What hazard is associated with Benzene cargo exposure?

  • A. Turns skin blue
  • B. Known human carcinogen causing leukemia and bone marrow damage
  • C. Heavy metal poisoning
  • D. Non-toxic
Answer: B — Known human carcinogen causing leukemia and bone marrow damage
Benzene is a aromatic hydrocarbon with severe chronic carcinogenic toxicity.

29. What is closed gauging on a chemical tanker?

  • A. Opening tank lids
  • B. Measuring by draft
  • C. Eye sight measuring
  • D. Measuring cargo level using vapor-tight devices without releasing toxic vapors
Answer: D — Measuring cargo level using vapor-tight devices without releasing toxic vapors
Closed gauging prevents crew exposure to toxic chemical fumes during level checks.

30. What chemical condition causes Phenol to solidify at temperatures below 40°C?

  • A. Nitrogen reaction
  • B. High melting point (~41°C) requiring continuous heating during transit
  • C. High water content
  • D. Evaporation
Answer: B — High melting point (~41°C) requiring continuous heating during transit
Phenol freezes at ~41°C; heating systems keep it liquid above 50°C.

Set 2 — 30 CHEMCO exit exam questions with answers

1. What chemical cargo property is defined as the lowest temperature at which liquid emits flammable vapor?

  • A. Flashpoint
  • B. Auto-ignition temp
  • C. Pour point
  • D. Boiling point
Answer: A — Flashpoint
Flashpoint determines cargo flammability classification under SOLAS and IBC rules.

2. What is the function of a toxic vapor return line during chemical loading?

  • A. Return displaced toxic/flammable tank vapors to shore treatment plant
  • B. Supply fresh water
  • C. Return liquid cargo
  • D. Equalize electric grounds
Answer: A — Return displaced toxic/flammable tank vapors to shore treatment plant
Vapor return lines route displaced vapors to shore recovery systems.

3. What is the role of an Inhibitor Certificate for chemical cargoes prone to polymerization?

  • A. Certifies engine power
  • B. Waives safety checks
  • C. Authorizes high speed
  • D. Certifies inhibitor name, concentration, date added, duration of effectiveness, and temp limits
Answer: D — Certifies inhibitor name, concentration, date added, duration of effectiveness, and temp limits
Shippers must provide inhibitor certificates verifying cargo stability during sea transit.

4. What type of personal protective suit provides complete gas-tight isolation against fatal chemical atmospheres?

  • A. Raincoat
  • B. Leather jacket
  • C. Gas-tight Type 1 (Level A) chemical suit with internal SCBA
  • D. Cotton boiler suit
Answer: C — Gas-tight Type 1 (Level A) chemical suit with internal SCBA
Level A gas-tight suits provide complete isolation against severe toxic chemical gases.

5. What is the maximum allowed discharge rate of Category Y cargo residues under MARPOL Annex II outside Special Areas?

  • A. Direct at jetty
  • B. Ship speed min 7 knots, below waterline discharge, distance > 12 nm from coast, water depth > 25 m
  • C. Any speed in port
  • D. 100 knots
Answer: B — Ship speed min 7 knots, below waterline discharge, distance > 12 nm from coast, water depth > 25 m
MARPOL Annex II specifies strict en-route discharge requirements for chemical tank washings.

6. What material coating is ruined if cleaned using high-pressure hot water above 60°C containing alkaline soaps?

  • A. Teak wood deck
  • B. Stainless steel
  • C. Epoxy tank coatings
  • D. Copper piping
Answer: C — Epoxy tank coatings
Hot water and strong alkalis cause blistering and degradation of epoxy linings.

7. What is the function of a cargo tank cofferdam on a chemical tanker?

  • A. Stores drinking water
  • B. Collects rainwater
  • C. Isolates chemical cargo tanks from accommodation, machinery spaces, or incompatible liquid tanks
  • D. Holds spare engine pistons
Answer: C — Isolates chemical cargo tanks from accommodation, machinery spaces, or incompatible liquid tanks
Cofferdams provide isolating void spaces preventing dangerous chemical cross-contamination.

8. What instrument measures relative humidity and dew point inside cargo tanks before loading moisture-sensitive chemicals?

  • A. Barometer
  • B. Chronometer
  • C. Anemometer
  • D. Electronic Hygrometer / Dew point meter
Answer: D — Electronic Hygrometer / Dew point meter
Hygrometers verify tank dryness before loading water-reactive chemical cargoes.

9. What action should be taken if Caustic Soda splashes into a seafarer's eye?

  • A. Immediately flush eye with clean fresh water at eyewash station for at least 15-20 minutes
  • B. Rub eye with rag
  • C. Apply engine oil
  • D. Close eye until tomorrow
Answer: A — Immediately flush eye with clean fresh water at eyewash station for at least 15-20 minutes
Immediate continuous water flushing prevents severe chemical alkali eye burns.

10. What is the function of high level and overfill alarms on chemical cargo tanks?

  • A. Provide audible/visual warnings at 95% and 98% capacity to prevent overflow
  • B. Measure ship roll
  • C. Signal pump room light
  • D. Indicate empty tank
Answer: A — Provide audible/visual warnings at 95% and 98% capacity to prevent overflow
High level (95%) and overfill (98%) alarms warn watchkeepers to prevent cargo overflows.

11. What is the primary danger of Nitrogen gas used for inerting chemical tanks?

  • A. Flammable explosion
  • B. Green skin
  • C. Acid burns
  • D. Oxygen displacement causing rapid asphyxiation and unconsciousness without warning
Answer: D — Oxygen displacement causing rapid asphyxiation and unconsciousness without warning
Nitrogen displaces air quietly, causing instant fatal oxygen deficiency.

12. What chemical cargo term describes liquids that produce severe lung damage if vapors are inhaled?

  • A. Respiratory toxic / Pulmonary edema hazard
  • B. Mineral water
  • C. Viscous liquid
  • D. Sweet scent
Answer: A — Respiratory toxic / Pulmonary edema hazard
Vapors of chemicals like Phosgene or Nitric acid cause fatal lung fluid accumulation.

13. What type of sampling equipment is used when taking chemical samples without opening tank hatches?

  • A. Closed-loop vapor lock sampling valve with portable sampling bottle
  • B. Open bucket
  • C. Glass cup
  • D. Soup ladle
Answer: A — Closed-loop vapor lock sampling valve with portable sampling bottle
Vapor locks allow sealed sampling without exposing crew to toxic vapors.

14. What document lists compatibility restrictions when planning stowage of multiple chemical cargoes?

  • A. Engine manual
  • B. Suez pass
  • C. Load line certificate
  • D. USCG Chemical Compatibility Chart / IBC Code Matrix
Answer: D — USCG Chemical Compatibility Chart / IBC Code Matrix
Compatibility matrices prevent stowage of reactive chemical pairs in adjacent tanks.

15. What is the function of a tank washing machine on chemical tankers?

  • A. Sandblasting
  • B. Paint spraying
  • C. High-pressure rotary water jets to wash chemical residues off bulkheads
  • D. Bilge pumping
Answer: C — High-pressure rotary water jets to wash chemical residues off bulkheads
Rotary tank washing machines clean internal bulkhead surfaces thoroughly.

16. Why must cargo pumps and pipelines be thoroughly blown down with air/N2 after cargo discharge?

  • A. Increase pressure
  • B. Cool main engine
  • C. Clear liquid pockets from piping to prevent contamination and line freezing
  • D. Clean hull
Answer: C — Clear liquid pockets from piping to prevent contamination and line freezing
Line blowing empties piping systems completely, leaving lines clean and dry.

17. What is Short Term Exposure Limit (STEL)?

  • A. 1 year limit
  • B. 24 hour limit
  • C. Ignition temp
  • D. Maximum allowable concentration for continuous 15-minute exposure period
Answer: D — Maximum allowable concentration for continuous 15-minute exposure period
STEL defines the safe peak exposure concentration allowed over 15 minutes.

18. What system prevents static electricity accumulation during high-rate loading of non-conducting chemical solvents?

  • A. Max speed pumping
  • B. Spraying water
  • C. Restricting initial loading rate (flow velocity < 1 m/s) and grounding/bonding lines
  • D. Opening hatches
Answer: C — Restricting initial loading rate (flow velocity < 1 m/s) and grounding/bonding lines
Flow velocities under 1 m/s prevent static spark accumulation during initial loading.

19. What step is taken if a chemical cargo tank lining shows extensive breakdown and rust spots?

  • A. Fill with seawater
  • B. Paint household paint
  • C. Tank must be de-gassed, cleaned, grit-blasted, and re-coated before loading compatible cargo
  • D. Ignore rust
Answer: C — Tank must be de-gassed, cleaned, grit-blasted, and re-coated before loading compatible cargo
Damaged tank coatings contaminate cargoes and lead to rapid hull steel corrosion.

20. Who is responsible for supervising all chemical cargo operations and safety checks on board?

  • A. Chief Cook
  • B. Steward
  • C. Chief Officer / Designated Cargo Officer
  • D. Deck Cadet
Answer: C — Chief Officer / Designated Cargo Officer
The Chief Officer leads cargo operations and dangerous chemical safety compliance.

21. You are preparing to contain an oil spill. You must first receive approval from the coastal authorities prior to __________.

  • A. employing a boom
  • B. using suction equipment
  • C. applying chemical agents
  • D. deploying skimmers
Answer: C — applying chemical agents
Chemical dispersants introduce additional substances into the marine environment and can harm marine life, so their use normally requires prior approval from the coastal State authority under its national contingency plan. Mechanical methods such as booms, skimmers and suction equipment can be used immediately without such approval.

22. Your vessel is taking on fuel when a small leak develops in the hose. You order the pumping stopped. Before you resume pumping, you should

  • A. notify the terminal superintendent
  • B. place a large drip pan under the leak and plug the scuppers
  • C. repair the hose with a patch
  • D. replace the hose
Answer: D — replace the hose
A leaking cargo or bunker hose has failed its integrity and must not be put back into service. Temporary patching is never acceptable; the defective hose should be replaced with one that is in date for pressure testing and in good condition before transfer resumes, in line with ISGOTT and terminal requirements.

23. If you detect oil in the water around your vessel while discharging fuel, the FIRST thing to do is _________ .

  • A. try to find out where the oil is coming from
  • B. call the Master
  • C. have the pumpman check the discharge piping
  • D. shutdown operations
Answer: D — shutdown operations
When oil is seen in the water during a transfer, the immediate action is to stop the operation so that any possible source of discharge is halted. Only after shutdown should the source be investigated, the Master informed and the SOPEP reporting procedure initiated.

24. Containment and Damage Control: which step is of highest importance for spill/damage control?

  • A. All personnel entering a contaminated space shall wear PPE
  • B. Actions toward controlling the immediate spread of the spill
  • C. For each pair entering a space, a trained person with appropriate equipment, will be on standby.
  • D. Action steps minimizing the impact to the ship and crew.
Answer: B — Actions toward controlling the immediate spread of the spill
In any spill response the first priority after ensuring personal safety is to control the immediate spread of the spill, stopping the source and containing the product. This limits pollution, fire and exposure hazards and is the core of SOPEP and SMPEP response actions.

25. What assigns for each new ship a calculable figure that will denote its total emissions of CO2 from combustion of fuel.

  • A. Energy Efficiency Design Index
  • B. Energy Inefficiency Design Index
  • C. SOX Design Index
  • D. VOX Design Index
Answer: A — Energy Efficiency Design Index
The Energy Efficiency Design Index, mandatory under MARPOL Annex VI chapter 4 for new ships, gives each ship a calculated figure of CO2 emissions per unit of transport work, expressed as grams of CO2 per tonne-mile, based on its design and installed power.

26. When did Annex VI take effect?

  • A. May 19, 2005
  • B. October 12, 1991
  • C. February 25, 1997
  • D. July 3, 2015
Answer: A — May 19, 2005
MARPOL Annex VI, Regulations for the Prevention of Air Pollution from Ships, was adopted by the 1997 Protocol and entered into force internationally on 19 May 2005 after meeting the ratification conditions.

27. The extent of MARPOL compliance is determined by:

  • A. Vessel type, size and speed
  • B. Vessel flag, type and age
  • C. Vessel type, size and crew
  • D. Vessel type, size and age
Answer: D — Vessel type, size and age
MARPOL requirements are applied according to the ship type (oil tanker, chemical tanker, other ship), its size in gross tonnage or deadweight, and its age, since many requirements depend on the date of build or contract, for example double hull and segregated ballast provisions under Annex I.

28. When you have completed bunkering operations, the hoses should be _________.

  • A. blown down with inert gas
  • B. drained into drip pans or tanks
  • C. stowed with their ends open for venting
  • D. steam cleaned and flushed with hot water
Answer: B — drained into drip pans or tanks
On completion of bunkering the hoses should be drained into drip trays or back into the tanks before disconnection, so that no oil remains to spill when the flanges are broken. Blanks are then fitted to the hose ends and the manifold.

29. What annex deals with regulations for the prevention of air pollution from ships?

  • A. Annex IV
  • B. Annex III
  • C. Annex I
  • D. Annex VI
Answer: D — Annex VI
MARPOL Annex VI contains the Regulations for the Prevention of Air Pollution from Ships, covering SOx, NOx, ozone-depleting substances, VOCs, shipboard incineration and energy efficiency. Annex I is oil, Annex III harmful substances in packaged form and Annex IV sewage.

30. What is the most important regulatory requirement for the master arriving at the lightering position?

  • A. Lightering of Oil and Hazardous Material Cargoes Pre-arrival notices.
  • B. Reporting of incidents.
  • C. Designation of lightering zones.
  • D. Factors considered in designating lightering zones.
Answer: A — Lightering of Oil and Hazardous Material Cargoes Pre-arrival notices.
Before arriving at a lightering position the Master must send the required pre-arrival notice for lightering of oil and hazardous material cargoes, giving vessel details, cargo and timing, so that the authorities and service providers can prepare. This is the primary regulatory obligation on arrival.

Set 3 — 30 CHEMCO exit exam questions with answers

1. Most minor spills of oil products are caused by

  • A. equipment failure
  • B. human error
  • C. major casualties
  • D. unforeseeable circumstances
Answer: B — human error
Industry statistics from ITOPF and OCIMF show that most small operational spills, especially during loading, discharging and bunkering, result from human error such as wrong valve settings, inattention or overfilling rather than equipment failure.

2. Containment and Damage Control: identify which step is of the highest importance for personal protection?

  • A. Don required PPE as determined from the MSDS. Contain liquid material using barriers, such as absorbents, rags or other equipment suitable to dam the flow.
  • B. Fight fire (if any), being careful to use firefighting methods compatible with the material involved.
  • C. Shut off or otherwise stem the spill at the source.
  • D. Contain liquid material using barriers, such as absorbents, rags or other equipment suitable to dam the flow.
Answer: A — Don required PPE as determined from the MSDS. Contain liquid material using barriers, such as absorbents, rags or other equipment suitable to dam the flow.
Personal protection comes first: responders must don the PPE identified in the SDS (MSDS) for the product before approaching the spill, and only then contain the liquid with absorbents or barriers. Without proper PPE, any other control action exposes personnel to toxic or corrosive hazards.

3. What is used to incinerate solid and liquid wastes arising from the operation of the ship?

  • A. Incinerator
  • B. Oily water separation
  • C. ISM Screen
  • D. Fire Sprinkler Cleaner
Answer: A — Incinerator
A shipboard incinerator, approved to the IMO standard under MARPOL Annex VI regulation 16, is used to burn solid and liquid wastes generated during the ship's normal operation, such as sludge and garbage, within permitted limits.

4. Oil Pollution Regulations require any transfer, or discharge of oil, or oily mixtures be recorded in the

  • A. Pollution Control Record
  • B. Bridge log
  • C. Oil Record book
  • D. Masters log
Answer: C — Oil Record book
MARPOL Annex I requires every oil transfer, ballasting, tank cleaning, discharge and disposal of oil residues to be recorded in the Oil Record Book, Part I for machinery space operations and Part II for cargo and ballast operations on oil tankers.

5. The Volatile Organic Compound (cargo vapor) Management Plan is required on what type of vessel?

  • A. Tank sensors
  • B. Container vessels
  • C. Ro-ro vessels
  • D. Crude Oil Carriers
Answer: D — Crude Oil Carriers
MARPOL Annex VI regulation 15.6 requires every tanker carrying crude oil to have on board and implement an approved VOC Management Plan to control emissions of volatile organic compounds during loading, voyage and discharge.

6. Your vessel is carrying 24,000 barrels (3816 cubic metres) of oil for discharge. The cargo hoses have an inside diameter of eight inches. The container around the loading manifold must hold _________.

  • A. three barrels
  • B. four barrels
  • C. six barrels
  • D. eight barrels
Answer: A — three barrels
Under US 33 CFR 155 requirements reflected in the USCG question bank, the size of the fixed spill containment under each loading manifold is based on the inside diameter of the transfer hose. For an eight-inch hose the bank requires a container capacity of three barrels.

7. It is generally NOT allowed to clean up an oil spill by using __________.

  • A. a boom
  • B. suction equipment
  • C. chemical agents
  • D. skimmers
Answer: C — chemical agents
Chemical dispersants are generally not permitted for oil spill cleanup without specific approval from the coastal State, because they spread oil into the water column and can harm marine life. Booms, skimmers and suction equipment are the preferred mechanical recovery means.

8. The total quantity of oil discharged at sea on new tankers must not exceed:

  • A. 1/15000 of the total quantity of that particular cargo of which the residue formed part
  • B. 1/20000 of the total quantity of that particular cargo of which the residue formed part
  • C. 1/25000 of the total quantity of that particular cargo of which the residue formed part
  • D. 1/30000 of the total quantity of that particular cargo of which the residue formed part
Answer: D — 1/30000 of the total quantity of that particular cargo of which the residue formed part
MARPOL Annex I regulation 34 limits the total quantity of oil discharged into the sea by an oil tanker delivered after 31 December 1979 to 1/30,000 of the total quantity of the particular cargo of which the residue formed part. Older tankers were allowed 1/15,000.

9. A starting interlock in the ODME ensures

  • A. the monitoring equipment is fully operational before commencing the discharge of the oil effluent at sea
  • B. prevents malfunctioning of the system
  • C. that an alarm is given off when the system malfunctions
  • D. stops discharge of the oil effluent when the oil content exceeds 5 part per million
Answer: A — the monitoring equipment is fully operational before commencing the discharge of the oil effluent at sea
The starting interlock of the ODME prevents the overboard discharge valve from being opened until the monitoring system is fully operational, as required by the IMO ODME guidelines under MARPOL Annex I regulation 31, so no effluent is discharged unmonitored.

10. A gas venting system on a tanker that has gas lines in each tank connected to a common gas main running the full length of the ship is called:

  • A. A gas-main system
  • B. A common-main system
  • C. A vent-main system
  • D. An independent system
Answer: B — A common-main system
In a common-main venting system each cargo tank's vent line connects to a common header running the length of the deck, which leads to a mast riser or vent stack. This differs from an independent system where each tank has its own P/V valve and vent.

11. Pneumatically Operating Valve; what is the most critical component for correct valve operation, based on your shipboard experience of running such a system?

  • A. Valve orifice
  • B. The Diaphragm
  • C. Valve stem
  • D. The valve springs
Answer: B — The Diaphragm
In a pneumatically operated valve the actuator diaphragm converts air pressure into stem movement. If the diaphragm is torn, hardened or leaking, the valve will not open or close fully, so its condition is the most critical factor for correct operation.

12. Advantages of using inert gas, pick one that is the main reason for its application,

  • A. No explosive mixtures can form in the tank.
  • B. Reduces corrosion.
  • C. Voyage cleaning of tanks is unnecessary.
  • D. Reduces pumping time because of positive pressure in the tanks.
Answer: A — No explosive mixtures can form in the tank.
The main purpose of an inert gas system, as required by SOLAS II-2 regulation 4.5.5, is to keep the oxygen content in cargo tanks below 8% so that a flammable mixture cannot form. Reduced corrosion is only a secondary benefit.

13. Cargo system Valves can be categorized in many ways: identify one operation that can be classified as, manual remote,

  • A. Local or remote actuation: Local control means the operator is at the valve and controls it directly.
  • B. When the valve is located some distance from the operator such as at the bottom of the cargo tank, it is then necessary to install a reach rod for remote actuation.
  • C. A reach rod assembly is a series of steel rods coupled to connect the stem of the valve in the tank to a valve operating stand on deck.
  • D. In automated cargo systems, the valves are frequently operated using hydraulic or pneumatic motors connected to the stem
Answer: C — A reach rod assembly is a series of steel rods coupled to connect the stem of the valve in the tank to a valve operating stand on deck.
A reach rod assembly is the classic manual remote valve operation: a series of steel rods coupled to the valve stem in the tank allows the valve to be operated by hand from a deck stand. Local control and hydraulic or pneumatic actuation fall into other categories.

14. Acidic solutions are formed in cargo tanks of tankers

  • A. when sulphur compounds in oil cargoes react with water
  • B. when sulphur compounds in oil cargoes react with oxygen
  • C. when sulphur compounds in oil cargoes react with hydrocarbon gas
  • D. when sulphur compounds in oil cargoes react with chemicals
Answer: A — when sulphur compounds in oil cargoes react with water
Sulphur compounds in oil cargoes, particularly hydrogen sulphide and mercaptans, react with water present in tanks to form acidic solutions, which accelerate corrosion of tank structures and coatings.

15. An inert gas generator burns what oil to generate inert gas ?

  • A. Crude oil
  • B. Gas oil
  • C. Heavy oil
  • D. Diesel oil
Answer: B — Gas oil
An inert gas generator burns a clean, low-sulphur distillate fuel such as gas oil in a combustion chamber, producing flue gas with low oxygen content and minimal sulphur oxides, which is then cooled and scrubbed before delivery.

16. Back flow of inert gas is prevented by:

  • A. An isolating valve
  • B. The deck water seal
  • C. A valve provided in the scrubber
  • D. The deck mechanical non-return valve
Answer: B — The deck water seal
The deck water seal is the principal device preventing the back flow of hydrocarbon gas from the cargo tanks to the IG plant and machinery spaces, as required by the FSS Code chapter 15. The non-return valve is an additional safeguard.

17. Tank coating requirements developed by IMO are applicable to

  • A. new crude oil tankers of 5000 GRT and above
  • B. new crude oil tankers of 5000 DWT and above
  • C. new crude oil tankers of 500 GRT and above
  • D. new crude oil tankers of 500 DWT and above
Answer: B — new crude oil tankers of 5000 DWT and above
The IMO Performance Standard for Protective Coatings of cargo oil tanks, made mandatory by SOLAS II-1 regulation 3-11, applies to new crude oil tankers of 5,000 tonnes deadweight and above.

18. A deepwell pump is a type of ___________.

  • A. screw pump
  • B. centrifugal pump
  • C. eductor
  • D. gear pump
Answer: B — centrifugal pump
A deepwell pump is a vertical centrifugal pump with the impeller at the tank bottom, driven through a long shaft by a motor on deck. It is widely used on chemical and product tankers for segregated cargo handling.

19. Bottom washing:

  • A. is done to remove traces of the previous cargo
  • B. will remove heavy wax sediments at the tank bottom
  • C. is not effective when carrying a small quantity of refined products
  • D. cannot be done with chemical solvents
Answer: A — is done to remove traces of the previous cargo
Bottom washing is carried out with fixed tank cleaning machines directed at the tank bottom to remove traces and residues of the previous cargo before loading a new one or before inspection.

20. The total capacity of all slop tanks on an oil tanker normally should be

  • A. 1% of the total oil carrying capacity of ship
  • B. 2% of the total oil carrying capacity of ship
  • C. 3% of the total oil carrying capacity of ship
  • D. 4% of the total oil carrying capacity of ship
Answer: C — 3% of the total oil carrying capacity of ship
MARPOL Annex I regulation 29 requires slop tanks with a total capacity of not less than 3% of the oil carrying capacity of the ship, reduced to 2% in certain cases such as where segregated ballast or COW arrangements allow.

21. An inert gas system is required to be fitted:

  • A. On all tankers of above 20,000 tonnes deadweight
  • B. On product tankers of above 20,000 tonnes deadweight
  • C. On crude oil tankers of above 20,000 tonnes deadweight
  • D. On chemical tankers of above 20,000 tonnes deadweight
Answer: C — On crude oil tankers of above 20,000 tonnes deadweight
The original SOLAS 1974 as amended by the 1978 Protocol required inert gas systems on crude oil tankers of 20,000 tonnes deadweight and upwards. Current SOLAS II-2 regulation 4.5.5 extends this to oil and chemical tankers of 8,000 dwt and above built after 2016.

22. Centrifugal pumps are otherwise known as

  • A. Reciprocating pumps
  • B. Gravity pumps
  • C. Positive discplacement pumps
  • D. Hydro-dynamic pumps
Answer: D — Hydro-dynamic pumps
Centrifugal pumps are hydro-dynamic or rotodynamic pumps: they impart velocity to the liquid with a rotating impeller and convert it to pressure in the volute. Positive displacement pumps such as reciprocating and screw types work on a different principle.

23. The ring main pipeline system is extensively used on:

  • A. VLCCs
  • B. Crude oil tankers
  • C. Medium range tankers
  • D. Product carriers
Answer: D — Product carriers
Product carriers carry several grades simultaneously and need flexible segregation, so the ring main pipeline system, which allows several tanks to be connected in different combinations, is widely used on them. Crude carriers normally use direct line systems.

24. Class B fires are caused by

  • A. combustible solids
  • B. flammable liquids
  • C. flammable gases
  • D. electricity
Answer: B — flammable liquids
Class B fires involve flammable liquids such as oil, petrol and solvents. Class A covers combustible solids, Class C flammable gases (in the European system), and electrical fires are treated separately.

25. Use of Pressure-Vacuum (PV) Relief Valve; label the diagram correctly,

  • A. 1-IG Main; 2-Deck Isolating Valve ; 3- Vent Main; 4- By-Pass Valve; 5- PV valve; 6- Tank Isolating Valve
  • B. 1-Deck Isolating Valve; 2- Vent Main; 3- IG Main; 4- By-Pass Valve; 5- PV valve; 6- Tank Isolating Valve
  • C. 1-Deck Isolating Valve; 2- IG Main; 3- Vent Main; 4- By-Pass Valve; 5- PV valve; 6- Tank Isolating Valve
  • D. 1-Deck Isolating Valve; 2- IG Main; 3- Vent Main; 4- By-Pass Valve; 5 - Tank Isolating Valve; 6- PV valve
Answer: C — 1-Deck Isolating Valve; 2- IG Main; 3- Vent Main; 4- By-Pass Valve; 5- PV valve; 6- Tank Isolating Valve
In the standard IG and venting diagram the deck isolating valve is followed by the IG main and the vent main, with a by-pass valve, the PV valve on the tank and the tank isolating valve. This sequence reflects the arrangement shown in the IMO model course illustration.

26. Cargo tank fill alarm indicator panels:

  • A. are normally fitted on the bridge and sometimes on deck
  • B. are normally fitted in the engine control room and sometimes on deck
  • C. are normally fitted on the bridge and sometimes in the engine control room
  • D. are normally fitted in the cargo control room and sometimes on deck
Answer: D — are normally fitted in the cargo control room and sometimes on deck
Cargo tank high level and overfill alarm indicator panels are normally fitted in the cargo control room where the officer on watch monitors cargo operations, with repeaters or audible and visual alarms on deck as required by IBC Code 15.19 and SOLAS.

27. Identify the equipment in the IG system correctly,

  • A. 1-O2 Analyzer ; 2-Demister; 3-Air Intake-Gas Freeing; 4- Regulating Valves; 5- Blowers
  • B. 1- Demister; 2-O2 Analyzer; 3-Air Intake-Gas Freeing; 4- Regulating Valves; 5- Blowers
  • C. 1- Demister; 2-O2 Analyzer; 3 - Blowers ; 4- Regulating Valves; 5- Air Intake-Gas Freeing
  • D. 1- Demister; 2-O2 Analyzer; 3-Regulating Valves; 4-Air Intake-Gas Freeing ; 5- Blowers
Answer: B — 1- Demister; 2-O2 Analyzer; 3-Air Intake-Gas Freeing; 4- Regulating Valves; 5- Blowers
In the IG system diagram the flue gas passes through the scrubber and demister, the oxygen analyser monitors the gas, the air intake is used for gas freeing, and the regulating valves and blowers control delivery. The sequence demister, O2 analyser, air intake, regulating valves and blowers matches the model course illustration.

28. Tank level measurement by gauging tape and plumb bob: find the labeling combination that is correct,

  • A. 1- Reference Point; 2-Tape Cut; 3-Bob Cut; 4-Ullage; 5- Innage
  • B. 1- Reference Point; 2-Tape Cut; 3-Bob Cut; 4-Innage; 5- Ullage
  • C. 1- Bob Cut; 2-Reference Point; 3-Tape Cut; 4-Ullage; 5- Innage
  • D. 1- Innage; 2-Tape Cut; 3-Bob Cut; 4-Ullage; 5- Reference Point
Answer: A — 1- Reference Point; 2-Tape Cut; 3-Bob Cut; 4-Ullage; 5- Innage
In tape and bob gauging the reference point is at the top of the gauging pipe, the tape cut and bob cut show where the product wets the tape, and ullage is measured from the reference point to the liquid surface while innage is measured from the bottom. This gives the labelling reference point, tape cut, bob cut, ullage, innage.

29. Cargo discharging: find a statement that ensures safe cargo discharging from start to finish,

  • A. When the vessel arrives at the discharge port, the inert gas system should be tested and ready for operation in due time for discharge.
  • B. Before pumping of cargo oil is started, the inert gas system should be in operation and connected to the deck line, with the pressure control in the "automatic" position.
  • C. Cargo discharge should not be commenced until all the conditions have been checked; tanks should be re- pressurized if required
  • D. During discharge the oxygen content and pressure of the inert gas in the inert gas main should be continuously recorded as per regulation.
Answer: D — During discharge the oxygen content and pressure of the inert gas in the inert gas main should be continuously recorded as per regulation.
During discharge SOLAS and the FSS Code require the oxygen content and pressure in the inert gas main to be continuously indicated and recorded, so that the tanks remain inerted and at positive pressure throughout the operation from start to finish.

30. Automatic shutdown systems independent of operator intervention: how to ensure that it will work correctly?

  • A. Express approval for their use is required from both the flag administration and the port state authorities.
  • B. Automatic shutdown systems are normally designed to shut the main cargo tank filling valve if the liquid level rises above the maximum level permitted.
  • C. Ensure that the activation point is set accurately, and that the operation of the device is checked by simulation whenever the system is recommissioned.
  • D. If the ship and shore shutdown circuits are to be linked their operation should be checked before cargo transfer begins; if not, the terminal should be informed of the closing rate of the ship's valves.
Answer: D — If the ship and shore shutdown circuits are to be linked their operation should be checked before cargo transfer begins; if not, the terminal should be informed of the closing rate of the ship's valves.
If ship and shore automatic shutdown circuits are linked, their operation must be tested before transfer begins. If they are not linked, the terminal must be told the ship's valve closing rate so that surge pressure from a sudden shutdown can be avoided, as advised in ISGOTT.

Set 4 — 30 CHEMCO exit exam questions with answers

1. Statements on Float Gauges; identify the key statement of importance,

  • A. Floats should be secured when at sea, except briefly during measurement of tank contents.
  • B. If the float remains unsecured at sea it will almost certainly be damaged due to sloshing of the cargo
  • C. Remote and local readings should be compared frequently to determine discrepancies;
  • D. Readings may need to be corrected to allow for tape and tank expansion or contraction, and ship trim and heel. Tables are normally provided for this purpose
Answer: B — If the float remains unsecured at sea it will almost certainly be damaged due to sloshing of the cargo
Float gauges must be secured at sea because unsecured floats are almost certainly damaged by cargo sloshing, leading to inaccurate readings or loss of the gauge. ISGOTT stresses this as the key operating point for float gauges.

2. Several types of bobs connected to handheld tapes: Identify those correctly,

  • A. 1-Innage Bob; 2-Plain Ullage Bob; 3-Extension Outage Bob; 4-Deep-grooved ullaged Bob
  • B. 1-Innage Bob; 2-Extension Outage Bob; 3-Deep-grooved ullaged Bob; 4-Plain Ullage Bob
  • C. 1-Extension Outage Bob; 2-InnageBob ; 3-Plain Ullage Bob; 4-Deep-grooved ullaged Bob
  • D. 1-Innage Bob; 2-Extension Outage Bob; 3-Plain Ullage Bob; 4-Deep-grooved ullaged Bob
Answer: D — 1-Innage Bob; 2-Extension Outage Bob; 3-Plain Ullage Bob; 4-Deep-grooved ullaged Bob
Handheld gauging tapes use different bobs for different purposes: innage bobs for innage measurement, extension outage bobs and plain ullage bobs for ullage, and deep-grooved ullage bobs for viscous products. The labelling innage, extension outage, plain ullage and deep-grooved ullage bob matches the reference diagram.

3. Example of cargo heating system: identify correct labelling

  • A. 1-Steam Return Line; 2-Compressed Air Line ; 3- Steam Supply Line; 4- Toxic Gas Detector
  • B. 1-- Toxic Gas Detector; 2-Steam Return Line; 3- Steam Supply Line; 4-Compressed Air Line
  • C. 1-Compressed Air Line; 2-Steam Return Line; 3- Steam Supply Line; 4- Toxic Gas Detector
  • D. 1-Steam Supply Line; 2-Steam Return Line; 3-Compressed Air Line; 4- Toxic Gas Detector
Answer: C — 1-Compressed Air Line; 2-Steam Return Line; 3- Steam Supply Line; 4- Toxic Gas Detector
A typical cargo heating coil arrangement on a chemical tanker shows the compressed air line for blowing through, the steam return line, the steam supply line and a toxic gas detector in the condensate observation tank. That sequence matches the model course diagram.

4. Inerting Operations:During normal operation of oil tankers the following operational modes frequently take place: find an operation that is required after tank cleaning during a ballast voyage and before loading

  • A. Inerting of empty tanks
  • B. Inerting during loading and simultaneous discharge of ballast
  • C. Inerting during loaded sea voyage
  • D. Inerting during discharging and ballasting
Answer: A — Inerting of empty tanks
After tank cleaning on a ballast voyage the tanks contain air, so before loading they must be re-inerted to bring the oxygen content below 8% by volume as required by SOLAS II-2 regulation 4.5.5 and the FSS Code chapter 15.

5. The terminal indicates to you that they are going to use a booster pump to assist the discharging operation. You start the discharge and in a few minutes the pressure drops sharply. This could be a result of the ___________.

  • A. booster pump coming on the line and discharging properly
  • B. booster pump failing to start
  • C. ship's pump speeding up
  • D. booster pump being lined up in the wrong direction
Answer: A — booster pump coming on the line and discharging properly
When a shore booster pump comes on line and pumps properly, it reduces the back pressure the ship's pump must work against, so the ship's manifold discharge pressure drops. A sudden drop shortly after starting is therefore consistent with the booster functioning correctly.

6. A restricted tank gauging system

  • A. Allows limited amounts of vapour to escape
  • B. Does not allow vapour to escape
  • C. Uses a float gauge
  • D. Does not use an ullage tape
Answer: A — Allows limited amounts of vapour to escape
Under the IBC Code a restricted gauging device penetrates the tank and, when in use, permits a small quantity of cargo vapour or liquid to escape to the atmosphere, such as a sounding pipe or ullage tube. A closed gauging device allows no vapour release.

7. The lowest temperature at which the liquid remains a fluid is called the:

  • A. The flow point
  • B. The pour point
  • C. The melting point
  • D. The Liquefaction point
Answer: B — The pour point
The pour point is the lowest temperature at which an oil will still flow under standard test conditions. Below it the product becomes too viscous or waxy to pour, which is important when planning cargo heating.

8. An inert gas system installed on a tanker is designed to

  • A. aid in the stripping and cleaning of cargo tanks
  • B. increase the rate of discharge of cargo
  • C. force toxic and explosive fumes from a cargo tank to vent to the outside atmosphere
  • D. lower the oxygen levels inside cargo tanks, making explosion nearly impossible
Answer: D — lower the oxygen levels inside cargo tanks, making explosion nearly impossible
An inert gas system is designed to keep the oxygen content in cargo tanks at 8% or less by volume, below the level at which hydrocarbon gas can burn, so that a fire or explosion in the tank becomes practically impossible, as required by SOLAS II-2 regulation 4.5.5.

9. For the purposes of cargo oil containment, the fixed container under the manifold of an eight-inch loading line must hold a minimum of

  • A. three barrels
  • B. four barrels
  • C. six barrels
  • D. eight barrels
Answer: A — three barrels
Under the US 33 CFR 155 requirements used in the USCG question bank, the fixed containment under a manifold is sized according to the hose or loading line diameter. For an eight-inch line the bank specifies a minimum capacity of three barrels.

10. What is the purpose of the relief valve of a cargo pump?

  • A. Provides for the removal of vapors
  • B. Allows two or more tanks to be filled at the same time
  • C. Provides for the emergency shutdown of the pump
  • D. Permits the return of cargo to the suction side of the pump
Answer: D — Permits the return of cargo to the suction side of the pump
The relief valve on a positive displacement cargo pump protects the pump and pipeline against overpressure by opening and returning cargo from the discharge side back to the suction side when the set pressure is exceeded, for example if a discharge valve is closed.

11. Identify correct labelling for Tanker VEC

  • A. 1- P/V Valve; 2- P/V Breaker; 3- Mast Riser; 4 - Deck water seal
  • B. 1- P/V Valve; 2- P/V Breaker; 3- Deck water seal; 4- Mast Riser
  • C. 1- Mast Riser; 2- P/V Breaker; 3- P/V Valve; - Deck water seal
  • D. 1- P/V Valve; 2- Mast Riser; 3- P/V Breaker; 4 - Deck water seal
Answer: D — 1- P/V Valve; 2- Mast Riser; 3- P/V Breaker; 4 - Deck water seal
In a typical tanker vapour emission control arrangement the P/V valve, mast riser, P/V breaker and deck water seal are arranged as shown in the standard diagram. The labelling P/V valve, mast riser, P/V breaker and deck water seal corresponds to that layout.

12. A single fitting installed in a pipeline that either blanks off the pipe or allows a full flow passage of a liquid through the pipe is referred to as a _____.

  • A. blind flange
  • B. pivot coupling
  • C. quick-release coupling
  • D. spectacle flange
Answer: D — spectacle flange
A spectacle flange is a single fitting with a solid blank on one side and an open ring on the other. Rotating it either blanks the pipeline completely or allows full flow, giving positive and visible segregation of cargo lines.

13. Hydrocarbon gas normally encounted in petroleum tankers cannot burn in an atmosphere containing oxygen less than

  • A. 2%
  • B. 11%
  • C. 5%
  • D. 8%
Answer: B — 11%
ISGOTT states that hydrocarbon gas normally encountered in petroleum tankers cannot burn in an atmosphere containing less than approximately 11% oxygen by volume. SOLAS sets the 8% limit for tank atmospheres to give a safety margin.

14. Who is responsible for ensuring instruments are sent ashore for calibration when required ?

  • A. The Company
  • B. The Master
  • C. The Safety Officer
  • D. The Chief Officer
Answer: D — The Chief Officer
Under typical SMS procedures the Chief Officer, as head of the deck department responsible for cargo and gas measuring instruments, ensures that gas detectors and other instruments are sent ashore for calibration when due and that calibration records are kept.

15. An on-board monitoring system, using level sensors permanently installed in each vessel compartment, will have a high level alarm set at not more than

  • A. 90% of compartment capacity
  • B. 95% of compartment capacity
  • C. 97% of compartment capacity
  • D. 99% of compartment capacity
Answer: B — 95% of compartment capacity
Overfill protection standards require the high level alarm to be set at not more than 95% of tank capacity, with a separate overfill alarm at about 98%, as reflected in IBC Code 15.19 and USCG requirements, giving time to stop loading before overflow.

16. The volatility of a flammable liquid is indicated by its

  • A. ignition temperature
  • B. flash point
  • C. flammable range
  • D. conversion index
Answer: B — flash point
The flash point, the lowest temperature at which a liquid gives off enough vapour to form a flammable mixture near its surface, is the standard indicator of volatility and fire hazard used in ISGOTT and the IBC Code classification of cargoes.

17. Which action must be taken when an individual cargo tank is closed off from the inert gas system by the tank isolation valve?

  • A. The tank must be gas freed.
  • B. The tank must be ballasted.
  • C. The tank must be vented to the atmosphere.
  • D. The bypass valve must also be closed.
Answer: C — The tank must be vented to the atmosphere.
When a cargo tank is isolated from the inert gas main by its isolating valve, it loses the protection of the main's P/V breaker, so it must be protected by venting to atmosphere through its own P/V valve or vent line to avoid over or under pressure, as required by the FSS Code chapter 15.

18. The purpose of inert gas systems aboard tankers is to

  • A. allow sufficient oxygen in the tank to sustain life
  • B. prevent outside air from entering the tank
  • C. provide increase in cargo discharge pressure
  • D. comply with double hull pollution prevention regulations
Answer: B — prevent outside air from entering the tank
An inert gas system keeps cargo tanks at a positive pressure with low-oxygen gas, which prevents outside air from entering the tank. Excluding air keeps the oxygen content below 8% and prevents a flammable atmosphere forming.

19. Before a tank is to be crude oil washed, the oxygen content in the tank must be measured at a position ________.

  • A. immediately above the level of the oil
  • B. at the top of the tank
  • C. in the vent riser
  • D. one meter from the deck
Answer: D — one meter from the deck
The IMO COW specifications and MARPOL Annex I require the oxygen content to be measured at a point one metre below the deck and at the middle of the ullage space before crude oil washing, and it must not exceed 8% by volume.

20. The explosive range of petroleum vapors mixed with air is

  • A. 0% to 1%
  • B. 1% to 10%
  • C. 10% to 15%
  • D. 12% to 20%
Answer: B — 1% to 10%
The flammable range of petroleum vapour in air is approximately 1% to 10% hydrocarbon by volume. Below the lower flammable limit the mixture is too lean and above the upper limit too rich to burn, as described in ISGOTT.

21. The (auto) ignition temperature is that temperature at which __________.

  • A. no spark or flame is required to ignite gas or vapor
  • B. a fuel begins to give off explosive vapors
  • C. a fuel if ignited will continue to burn
  • D. a 1% mixture of the fuel with air will explode
Answer: A — no spark or flame is required to ignite gas or vapor
The auto-ignition temperature is the lowest temperature at which a substance will ignite spontaneously in air without any spark, flame or other external ignition source, simply by being heated.

22. In reference to accidental oil pollution, the most critical time during bunkering is when

  • A. you first start to receive fuel hoses are being disconnected
  • B. hoses are being blown down
  • C. final topping off is occurring
  • D. hoses are being disconnected
Answer: C — final topping off is occurring
Topping off is the most critical stage of bunkering because the tank is nearly full, flow must be reduced and valves changed over, and any delay or misjudgement results in overflow through the vents. Most bunker spills occur at this stage, so extra manning and reduced rates are required.

23. Which characteristic is an advantage of a butterfly valve as compared to a gate valve?

  • A. Precise control over cargo flow
  • B. Quick operation
  • C. No resistance to cargo flow when open
  • D. Less maintenance required
Answer: B — Quick operation
A butterfly valve needs only a quarter turn to go from fully closed to fully open, so it can be operated much faster than a gate valve, which needs many turns of the handwheel. It also takes less space and is simpler to actuate remotely.

24. Which of the following is not an exception provided under MARPOL, Annex-1, regarding the discharge of oil or oily mixture into the sea?

  • A. Discharge for the purpose of securing safety of a ship
  • B. Discharge for the purpose of saving life at sea
  • C. Discharge resulting due to damage to the ship because of Master's fault even if the Master/Owner of the ship has taken all reasonable precautions to prevent/minimize discharge
  • D. Discharge resulting due to damage to the ship not because of Master's fault, but because of a third party's fault and action awaited by Master from that third party to prevent /minimize discharge
Answer: D — Discharge resulting due to damage to the ship not because of Master's fault, but because of a third party's fault and action awaited by Master from that third party to prevent /minimize discharge
MARPOL Annex I regulation 4 excepts discharges to secure ship safety or save life, and discharges from damage provided all reasonable precautions were taken by the ship. Waiting for a third party to act is not an exception, as the Master must himself take all reasonable steps to prevent or minimise the discharge.

25. While using a combustible gas indicator, if the hydrocarbon content of the atmosphere exceeds the U.E.L., the needle of the indicator will

  • A. remain at zero without moving
  • B. move to the maximum reading and stay there
  • C. move halfway up the scale
  • D. move to the maximum reading and immediately return to zero
Answer: D — move to the maximum reading and immediately return to zero
A catalytic combustible gas indicator works on a Wheatstone bridge. When the concentration exceeds the UEL the needle swings briefly to full scale and then falls back to zero because there is insufficient oxygen to burn on the filament, which can mislead the operator into thinking the atmosphere is safe.

26. In the ‘flow through’ method of ballast water exchange:

  • A. Ballast equal to approximately two times the tank capacity must be pumped through the tank
  • B. Ballast equal to approximately three times the tank capacity must be pumped through the tank
  • C. Ballast equal to approximately four times the tank capacity must be pumped through the tank
  • D. Ballast equal to approximately five times the tank capacity must be pumped through the tank
Answer: B — Ballast equal to approximately three times the tank capacity must be pumped through the tank
Under the Ballast Water Management Convention regulation D-1, the flow-through method of exchange requires pumping through at least three times the volume of each ballast tank to achieve the 95% volumetric exchange standard.

27. The preferred type of pollution control for oil spills on the water is(are)

  • A. straw
  • B. booms
  • C. skimmers
  • D. chemical dispersants
Answer: B — booms
Booms are the preferred primary means of controlling an oil spill on water because they contain the oil and prevent it spreading, allowing recovery by skimmers. Chemical dispersants need coastal State approval and are a secondary option.

28. Which operation may cause the pressure in an inert tank to fall below the prescribed limits?

  • A. Loading
  • B. Discharging
  • C. Crude oil washing
  • D. Steaming tanks
Answer: B — Discharging
During discharge cargo is pumped out faster than the tank space may be replaced, so the tank pressure tends to fall. If the IG supply cannot keep pace, the pressure may drop below the prescribed minimum, risking air ingress, so discharge rate must be matched to IG capacity.

29. The most likely location for a liquid cargo fire to occur on a tanker would be

  • A. in the midships house
  • B. at the main deck manifold
  • C. at the vent header
  • D. in the pumproom
Answer: D — in the pumproom
The cargo pumproom contains pumps, seals, glands and pipelines handling cargo below deck in an enclosed space where vapours can accumulate. It is therefore the most likely location for a liquid cargo fire, which is why SOLAS requires gas detection, ventilation and fixed fire protection there.

30. Identify the correct labeling, when the tanker has heeled to a small angle.

  • A. 1- Metacenter; 2- GZ- Righting Lever; 3-Center of Gravity; 4- Center of Buoyancy
  • B. 1- Center of Gravity; 2- GZ- Righting Lever; 3-Center of Buoyancy; 4- Metacenter
  • C. 1- Metacenter; 2- GZ-Shift of Buoyancy; 3-Center of Buoyancy; 4- Center of Gravity
  • D. 1- Metacenter; 2- GZ- Righting Lever; 3-Center of Buoyancy; 4- Center of Gravity
Answer: D — 1- Metacenter; 2- GZ- Righting Lever; 3-Center of Buoyancy; 4- Center of Gravity
When a ship heels to a small angle the centre of buoyancy moves to the low side, and the vertical through it meets the centreline at the metacentre. The horizontal distance from the centre of gravity to that vertical is the righting lever GZ. The labelling metacentre, GZ, centre of buoyancy and centre of gravity is correct.

Set 5 — 30 CHEMCO exit exam questions with answers

1. Working instructions specifying the manner in which the ship is to be loaded and ballasted to avoid unacceptable stresses in the vessel’s structure is required for tankers:

  • A. Greater than 50 metres in length
  • B. Greater than 75 meters in length
  • C. Greater than 100 meters in length
  • D. Greater than 150 meters in length
Answer: D — Greater than 150 meters in length
The Load Line Convention regulation 10 and SOLAS require ships over 150 metres in length to carry an approved loading manual and loading instrument with instructions to avoid unacceptable hull stresses during loading and ballasting.

2. A self-contained breathing apparatus is used to

  • A. make underwater repairs to barges
  • B. determine if the air in a tank is safe for men
  • C. enter areas that may contain dangerous fumes or lack oxygen
  • D. resuscitate an unconscious person
Answer: C — enter areas that may contain dangerous fumes or lack oxygen
A self-contained breathing apparatus supplies breathable air from a cylinder carried by the wearer, allowing safe entry into spaces with toxic or flammable vapours or oxygen deficiency, for example for rescue or firefighting. It is not used for testing the atmosphere.

3. Part A of the the ISGOTT Ship/Shore Safety Check-List provides operational procedures for:

  • A. Transfer of bulk liquids, physical checks
  • B. Transfer of bulk liquids – elements to be verified verbally
  • C. Additional considerations for Bulk Liquid Chemicals
  • D. Additional considerations for Bulk Liquefied Gases
Answer: A — Transfer of bulk liquids, physical checks
Part A of the ISGOTT Ship/Shore Safety Checklist covers the general checks for transfer of bulk liquids that are physically verified by ship and shore representatives, such as moorings, access, communications and emergency arrangements.

4. The approval period for a shipboard Oil Pollution Emergency Plan expires after

  • A. two years
  • B. three years
  • C. four years
  • D. five years
Answer: D — five years
A vessel oil spill response plan under US OPA 90 rules in 33 CFR 155 is approved for a period of five years, after which it must be resubmitted for approval. The plan must also be reviewed annually by the operator.

5. Which of the listed functions is the purpose of a gas scrubber in an inert gas generation system?

  • A. Cools the inert gas.
  • B. Maintains the oxygen content at 5% by volume.
  • C. Bleeds off static electricity in the inert gas.
  • D. Maintains flow to the water seal on the gas main.
Answer: A — Cools the inert gas.
The scrubber cools the hot flue gas from the boiler uptake by spraying seawater through it, while also removing soot and most of the sulphur dioxide. Cooling is its main function, since hot gas cannot be delivered to the cargo tanks.

6. With an increase in temperature the volume of flammable and combustible liquids____.

  • A. expands
  • B. contracts
  • C. remains constant
  • D. remains constant if pressure remains constant
Answer: A — expands
Flammable and combustible liquids expand as their temperature rises, which is why ullage must be left in cargo tanks to allow for thermal expansion during the voyage and why volume measurements are corrected to standard temperature.

7. The standard unit of liquid volume used in the petroleum industry, as well as the tanker industry, is a __________.

  • A. barrel
  • B. drum
  • C. gallon
  • D. liter
Answer: A — barrel
The barrel, equal to 42 US gallons or about 159 litres, is the standard unit of liquid volume in the petroleum and tanker industries for cargo quantities and bills of lading.

8. Combustible gas indicators operate by drawing an air sample into the instrument

  • A. over an electrically heated platinum filament
  • B. where it is mixed with nitrogen
  • C. where it is ignited by a sparking device
  • D. where its specific gravity is measured
Answer: A — over an electrically heated platinum filament
A catalytic combustible gas indicator draws the sample over an electrically heated platinum filament. Combustible gas burns on the filament, raising its temperature and resistance, which unbalances the Wheatstone bridge and gives a reading in percent LEL.

9. After each reading of an oxygen indicator, the instrument should be purged with

  • A. CO2
  • B. fresh air
  • C. the tested compartment's air
  • D. water
Answer: B — fresh air
After each reading the oxygen analyser should be purged with fresh air so that the sensor returns to 20.9% and residual sample gas does not affect the next measurement or damage the cell.

10. When the cofferdam to be purged to check the leakage and remove the leaked oil?

  • A. Before starting the cargo operation
  • B. Before starting the cargo operation and after the cargo operation is completed
  • C. During the cargo operation
  • D. After the cargo operation is completed
Answer: B — Before starting the cargo operation and after the cargo operation is completed
Cofferdams around cargo spaces, such as at pump seals, should be purged and checked for leakage before cargo operations commence and again after completion, so that any leaked cargo is detected and removed and does not create a hazard or contamination.

11. How the Framo pump has almost eliminated cavitation for free flowing liquids?

  • A. Volute casing is designed in such a way, that its smoothness avoids cavitation
  • B. The backwards curved vanes eliminate the cavitation
  • C. The hydrofoil design of the curved vanes, eliminate cavitation
  • D. Since the suction pipe is eliminated, cavitation is also eliminated for liquids with free flow
Answer: D — Since the suction pipe is eliminated, cavitation is also eliminated for liquids with free flow
A Framo submerged pump sits at the bottom of the tank with the impeller immersed in cargo, so there is no long suction pipe and the liquid flows directly into the impeller. With no suction lift, cavitation is practically eliminated for free-flowing liquids.

12. Select the correct statement.

  • A. Pressure type vacuum valves can prevent Backflow.
  • B. Dynamic pressure is a function of the fluid velocity and its density.
  • C. The water reservoir of a self-priming pump may be at the back of the impeller.
  • D. Stripping pumps are not of the self-priming type.
Answer: B — Dynamic pressure is a function of the fluid velocity and its density.
Dynamic pressure is the kinetic energy per unit volume of a moving fluid, equal to half the density multiplied by the square of the velocity. It therefore depends on fluid velocity and density.

13. Why the cargo pump in the Framo cannot be overloaded?

  • A. The pressure of hydraulic oil to the motor driving the cargo pump is designed in such a way that, the flow is always kept constant
  • B. The pressure of hydraulic oil to the motor driving the cargo pump is designed in such a way that, the pump runs at the optimum speed
  • C. The pressure of hydraulic oil to the motor driving the cargo pump is designed in such a way that, when the pump over speeds, the flow of oil is reduced
  • D. The pressure of hydraulic oil to the motor driving the cargo pump is designed in such a way that, the pressure can run the pump at 75% of the capacity
Answer: B — The pressure of hydraulic oil to the motor driving the cargo pump is designed in such a way that, the pump runs at the optimum speed
In a Framo hydraulic system the hydraulic pressure supplied to the cargo pump motor is limited so that the pump runs at its optimum speed. Because the drive pressure is controlled, the pump cannot be driven beyond its design load and overloading is prevented.

14. Normally how much hydraulic oil is required to run the Framo portable pump?

  • A. 360 litres per min
  • B. 250 litres per min
  • C. 140 litres per min
  • D. 90 litres per min
Answer: C — 140 litres per min
Framo portable hydraulic pumps are typically driven by a hydraulic oil flow of around 140 litres per minute from the ship's power pack or a portable unit, according to the manufacturer's operating data.

15. Select the correct point regarding the operation of the portable pumps?

  • A. Before using portable pump, rig the pump on the deck and while pumping, lower the hose in the tank
  • B. When the liquid cargo level goes down, lower the hose accordingly, keeping the rigged pump on the deck
  • C. Make sure that the portable pump is completely submerged and lowered till the bottom of the tank and then start the pumping operation
  • D. Ensure that only the lower half of the pump is submerged and is lowered as the cargo level falls.
Answer: D — Ensure that only the lower half of the pump is submerged and is lowered as the cargo level falls.
A portable submersible pump should be lowered so that it is partly submerged and then lowered progressively as the cargo level falls. This keeps the pump inlet immersed, avoids overloading and prevents the pump resting on the tank bottom and drawing sediment.

16. What is the pressure of the hydraulic oil in the return side after running the hydraulic motor?

  • A. Around 3 Bar
  • B. Around 10 bar
  • C. Around 15 bar
  • D. Above 15 bar
Answer: A — Around 3 Bar
In a Framo hydraulic circuit the return line from the hydraulic motor operates at a low pressure of around 3 bar, sufficient to return oil to the tank and keep a positive pressure on the motor return side.

17. Normally what is the discharge capacity of Framo portable pumps?

  • A. 150 cubic meter per hour
  • B. 100 cubic meter per hour
  • C. 70 cubic meter per hour
  • D. 200 cubic meter per hour
Answer: C — 70 cubic meter per hour
Framo portable hydraulic cargo pumps typically have a discharge capacity of about 70 cubic metres per hour, which makes them suitable for emergency transfers and stripping rather than bulk discharge.

18. In a centrifugal pump:

  • A. The discharge side has a negative pressure.
  • B. The fluid moves in a direction opposite to the impeller.
  • C. The fluid moves in the same direction as the impeller.
  • D. The width of the discharge pipeline decreases outwards.
Answer: C — The fluid moves in the same direction as the impeller.
In a centrifugal pump the liquid is carried round by the impeller vanes and thrown outward in the same direction of rotation, gaining velocity that is converted to pressure in the volute casing.

19. Where is cofferdam in Framo pumps?

  • A. On the cargo pump side of the seal
  • B. On the hydraulic motor side of the seal
  • C. On both pump and motor side of the seal
  • D. Not on the pump end or the motor end
Answer: C — On both pump and motor side of the seal
In a Framo submerged pump a cofferdam separates the cargo seal from the hydraulic oil seal, so it lies on both the pump and motor side of the seals. Any leakage of cargo or hydraulic oil collects in the cofferdam and is detected by purging.

20. Bernoulli’s principle states that:

  • A. pressure (P) x height (H) is a constant
  • B. height (H) x velocity (V) is a constant
  • C. pressure (P) x velocity (V) is a constant
  • D. pressure (P) x density (D) is a constant
Answer: C — pressure (P) x velocity (V) is a constant
Bernoulli's principle relates pressure and velocity in a flowing fluid: when velocity increases, static pressure decreases, so pressure and velocity energy together remain constant along a streamline. The bank expresses this relationship between pressure and velocity.

21. How the speed of the portable pump can be varied?

  • A. Portable pump speed cannot be varied
  • B. Using the flow control valve of the main cargo pump
  • C. By varying the speed of the feed pump
  • D. The portable pump is always rigged with its own flow control valve which is used for speed variation
Answer: D — The portable pump is always rigged with its own flow control valve which is used for speed variation
A portable hydraulic pump is rigged with its own hydraulic flow control valve. Adjusting this valve changes the hydraulic oil flow to the motor and therefore the pump speed and output.

22. What kind of pumps can move extremely thick fluids like sludge without clogging ?

  • A. Rotary vane pumps
  • B. Reciprocating pumps
  • C. Deep well pumps
  • D. Screw pumps
Answer: D — Screw pumps
Screw pumps are positive displacement rotary pumps that move fluid smoothly along the meshing screw cavities with low shear, so they can handle very viscous fluids such as sludge and heavy oils without clogging.

23. What is the pressure of the hydraulic oil in the inlet side for running the hydraulic motor?

  • A. Around 50 Bar
  • B. Around 170 bar
  • C. Around 100 bar
  • D. Around 25 bar
Answer: B — Around 170 bar
In a Framo hydraulic system the supply pressure to the cargo pump hydraulic motor is typically around 170 bar at full load, as given in the manufacturer's operating data.

24. The reciprocating pump creates a suction effect when there is a

  • A. decrease in pressure
  • B. increase in pressure
  • C. no change in pressure
  • D. decrease or an increase in pressure
Answer: A — decrease in pressure
On the suction stroke of a reciprocating pump the piston moves to increase cylinder volume, creating a pressure drop below atmospheric. The higher pressure on the liquid surface pushes liquid into the cylinder, producing the suction effect.

25. What happens within the hull girder due to the development of bending moment due to stresses on hull are the following: find a statement that provides structural strength to the hull girder

  • A. A bending stress is developed at every transverse section of the hull.
  • B. The universal expression for bending stress is:bending stress = (bendingmoment)/(section modulus)
  • C. Maximum bending moment at the midship means that the bending stress at the midships will be the maximum, and hence the deciding factor for the design.
  • D. The bending stress at the midship is kept within safe limits by designing the midship section with a sufficient section modulus.
Answer: D — The bending stress at the midship is kept within safe limits by designing the midship section with a sufficient section modulus.
Bending stress equals bending moment divided by section modulus, and the bending moment is usually largest amidships. Designing the midship section with sufficient section modulus keeps the stress within safe limits, which is what provides the hull girder with its structural strength.

26. When doing an enclosed space rescue, the person in charge must co- ordinate the rescue:

  • A. From inside the space
  • B. From the Bridge
  • C. From outside the space
  • D. From the Engine Control Room
Answer: C — From outside the space
The person in charge of an enclosed space rescue must remain outside the space to coordinate the team, maintain communication with the rescuers and the bridge, and control the operation. Entering would remove the overall control and add another person at risk.

27. Select the correct statement.

  • A. A tanker with a defective oil discharge monitoring and control system may undertake one ballast voyage before proceeding to a repair port, under certain circumstances.
  • B. A tanker with a defective oil discharge monitoring and control system cannot undertake a ballast voyage.
  • C. A tanker with a defective oil discharge monitoring and control system need only repair the system before the next annual MARPOL survey of the IOPP Certificate.
  • D. A tanker with a defective oil discharge monitoring and control system may undertake one ballast voyage and one loaded voyage before proceeding to a repair port, provided permission is taken from the relevant authority.
Answer: A — A tanker with a defective oil discharge monitoring and control system may undertake one ballast voyage before proceeding to a repair port, under certain circumstances.
MARPOL Annex I regulation 31 and the associated guidelines allow a tanker with a failed ODME to undertake one ballast voyage before proceeding to a repair port, subject to the Administration's conditions, provided the failure is recorded in the Oil Record Book.

28. Control of Entry into Enclosed Spaces; identify the most important statement which is a key measure to safe entry

  • A. Prior to entry into an enclosed space, a risk assessment should be completed to identify the potential hazards and to determine the safeguards to be adopted.
  • B. The safe working practice should be documented and approved by the responsible officer before being countersigned by the master, who confirms that the practice is safe and in compliance with the ship’s Safety Management System.
  • C. The permit, or other enabling document, should be sighted and completed by the person entering the space, prior to entry.
  • D. The controls required for safe entry vary with the task being performed and the potential hazards identified during the risk assessment.
Answer: A — Prior to entry into an enclosed space, a risk assessment should be completed to identify the potential hazards and to determine the safeguards to be adopted.
The key measure for safe enclosed space entry, as set out in IMO Resolution A.1050(27) and ISGOTT, is a risk assessment completed before entry to identify the hazards and determine the safeguards, such as ventilation, atmosphere testing, PPE and rescue arrangements.

29. Lung inflammation will cause:

  • A. Breathlessness and drowsiness
  • B. Breathlessness and confusion
  • C. Breathlessness and a dry cough
  • D. Breathlessness and slurred speech
Answer: C — Breathlessness and a dry cough
Inflammation of the lungs, for example from inhaling irritant or toxic cargo vapours, typically causes breathlessness and a dry cough as the airways become irritated, as described in the IMO Medical First Aid Guide.

30. The Convention that allows States to intervene in a pollution incident at sea is the

  • A. MARPOL Convention
  • B. SOLAS Convention
  • C. CLC Convention
  • D. Intervention Convention
Answer: D — Intervention Convention
The International Convention relating to Intervention on the High Seas in Cases of Oil Pollution Casualties, 1969, gives coastal States the right to take measures on the high seas to prevent, mitigate or eliminate grave and imminent danger of pollution from a maritime casualty.

Set 6 — 30 CHEMCO exit exam questions with answers

1. Emergency alarm signals are provided on tankers in case of the following; which one of these alarms will be of major importance on a double-hull tankship with empty ballast tanks?

  • A. High concentration of toxic or flammable vapors
  • B. A discharge in engine-room or pumproom
  • C. When level of oxygen in inert gas entering tanks exceeds 5%
  • D. High level of oil residues in overboard discharge
Answer: A — High concentration of toxic or flammable vapors
On a double-hull tanker the empty ballast tanks surround the cargo tanks, so any leak from the cargo tanks can create toxic or flammable vapours in these spaces. SOLAS II-2 regulation 4.5.7 requires gas sampling of double-hull spaces, making high vapour concentration alarms the most important here.

2. While in port, if a fire occurs on board ship, support available from the shore includes the following; which one, in your opinion, makes the most important distinction for a shipboard fire?

  • A. Assistance from the fire brigade – experienced manpower and firefighting equipment.
  • B. Medical services of shore hospitals including ambulances with stretchers and paramedics in attendance, helicopters, etc.
  • C. Transportation for evacuating personnel from ship that are non-essential for firefighting.
  • D. Catering services where ship’s resources are restricted by the fire.
Answer: A — Assistance from the fire brigade – experienced manpower and firefighting equipment.
The most significant shore support for a shipboard fire in port is the fire brigade, which brings experienced firefighters and additional equipment beyond the ship's own resources. Medical, evacuation and catering support are useful but secondary to fighting the fire itself.

3. Typical Locations for High Sensitivity to Fatigue Failure The following areas are considered to be prone to fatigue failure on double hull oil tankers: which one is the most common

  • A. Side shell area below the load and ballast waterlines. These areas are subjected to the highest cycle loading through the ship’s life due to the passage of waves along the side of the ship.
  • B. Deck plating at connection to primary supporting members.
  • C. Connection between transverse bulkheads to the upper and lower bulkhead stools.
  • D. Connection between lower hopper sloping plating and inner bottom plating.
Answer: A — Side shell area below the load and ballast waterlines. These areas are subjected to the highest cycle loading through the ship’s life due to the passage of waves along the side of the ship.
On double-hull tankers the side shell area between the ballast and load waterlines experiences the highest number of cyclic loads from waves passing along the ship throughout its life, making it the most common location for fatigue cracking at longitudinal end connections.

4. Safeguards for Enclosed Space Entry; Before allowing access to the space, the responsible officer should ensure, amongst other things, that: identify the most important of all the elements

  • A. The personal protective equipment to be used by people entering the enclosed space must be prescribed.
  • B. Approved safety torches.
  • C. Approved UHF radio.
  • D. Personal gas detector or an area gas detector and alarm.
Answer: A — The personal protective equipment to be used by people entering the enclosed space must be prescribed.
Before entry the responsible officer must ensure the personal protective equipment for those entering is prescribed according to the hazards identified. This underpins the other safeguards and follows IMO Resolution A.1050(27) and ISGOTT enclosed space entry guidance.

5. In case of a collision, the following, amongst other steps are considered as a general plan of action; which one will be a priority in case of an underwater hull damage?

  • A. Assessing possible pollution due to rupture of fuel and or cargo (oil or chemical) tanks;
  • B. Taking corrective action to minimize the quantum of pollution; reporting the incident.
  • C. Assembling the emergency party.
  • D. Preparing for or implementing fire-fighting measures (in the event of a fire).
Answer: A — Assessing possible pollution due to rupture of fuel and or cargo (oil or chemical) tanks;
With underwater hull damage after a collision the priority is to assess possible pollution from ruptured fuel or cargo tanks, so that the extent of damage and spillage is known and the SOPEP or SMPEP response can be planned, along with stability and damage control.

6. The Medical First Aid Guide is published by the:

  • A. International Maritime Organisation
  • B. World Health Organisation
  • C. United Nations
  • D. International Labour Organisation
Answer: A — International Maritime Organisation
The Medical First Aid Guide for Use in Accidents Involving Dangerous Goods (MFAG) is published by IMO (developed jointly with WHO and ILO).

7. Find a statement that in your opinion, is the most critical in a grounding incident?

  • A. Grounding can cause loss of human life.
  • B. Grounding can cause harmful environmental impact, especially in the case where large tanker ships are involved.
  • C. Grounding can cause financial consequences to local communities close to the accident.
  • D. Grounding can cause financial consequences to ship- owners, due to ship loss or penalties.
Answer: A — Grounding can cause loss of human life.
The loss of human life is the most critical consequence of any grounding, because safety of life is the overriding priority under SOLAS and the ISM Code. Environmental and financial impacts are serious but secondary.

8. Safeguards for Enclosed Space Entry; Before allowing access to the space, the responsible officer should ensure, amongst other things, that: identify the most important of all the elements

  • A. A rescue harness, complete with lifeline, is ready for immediate use at the entrance to the space.
  • B. Fully charged safety torch is ready for immediate use at the entrance to the space.
  • C. A responsible member of the crew is in constant attendance outside the enclosed space, in the immediate vicinity of the entrance and in direct contact with a responsible officer.
  • D. These persons should be trained in the actions to be taken in the event of an emergency.
Answer: C — A responsible member of the crew is in constant attendance outside the enclosed space, in the immediate vicinity of the entrance and in direct contact with a responsible officer.
A responsible crew member in constant attendance at the entrance, in direct contact with the responsible officer, is essential so that any emergency inside is detected immediately and the alarm raised. This attendant is required by IMO Resolution A.1050(27) and ISGOTT.

9. Statements on Boiler: identify a statement that supports the use of a watertube boiler with a superheater in many tanker vessels?

  • A. The boiler on a tanker vessel is equally important as the main propulsion engines
  • B. On a large oil tanker, the fuel consumption in the boiler could be as high as 2/3rd of the engines.
  • C. Without having steam at superheated condition, you may not be able to operate the cargo pump turbines efficiently and safely
  • D. Without having steam, you may not be able to maintain the oil temperatures correctly within the cargo tanks for discharging.
Answer: C — Without having steam at superheated condition, you may not be able to operate the cargo pump turbines efficiently and safely
Many tankers have steam turbine-driven cargo pumps, which need superheated steam to operate efficiently and safely without condensation and erosion in the turbine. This is why watertube boilers with superheaters are fitted on such vessels.

10. Which function is NOT provided by the scrubber of an inert gas system?

  • A. Cools the inert gas.
  • B. Removes particulate matter like soot.
  • C. Maintains gas pressure in the tanks.
  • D. Removes chemical impurities from the gas.
Answer: C — Maintains gas pressure in the tanks.
The IG scrubber cools the flue gas, removes soot and particulate matter, and washes out sulphur dioxide and other chemical impurities. It does not maintain gas pressure in the tanks; that is done by the blowers and the pressure regulating valve.

11. Introducing inert gas into a tank already inert with the object of further reducing the oxygen or hydrocarbon content to prevent combustion if air enters the tank is called

  • A. purging
  • B. gas freeing
  • C. gas dispersion
  • D. bonding
Answer: A — purging
ISGOTT defines purging as introducing inert gas into a tank that is already inert, to further reduce the oxygen and hydrocarbon content so that when air is later introduced for gas freeing, no part of the tank atmosphere passes through the flammable range.

12. Typically nitrogen contained in inert gas generated from boiler flue gas, at the scrubber outlet is

  • A. 50%
  • B. 60%
  • C. 70%
  • D. 83%
Answer: D — 83%
Typical inert gas from boiler flue gas at the scrubber outlet consists of about 83% nitrogen, 12 to 14% carbon dioxide, 2 to 4% oxygen, with small amounts of water vapour and sulphur dioxide, as given in ISGOTT and the IMO IG guidelines.

13. Which statement about inert gas pressures in a cargo tank is TRUE?

  • A. The pressures of the inert gas in the tank may create excessive pressure at the pump while discharging.
  • B. Gas pressures should be maintained at the highest permissible level throughout the discharging process.
  • C. High gas pressures may cause pyrophoric oxidation in the tank.
  • D. High gas pressures may cause loss of suction when stripping.
Answer: B — Gas pressures should be maintained at the highest permissible level throughout the discharging process.
During discharge the inert gas pressure should be kept as high as is permissible, so that as cargo is pumped out the tanks never approach a vacuum or allow air ingress. Maintaining positive pressure also helps pump suction, as recommended in ISGOTT.

14. The purpose of the deck seal in an inert gas system is to prevent

  • A. flammable vapors from entering machinery space
  • B. flue gas escaping to atmosphere
  • C. inert gas escaping to atmosphere
  • D. air entering inert gas system
Answer: A — flammable vapors from entering machinery space
The deck water seal prevents the back flow of hydrocarbon vapours from the cargo tanks through the IG main to the IG plant and the machinery space, which would otherwise create a serious fire hazard. The FSS Code chapter 15 requires it as the main non-return device.

15. After the initial cleaning of flue gas in an inert gas system the gas is passed through what device for final cleaning?

  • A. Scrubber
  • B. Demister
  • C. Deck water seal
  • D. Final filter
Answer: B — Demister
After the scrubber has cooled and washed the flue gas, it passes through a demister, which removes entrained water droplets and remaining fine particles before the gas reaches the blowers and the deck main.

16. The "flammable limits" of an atmosphere are the

  • A. two temperatures between which an atmosphere will self ignite
  • B. upper and lower percentage of vapor concentrations in an atmosphere which will burn if an ignition source is present
  • C. upper and lower pressures between which an atmosphere will not burn
  • D. two temperatures between which an atmosphere will burn if an ignition source is present
Answer: B — upper and lower percentage of vapor concentrations in an atmosphere which will burn if an ignition source is present
Flammable limits are the lower and upper percentages by volume of vapour in air between which the mixture will burn if an ignition source is present. Below the lower limit the mixture is too lean and above the upper limit too rich.

17. Flue gas is drawn from the boiler uptake and delivered to the inert gas scrubber by a:

  • A. Exhaust gas pressure from the stack
  • B. High capacity fan
  • C. Inert gas compressor
  • D. Natural aspiration
Answer: B — High capacity fan
In a flue gas IG system high capacity fans, the IG blowers, draw gas from the boiler uptake through the scrubber and deliver it under pressure to the deck main and cargo tanks. Stack pressure alone is insufficient.

18. What is the major function of the deck water seal in an inert gas system?

  • A. Relieves excessive pressures from the system.
  • B. Isolates hazardous areas from nonhazardous areas.
  • C. Prevents the flow of inert gas into closed or isolated tanks.
  • D. Removes any leftover water or soot after the gas has been scrubbed.
Answer: B — Isolates hazardous areas from nonhazardous areas.
The deck water seal forms a gas-tight barrier between the hazardous cargo area and the non-hazardous IG plant and machinery spaces, preventing back flow of hydrocarbon gas while allowing inert gas to pass forward to the tanks.

19. Inert gas systems must be capable of delivering inert gas with an oxygen content by volume in the inert gas main of not more than

  • A. 2%
  • B. 5%
  • C. 8%
  • D. 11%
Answer: B — 5%
The FSS Code chapter 15 requires the inert gas system to be capable of delivering inert gas with an oxygen content of not more than 5% by volume in the IG supply main at the required rate.

20. On a hydrocarbon flammability chart the line which extends from 0% to 21.8% oxygen, lying tangent to the flammability range, is called the

  • A. minimum oxygen content line upper threshold limit
  • B. critical displacement line
  • C. critical dilution line
  • D. upper threshold limit
Answer: C — critical dilution line
On the flammability diagram the critical dilution line runs from pure air at 21% oxygen tangent to the flammable zone. Mixtures on the inert side of this line can be diluted with air without passing through the flammable range, which is the basis of purging before gas freeing in ISGOTT.

21. The component in an inert gas system used for cleaning the gas of solid and sulfur combustion products, while simultaneously cooling the inert gas, is called the

  • A. filter
  • B. cooler
  • C. scrubber
  • D. purifier
Answer: C — scrubber
The scrubber washes the flue gas with seawater, removing soot and sulphur combustion products while simultaneously cooling the gas to near seawater temperature before it passes to the demister and blowers.

22. Inert gas systems must be capable of maintaining inert gas with an oxygen content by volume in the cargo tanks of not more than

  • A. 2%
  • B. 5%
  • C. 8%
  • D. 11%
Answer: C — 8%
SOLAS II-2 regulation 4.5.5 and the FSS Code chapter 15 require the inert gas system to maintain the atmosphere in any part of the cargo tanks at an oxygen content of not more than 8% by volume and at a positive pressure.

23. You are discharging cargo and the inert gas system is in operation to inert the tanks. The pressure in a tank being discharged starts to drop below the allowable limit. What action should you take?

  • A. Cut in another IG fan to increase gas flow.
  • B. Open the pressure control valve until the pressure increases.
  • C. Open the tank isolation valve to the fully open position.
  • D. Reduce the pumping rate.
Answer: B — Open the pressure control valve until the pressure increases.
If tank pressure falls during discharge, the pressure control valve should be opened to increase the flow of inert gas into the deck main and restore positive pressure. If this is insufficient, the discharge rate must then be reduced.

24. The fresh air intake of the inert gas system

  • A. prevents the flue gas from falling below an oxygen content of 3%
  • B. allows the inert gas piping to be used for gas freeing the tanks
  • C. opens when there is excessive vacuum on the deck water seal
  • D. enables outside air to mix with and to cool the hot flue gasses
Answer: B — allows the inert gas piping to be used for gas freeing the tanks
The fresh air intake allows the IG blowers to deliver fresh air through the IG main and distribution piping to the cargo tanks, so the same system can be used for gas freeing after purging, as provided in FSS Code chapter 15.

25. What is the maximum oxygen content below which flaming combustion will no longer occur?

  • A. 5%
  • B. 8%
  • C. 10%
  • D. 12%
Answer: B — 8%
SOLAS and the FSS Code take 8% oxygen by volume as the level below which a tank atmosphere is considered inert and flaming combustion of hydrocarbon gas will not occur, which includes a safety margin below the theoretical 11% limit given in ISGOTT.

26. In which of the following conditions, the IG blower fans should shut down automatically?

  • A. Oxygen content above 8%
  • B. Low water level in deck seal
  • C. Low water level in the scrubber tower
  • D. High scrubber water level
Answer: D — High scrubber water level
The FSS Code chapter 15 requires the IG blowers and gas regulating valve to shut down automatically on high water level in the scrubber, to prevent water being carried over into the blowers and deck main, as well as on low scrubber water supply.

27. What type of liquid is used in the liquid P/V breaker?

  • A. Hydraulic oil
  • B. Water-antifreeze mixture
  • C. Distilled water
  • D. Oil from the cargo
Answer: B — Water-antifreeze mixture
A liquid-filled P/V breaker is filled with a water and antifreeze mixture, typically glycol, so that the liquid seal does not freeze in cold weather and continues to protect the tanks against excessive pressure or vacuum.

28. What is the maximum percent of oxygen, by volume, allowed to be maintained in the cargo tanks prior to the commencement of crude oil tank washing?

  • A. 5%
  • B. 8%
  • C. 10%
  • D. 12%
Answer: B — 8%
MARPOL Annex I and the IMO COW specifications require the oxygen content of each tank to be crude oil washed to be not more than 8% by volume, and the tank to be at positive pressure, before washing begins.

29. Checks to be done, amongst others, before and during COW are listed; identify the most important safety check

  • A. When carrying out crude oil washing during cargo discharge, the Master should inform the terminal competent authority 24 hours before commencement (or other ship when ship-to-ship transfer is involved)
  • B. The Oxygen analyzing equipment to be tested and working satisfactorily
  • C. Inert gas in tank to be checked – (Oxygen to be less than 8%), IG pressure to be satisfactory (positive pressure)
  • D. All hydrant valves on the tank washing line to be shut
Answer: C — Inert gas in tank to be checked – (Oxygen to be less than 8%), IG pressure to be satisfactory (positive pressure)
The most important safety check before and during COW is confirming that the tank to be washed is inerted with oxygen below 8% by volume and at positive IG pressure, as required by MARPOL Annex I regulation 35 and the COW specifications, since washing generates static electricity.

30. Concurrent COW with cargo discharge: identify the precaution for the Concurrent COW method for use

  • A. COW concurrent method utilizes the crude oil stream being discharged, together with its associated back pressure, to supply the COW pipeline with crude oil.
  • B. COW concurrent method can be achieved either by a "bleed-off' system from the main crude oil discharge pipelines for supply to the COW pipeline or by separate supply using a designated cargo pump.
  • C. COW concurrent method: The normal minimum back pressure required for the operation of the COW guns is 8 kg/cm2.
  • D. COW concurrent method: If supply is achieved by the bleed-off from the bulk discharge, then sufficient back pressure has to be maintained at all times.
Answer: C — COW concurrent method: The normal minimum back pressure required for the operation of the COW guns is 8 kg/cm2.
For concurrent COW the washing machines need a sufficient back pressure to work effectively, and the normal minimum required at the COW guns is about 8 kg/cm2. If this pressure is not maintained the washing will be ineffective.

Set 7 — 30 CHEMCO exit exam questions with answers

1. When evacuating a seaman by helicopter lift, the vessel should be__________.

  • A. stopped with the wind dead ahead
  • B. stopped with the wind on the beam
  • C. underway with the wind 30° on the bow
  • D. underway on a course to provide no apparent wind
Answer: C — underway with the wind 30° on the bow
IAMSAR guidance is for the ship to be underway at a steady speed with the wind about 30° on the bow, normally the port bow when hoisting from aft, so the helicopter can hover into the wind with good visibility and minimal turbulence from the superstructure.

2. A rescue helicopter's hoist area should have a radius of at least __________.

  • A. 6 feet of clear deck
  • B. 10 feet of clear deck
  • C. 25 feet of clear deck
  • D. 50 feet of clear deck
Answer: D — 50 feet of clear deck
IAMSAR guidance and the USCG bank call for a clear hoisting area of at least 50 feet radius, free of masts, rigging and loose objects, so the helicopter's winch and rotor clearance are safe.

3. Usually the most gentle way of riding out a severe storm on a larger vessel is__________.

  • A. head on at slow speeds
  • B. hove to
  • C. running before the seas
  • D. to rig a sea anchor
Answer: C — running before the seas
Running before the seas generally gives the gentlest motion in a severe storm, since the relative speed of the waves is reduced. It has risks of pooping and broaching if speed is not managed carefully.

4. Your vessel is off a lee shore in heavy weather and laboring. Which action should you take?

  • A. Put the sea and wind about two points on either bow and reduce speed.
  • B. Heave to in the trough of the sea.
  • C. Put the sea and wind on either quarter and proceed at increased speed.
  • D. Put the bow directly into the sea and proceed at full speed.
Answer: A — Put the sea and wind about two points on either bow and reduce speed.
Off a lee shore the vessel must keep its head to the weather and avoid being set down. Putting the wind and sea about two points on either bow with reduced speed lessens pounding and labouring while maintaining steerage and holding off the shore.

5. You are steaming in a heavy gale and find it necessary to heave to. Under most circumstances, this is best done by __________.

  • A. stopping the engines and drifting beam to the seas
  • B. going slow astern and taking the seas on the quarter
  • C. taking the sea fine on the bow and reducing the speed to the minimum to hold that position
  • D. maintaining speed and taking the sea broad on the bow
Answer: C — taking the sea fine on the bow and reducing the speed to the minimum to hold that position
Heaving to in a heavy gale is best done by bringing the sea fine on the bow and reducing speed to the minimum that holds that heading. This reduces pounding and keeps the ship from falling into the trough.

6. Snow has obliterated surface features and the sky is covered with uniform, altostratus clouds. There are no shadows and the horizon has disappeared. What is this condition called?

  • A. Ice blink
  • B. Whiteout
  • C. Water sky
  • D. Aurora reflection
Answer: B — Whiteout
A whiteout occurs over snow or ice under a uniform overcast sky, when diffuse light removes all shadows and contrast so that surface features and the horizon disappear, making judgement of distance and depth impossible.

7. A vessel is wind rode when it is __________.

  • A. at anchor and heading into the wind
  • B. backing into the wind
  • C. carrying lee rudder
  • D. necessary to apply a leeway correction to the course
Answer: A — at anchor and heading into the wind
A vessel is wind rode when lying at anchor with its head into the wind, because the wind has a stronger effect on its heading than the current. A tide rode ship lies to the current.

8. When evacuating a seaman by helicopter lift, which course should the ship take?

  • A. Downwind so that the apparent wind is close to nil.
  • B. A course that will keep a free flow of air, clear of smoke, over the hoist area.
  • C. A course that will have the hoist area in the lee of the superstructure.
  • D. With the wind dead ahead because the helicopter is more maneuverable when going into the wind.
Answer: B — A course that will keep a free flow of air, clear of smoke, over the hoist area.
During helicopter hoisting the ship should steer a course that gives a free flow of air over the hoist area, clear of funnel smoke and turbulence, so the pilot has good visibility and stable hover conditions, as advised in IAMSAR Volume III.

9. When the gyro-pilot is used for steering, what control is adjusted to compensate for varying sea conditions?

  • A. Rudder control
  • B. Sea control
  • C. Lost motion adjustment
  • D. Weather adjustment
Answer: D — Weather adjustment
The weather adjustment control on a gyro-pilot sets a dead band so that the autopilot does not respond to small yaws caused by sea conditions. This reduces unnecessary rudder movement and wear in heavy weather.

10. What types of mooring lines are used for larger tankers?

  • A. Ropes with high elastic elongation properties
  • B. Ropes with low plastic elongation properties
  • C. Ropes with high modulus of rigidity
  • D. Strain hardened ropes
Answer: C — Ropes with high modulus of rigidity
OCIMF Mooring Equipment Guidelines require large tankers to use mooring lines with low elongation, such as steel wire or high modulus synthetic fibre ropes, so the ship's movement at the berth is limited and loads are shared evenly between lines.

11. Normally Brakes must be ___________tightened to achieve the required holding capacity of the line's Minimum Breaking Load.

  • A. 30%
  • B. 50%
  • C. 60%
  • D. 75%
Answer: C — 60%
OCIMF Mooring Equipment Guidelines recommend that winch brakes be set to hold 60% of the minimum breaking load of the line, so the brake renders before the line parts and protects the rope and fittings.

12. ‘It is preferred to have all mooring lines of the same material and construction’ This is strictly followed due to

  • A. The load on all the mooring lines should be same
  • B. To avoid undue stress on mooring lines
  • C. To increase the life of the mooring lines
  • D. To avoid compressive over loading of any of the mooring ropes
Answer: B — To avoid undue stress on mooring lines
Lines of different material or construction stretch differently under load, so stiffer lines take a disproportionate share and may be overstressed. Using the same material and construction ensures loads are shared evenly and avoids undue stress on individual lines, as advised by OCIMF.

13. How to prevent failure of the mooring and other components in the mooring system during large swell conditions?

  • A. By attaching fibre tails in the mooring ropes
  • B. By attaching fibre tails on the ends in the mooring ropes
  • C. By attaching fibre tails on the sides of the mooring ropes
  • D. By attaching fibre tails perpendicular to the mooring ropes
Answer: B — By attaching fibre tails on the ends in the mooring ropes
Fitting synthetic fibre tails at the ends of steel wire or HMSF mooring lines adds elasticity, absorbing dynamic loads from swell and ship motion, which prevents failure of the lines and fittings, as recommended in the OCIMF Mooring Equipment Guidelines.

14. Mooring winch brakes should be tested at regular intervals, not exceeding _____. Choose the correct period from below?

  • A. 18 months
  • B. 12 months
  • C. 24 months
  • D. 30months
Answer: B — 12 months
OCIMF Mooring Equipment Guidelines recommend that the holding capacity of mooring winch brakes be tested at regular intervals not exceeding 12 months, and after any event that could affect brake performance.

15. What is the possible alternate for winch-stowed steel wire ropes for the mooring of large tankers at terminals?

  • A. Low Modulus synthetic fibre ropes
  • B. High Modulus synthetic wire ropes
  • C. High Modulus synthetic fibre ropes
  • D. Low Modulus nylon ropes
Answer: C — High Modulus synthetic fibre ropes
High modulus synthetic fibre ropes such as HMPE or aramid have very low elongation similar to steel wire but are far lighter and easier to handle, so they are the accepted alternative to winch-stowed wires on large tankers under OCIMF guidance.

16. Why mooring wires used by large tankers are normally stored on self- stowing mooring winches?

  • A. Self - stowing winches are convenient
  • B. Weight and size make manual handling difficult
  • C. Self – stowing winches have brakes
  • D. Self-stowing winches are reliable
Answer: B — Weight and size make manual handling difficult
Steel wire mooring ropes on large tankers are very heavy and of large diameter, so manual handling would be difficult and dangerous. They are therefore kept on self-stowing winch drums for safe and efficient handling.

17. What is IOPC fund?

  • A. International Oil Pollution Compensation Funds
  • B. International Oil tanker Pollution Compensation Funds
  • C. International Oil and hazardous chemical Compensation Funds
  • D. International Oil Pollution Compensatory Funds
Answer: A — International Oil Pollution Compensation Funds
The IOPC Funds are the International Oil Pollution Compensation Funds, established under the 1971 and 1992 Fund Conventions, which provide compensation for oil pollution damage from tankers beyond the shipowner's liability under the CLC.

18. In March 1989, Exxon Valdez ran aground in Alaska (U.S.) spilling approximately 40,000 tons of crude oil into the sea, causing serious environmental damage. What was the outcome legislation that followed the disaster?

  • A. CLC Convention and the Fund Convention
  • B. Oil Pollution Act of 1990 (OPA 90)
  • C. Bunker Convention
  • D. LLMC Convention
Answer: B — Oil Pollution Act of 1990 (OPA 90)
The Exxon Valdez grounding in Prince William Sound in 1989 led the United States to enact the Oil Pollution Act of 1990, which introduced vessel response plans, double hull requirements and greater liability for tanker owners.

19. What does LLMC Convention stand for?

  • A. Convention on Limitations of Liabilities for Maritime Claims
  • B. Conventionon Limited Liabilities for Marine Claims
  • C. Convention on Liabilities limited for Marine Claims
  • D. Convention on Liabilities with Limits for Maritime Claims
Answer: A — Convention on Limitations of Liabilities for Maritime Claims
LLMC is the Convention on Limitation of Liability for Maritime Claims, 1976, which allows shipowners and salvors to limit their liability for certain claims to amounts based on the ship's tonnage.

20. The meaning of the CLC Convention is,

  • A. Civil Liability Convention for Oil Pollution Damage
  • B. Civil Liability Convention for Damage from NLS
  • C. Civil Liability Convention for Air Pollution
  • D. Civil Liability Convention for pollution by Sewage
Answer: A — Civil Liability Convention for Oil Pollution Damage
CLC is the International Convention on Civil Liability for Oil Pollution Damage, 1969 and its 1992 Protocol, which places strict liability on the tanker owner for oil pollution damage and requires compulsory insurance.

21. Under which operation the volumetric cargo losses are more?

  • A. During Tank to tank transfer onboard
  • B. During Ship to shore transfer
  • C. During COW
  • D. During circulation inside the same Tank onboard
Answer: B — During Ship to shore transfer
Volumetric cargo losses are greatest during ship to shore transfer because of evaporation of light ends, vapour release, line contents, measurement differences and clingage. This is the stage where most transit loss claims arise.

22. In spite of using clean sample bottles to acquire individual samples from each level (ie top, middle and bottom of each of the ship’s tanks) and clearly labelled for density calculation, why the final result may not provide the correct density value?

  • A. Due to temperature variations
  • B. Due to Viscosity variations
  • C. Due to the loss of volatile fractions to atmosphere
  • D. Due to changes in Emulsion
Answer: C — Due to the loss of volatile fractions to atmosphere
Even with clean, labelled bottles, lighter volatile fractions evaporate during sampling, handling and storage, which changes the composition of the sample and makes the measured density unrepresentative of the cargo.

23. What can be the probable causes for a gross mismatch between ship and shore oil figures?

  • A. Ullages incorrectly measured, Tanks filled but not taken into account, The contents of pipelines not allowed for, Cargo mistakenly loaded on top of ballast and Cargo lost in the shore installation.
  • B. Incorrectly measured Ullages/ Temperatures/ densities, Tanks filled but not taken into account, The contents of pipelines not allowed for, Incorrect temperatures or densities, Cargo mistakenly loaded on top of ballast and Cargo lost in the shore installation.
  • C. Ullages incorrectly measured, Tanks filled but not taken into account, The contents of pipelines not allowed for, Incorrect temperatures or densities, and Cargo lost in the shore installation.
  • D. Ullages incorrectly measured, The contents of pipelines not allowed for, Incorrect temperatures or densities, Cargo mistakenly loaded on top of ballast and Cargo lost in the shore installation.
Answer: B — Incorrectly measured Ullages/ Temperatures/ densities, Tanks filled but not taken into account, The contents of pipelines not allowed for, Incorrect temperatures or densities, Cargo mistakenly loaded on top of ballast and Cargo lost in the shore installation.
Gross ship and shore discrepancies usually result from errors in ullage, temperature or density measurement, tanks filled but not accounted for, pipeline contents not allowed for, cargo loaded on top of ballast, and losses within the shore installation. The fullest list covers all these causes.

24. Normally which one will affect the final cargo measurement more when there is a 0.1% variation in their respective reading?

  • A. Ullage measurement
  • B. Density measurement
  • C. Temperature measurement
  • D. Water in cargo measurement
Answer: C — Temperature measurement
Temperature errors have a large effect on cargo calculation because the volume correction factor depends on temperature, so a small error in temperature reading changes the standard volume of the entire cargo. The bank treats temperature as the most sensitive measurement.

25. Why water finding pastes or electronic tape interface reading to measure water in the take do not give accurate results?

  • A. Due to emulsion
  • B. Due to temperature difference
  • C. Due temperature and density difference
  • D. Due to differences in Viscosity
Answer: A — Due to emulsion
Water finding paste and interface probes can give inaccurate results when there is an emulsion layer between oil and free water, because there is no clear interface to detect, so the water cut may be misread.

26. What are all the Claims/ disputes you can successfully defend if some records if maintained on board properly?

  • A. Shortage, contamination and demurrage / dispatch disputes.
  • B. Shortage, performance claims, and demurrage / dispatch disputes.
  • C. Shortage, contamination, performance claims, and demurrage / dispatch disputes.
  • D. Contamination performance claims, and demurrage / dispatch disputes.
Answer: B — Shortage, performance claims, and demurrage / dispatch disputes.
Properly maintained records such as ullage reports, pumping logs, notices of protest and speed and consumption data enable the ship to defend shortage claims, performance claims and demurrage or despatch disputes.

27. What are the factors that may affect the calculation of OBQ value?

  • A. Residues on tank floors, the age of the vessel and previous cargoes carried.
  • B. Residues on tank floors and previous cargoes carried.
  • C. Residues on tank floors and structures, and previous cargoes carried.
  • D. Residues on tank floors and structures, and these will vary with the age of the vessel and previous cargoes carried.
Answer: D — Residues on tank floors and structures, and these will vary with the age of the vessel and previous cargoes carried.
On board quantity depends on residues remaining on tank floors and structures, which vary with the age of the vessel, the condition of its tanks and coatings, and the previous cargoes carried.

28. What are all the cargo measurement issues creep up when liquid cargo is measured for volume calculations

  • A. Ullage, listing of vessel, sea conditions, and temperature of cargo
  • B. Ullage, listing of vessel, sea conditions, water in cargo and temperature of cargo
  • C. Ullage, listing of vessel, sea conditions, water in cargo, density and temperature of cargo
  • D. Ullage, listing of vessel, water in cargo, density and temperature of cargo
Answer: B — Ullage, listing of vessel, sea conditions, water in cargo and temperature of cargo
Volume measurement of liquid cargo is affected by ullage readings, list and trim of the vessel, sea conditions, water in the cargo and cargo temperature. These factors must all be corrected for to obtain accurate gross and net volumes.

29. What can be the ship’s defence if the Oil discharged from board is more than the B/L figure?

  • A. Water seepage into cargo onboard the ship
  • B. The onboard quantity (OBQ) prior to loading has not been taken into consideration
  • C. The cargo has been slightly over heated to reduce viscosity
  • D. The flow meter on the shore at the discharge port is not working well
Answer: B — The onboard quantity (OBQ) prior to loading has not been taken into consideration
If the ship discharges more than the bill of lading figure, the likely explanation is that the on board quantity before loading was not taken into account. Including the OBQ in the vessel experience factor and calculations reconciles the difference.

30. What are all the normal defence for the Ship, in case of an ‘Oil Shortage’

  • A. To prove that all the cargo has been discharged with no (ROB).
  • B. To prove that there was no significant in-transit loss
  • C. To prove that the ship tank calibrations are more accurate than the shore tank calibrations.
  • D. To prove that the shore’s flow meter is wrong
Answer: A — To prove that all the cargo has been discharged with no (ROB).
The ship's primary defence against an oil shortage claim is to prove that all cargo was discharged and no cargo remained on board, supported by dry tank certificates and ROB measurements witnessed by the surveyor.

Set 8 — 30 CHEMCO exit exam questions with answers

1. Why is it the potential for volumetric losses is greater where COW is performed?

  • A. During COW, the cargo is being formed into a low pressure spray and completely atomised
  • B. During COW, the cargo is being formed into a high pressure spray and completely atomised
  • C. During COW, the cargo is being formed into a high pressure spray and partially atomised
  • D. During COW, the cargo is being formed into a low pressure spray and partially atomised
Answer: C — During COW, the cargo is being formed into a high pressure spray and partially atomised
During COW the crude oil is delivered through washing machines as a high pressure jet, which becomes partially atomised. This releases light hydrocarbon fractions as vapour, increasing the potential for volumetric loss.

2. When the sea conditions are not exactly calm, how will you make sure that the ullage measurement reading is closer to accurate?

  • A. For each tank, take 5 ullage measurements and average, then apply trim correction
  • B. For each tank, take 3 ullage measurements and average, then apply trim correction
  • C. For each tank, take 5 ullage measurements, leave the maximum and minimum values, then average the remaining three values and apply trim correction
  • D. For each tank, take 5 ullage measurements, leave the maximum and minimum values, then average the remaining three values.
Answer: C — For each tank, take 5 ullage measurements, leave the maximum and minimum values, then average the remaining three values and apply trim correction
In a seaway the liquid surface moves, so several readings are taken and the extreme high and low values are discarded to remove the worst wave effects. The remaining three readings are averaged and the trim correction is then applied to obtain a representative corrected ullage for cargo calculation.

3. Select the appropriate sentence from below describing the ‘Oil Shortage claim’

  • A. The discrepancy between what has been received on board and what has been discharged from the ship
  • B. The discrepancy between what has been received on board as per B/L and what has been discharged from the ship
  • C. The discrepancy between the quantity of cargo as stated in the B/L and the out turn quantity as calculated in the discharge port.
  • D. The discrepancy between the quantity of cargo as stated in the B/L and the out turn quantity as calculated in the discharge port after due consideration for the allowable transportation loss
Answer: D — The discrepancy between the quantity of cargo as stated in the B/L and the out turn quantity as calculated in the discharge port after due consideration for the allowable transportation loss
A shortage claim arises from the difference between the Bill of Lading quantity and the outturn quantity measured at the discharge port, but only after allowing for the accepted transportation loss. Small losses from evaporation, clingage and measurement tolerance are normal and are not treated as a claimable shortage.

4. How to find out ‘True in-Transit losses’ during the voyage?

  • A. The ship’s gross volume at normal temperature on loading is compared with the ship’s gross volume at normal temperature prior to discharge
  • B. The ship’s gross volume at atmospheric temperature on loading is compared with the ship’s gross volume at atmospheric temperature prior to discharge
  • C. The ship’s gross volume at standard temperature on loading is compared with the ship’s gross volume at standard temperature prior to discharge
  • D. The ship’s gross volume at atmospheric temperature & pressure on loading is compared with the ship’s gross volume at atmospheric temperature & pressure prior to discharge
Answer: C — The ship’s gross volume at standard temperature on loading is compared with the ship’s gross volume at standard temperature prior to discharge
True in-transit loss is found by comparing the ship's gross volume corrected to standard temperature (15°C or 60°F) on completion of loading with the gross standard volume just before discharge. Correcting both figures to the same standard temperature removes thermal expansion effects, leaving the real change in quantity.

5. What are all the records, if maintained onboard will assist in case of claims /disputes?

  • A. Voyage abstract (deck), notice of readiness (NOR), port log, Cargo pumping/loading/transfer records and Oil record book including bunker operations
  • B. Voyage abstract (deck and engine), notice of readiness (NOR), port log, Cargo pumping/ transfer records and Oil record book including bunker operations
  • C. Voyage abstract (deck and engine), notice of readiness (NOR), port log, Cargo pumping/loading/transfer records and Oil record book.
  • D. Voyage abstract (deck and engine), notice of readiness (NOR), port log, Cargo pumping/loading/transfer records and Oil record book including bunker operations
Answer: D — Voyage abstract (deck and engine), notice of readiness (NOR), port log, Cargo pumping/loading/transfer records and Oil record book including bunker operations
In a cargo dispute the most complete set of evidence is needed: deck and engine voyage abstracts, the notice of readiness, port log, cargo loading, pumping and transfer records, and the Oil Record Book including bunker operations. Together these show timings, quantities and any internal transfers that could explain discrepancies.

6. How to find out ‘Theoretical in-Transit losses’ during the voyage?

  • A. The ship’s net volume on board at standard temperature on completion of loading is compared with the net volume on board at standard temperature prior to the commencement of discharge emptying and filling losses.
  • B. The ship’s net volume on board at normal temperature & pressure on completion of loading is compared with the net volume on board at normal temperature & pressure prior to the commencement of discharge emptying and filling losses.
  • C. The ship’s gross volume on board at standard temperature on completion of loading is compared with the net volume on board prior to the commencement of discharge emptying and filling losses.
  • D. The ship’s net volume on board at standard temperature on completion of loading is compared with the gross volume on board at standard temperature prior to the commencement of discharge emptying and filling losses.
Answer: A — The ship’s net volume on board at standard temperature on completion of loading is compared with the net volume on board at standard temperature prior to the commencement of discharge emptying and filling losses.
Theoretical in-transit loss compares the ship's net volume corrected to standard temperature on completion of loading with the net standard volume on board just before discharge commences. Using net figures at the same standard temperature excludes free water and thermal expansion, so only the apparent quantity change during the voyage remains.

7. What are the international classification that describes petroleum liquid cargoes ?

  • A. flammable and combustible
  • B. volatile and non-volatile
  • C. Organic and Inorganic
  • D. Acidic and non-acidic
Answer: B — volatile and non-volatile
ISGOTT classifies petroleum liquid cargoes as volatile or non-volatile, based on flash point. Non-volatile petroleum has a flash point of 60°C or above, while volatile petroleum has a flash point below 60°C and can produce flammable gas at normal ambient temperatures.

8. Petroleum liquids derived from the naturally occurring crude oil that may include the following

  • A. Gasoline, Lubricant, Asphalt
  • B. Phosphoric acid, Sulfuric acid, Hydrochloric acid
  • C. Caustic soda, molten sulfur, Boric acid
  • D. Tallow, grease, molasses
Answer: A — Gasoline, Lubricant, Asphalt
Gasoline, lubricating oils and asphalt (bitumen) are all products refined from naturally occurring crude oil. The acids, caustic soda, molten sulphur, tallow and molasses in the other choices are inorganic chemicals or animal and vegetable products, not petroleum derivatives.

9. The EmS guide is given in

  • A. Volume 1 of IMDG code
  • B. Volume 2 of IMDG code
  • C. IMDG code supplement
  • D. SOLAS
Answer: C — IMDG code supplement
The Emergency Response Procedures for Ships Carrying Dangerous Goods (EmS Guide) is published in the IMDG Code Supplement, together with the Medical First Aid Guide (MFAG). Volumes 1 and 2 contain the main provisions and the Dangerous Goods List, which gives the EmS fire and spillage schedule codes.

10. MARPOL Annex I came into force in

  • A. 1987
  • B. 1983
  • C. 1992
  • D. 2003
Answer: B — 1983
MARPOL 73/78, including the mandatory Annex I on prevention of pollution by oil, entered into force on 2 October 1983. Annex II for noxious liquid substances followed later, in April 1987.

11. How to reduce Hydrogen Sulphide Hazard in Residual Fuel Oils?

  • A. Ventilation to lower the concentration of vapour in the ullage space and in specific areas where vapours may accumulate should be carried out as soon as practicable.
  • B. Transfer the oil to some other tank using fuel transfer pump,
  • C. Keep heating the oil to maintain a higher temperature
  • D. Circulate the oil in the same tank using the fuel transfer pump
Answer: A — Ventilation to lower the concentration of vapour in the ullage space and in specific areas where vapours may accumulate should be carried out as soon as practicable.
Hydrogen sulphide released from residual fuel oil accumulates in the tank ullage space and nearby areas. ISGOTT advises reducing the hazard by ventilating these spaces as soon as practicable to lower the vapour concentration, while transferring, circulating or heating the oil would release more H2S.

12. What is pressure surge ?

  • A. When the pressure of oil increases suddenly at the manifold
  • B. When the pressure of oil decreases suddenly at the manifold
  • C. When the discharge pressure at the pump drops to zero
  • D. A sudden increase in the pressure of the liquid in a pipeline brought about by an abrupt change in flow rate
Answer: D — A sudden increase in the pressure of the liquid in a pipeline brought about by an abrupt change in flow rate
ISGOTT defines a pressure surge as a sudden increase in liquid pressure in a pipeline caused by an abrupt change in flow rate, typically from rapid valve closure. The surge travels along the line and can rupture hoses, loading arms or pipework, so valve closure times must be controlled.

13. Burning of candle is an example of ______________.

  • A. rapid combustion
  • B. spontaneous combustion
  • C. slow oxidation
  • D. explosion
Answer: A — rapid combustion
A candle flame is a self-sustaining rapid oxidation producing heat and light (rapid combustion); slow oxidation is rusting, spontaneous combustion needs no ignition source.

14. What is flammable range ?

  • A. The range in which nothing will burn
  • B. The range in which the oxygen content is too low to cause explosion
  • C. The range in which the oxygen content is too high to cause explosion
  • D. The range of hydrocarbon gas concentrations in air between the lower and upper flammable limits. Mixtures within this range are capable of being ignited and of burning.
Answer: D — The range of hydrocarbon gas concentrations in air between the lower and upper flammable limits. Mixtures within this range are capable of being ignited and of burning.
ISGOTT defines the flammable range as the range of hydrocarbon gas concentrations in air between the lower and upper flammable limits. Mixtures inside this range can be ignited and will burn, while mixtures below the LFL are too lean and those above the UFL are too rich.

15. What is the eight-hour safe exposure limit for Carbon Monoxide?

  • A. 15ppm
  • B. 25ppm
  • C. 125ppm
  • D. 250ppm
Answer: B — 25ppm
The commonly applied 8-hour time-weighted average exposure limit (TLV-TWA) for carbon monoxide is 25 ppm. CO is colourless and odourless and combines with haemoglobin far more readily than oxygen, so even low continuous concentrations are dangerous.

16. What is Oxygen deficiency?

  • A. Oxygen less than 21%
  • B. Oxygen less than 16%
  • C. Oxygen less than 8%
  • D. Oxygen less than 5%
Answer: A — Oxygen less than 21%
ISGOTT describes an oxygen-deficient atmosphere as one containing less than 21% oxygen by volume, the normal content of air. Any reading below 21% means something has displaced or consumed oxygen, and the space must not be entered without further ventilation and testing.

17. It is possible to find the appropriate EmS SPILLAGE SCHEDULE from the

  • A. Proper shipping name
  • B. UN Number
  • C. Packing group
  • D. Packing instructions
Answer: B — UN Number
Each entry in the IMDG Dangerous Goods List is identified by its UN number, and column 15 gives the EmS codes, such as F-E and S-D, for that UN number. The spillage schedule is therefore found by looking up the UN number.

18. Pyrophoric oxidation occurs when loading:

  • A. Light crude oils
  • B. Sour crude oils
  • C. Refined products
  • D. Chemical cargoes
Answer: B — Sour crude oils
Sour crude oils contain hydrogen sulphide, which reacts with rust in tanks lacking oxygen to form pyrophoric iron sulphide. When air later reaches these deposits they oxidise rapidly and can glow red hot, igniting flammable gas, which is why inert gas is kept in tanks carrying sour crude.

19. Systemic poisons are those that cause an adverse health effect on------------

  • A. the whole body
  • B. several organs of the human body
  • C. the skin only
  • D. a specific organ
Answer: D — a specific organ
Systemic toxins are absorbed into the bloodstream and produce harmful effects at a site away from the point of contact, typically a target organ such as the liver, kidneys or nervous system. The bank defines this as damage to a specific organ, unlike local irritants that act only on the skin.

20. The products of combustion are

  • A. carbon dioxide and water
  • B. oxygen and water
  • C. only carbon dioxide
  • D. only oxygen
Answer: A — carbon dioxide and water
Complete combustion of hydrocarbon fuels with sufficient oxygen produces carbon dioxide and water vapour, while releasing heat. Oxygen is consumed in the reaction, so it cannot be a product, and water is always formed from the hydrogen in the fuel.

21. In the burning process hydrocarbon gases react with oxygen in the air:

  • A. To produce carbon and water
  • B. To produce hydrogen and water
  • C. To produce carbon dioxide and water
  • D. To produce carbon monoxide and water
Answer: C — To produce carbon dioxide and water
When hydrocarbon gases burn, carbon combines with oxygen to form carbon dioxide and hydrogen combines with oxygen to form water. Carbon monoxide or soot forms only when combustion is incomplete because there is not enough oxygen.

22. Buildup of electrostatic charge when loading static accumulator oils is avoided by:

  • A. Increasing the flow rate
  • B. Not using natural fibre ropes in ullaging equipment
  • C. Taking tank soundings within a metal sounding pipe
  • D. Fitting, fixed equipment away from the tank wall
Answer: C — Taking tank soundings within a metal sounding pipe
ISGOTT allows dipping, ullaging and sampling of static accumulator cargoes in a non-inerted tank when done within a sounding pipe, because the earthed metal pipe prevents charge from building up on the liquid surface around the equipment. Increasing flow rate would generate more static charge.

23. What is a resuscitator ?

  • A. Equipment to revive an unconscious person
  • B. To supply air to a person in a tank
  • C. Equipment to restore the breathing of a person overcome by gas or lack of oxygen
  • D. It is a rescue equipment for use in emergency
Answer: C — Equipment to restore the breathing of a person overcome by gas or lack of oxygen
A resuscitator is a device that supplies oxygen or air under controlled pressure to restore breathing in a casualty overcome by gas or lack of oxygen. Tankers carry one under SOLAS for enclosed space rescue, and it is used by trained persons after the casualty has been removed.

24. What is the TLV-TWA for hydrogen sulphide over a period of 8 hours ?

  • A. 5 ppm
  • B. 10 ppm
  • C. 15 ppm
  • D. 20 ppm
Answer: A — 5 ppm
ISGOTT gives an 8-hour time-weighted average TLV for hydrogen sulphide of 5 ppm, with a short-term limit of 10 ppm. Above about 100 ppm H2S paralyses the sense of smell, so odour can never be relied upon for detection.

25. The International Medical Guide for Ships gives guidelines on how to diagnose, treat and prevent health problems in seafarers, mainly focusing on the first _____________ hours after injury.

  • A. 6
  • B. 48
  • C. 12
  • D. 24
Answer: B — 48
The International Medical Guide for Ships, published by WHO with IMO and ILO, is written to help non-medical crew diagnose, treat and prevent health problems on board. The bank states that it concentrates on care during the first 48 hours after injury, before shore medical help can be obtained.

26. When required to work in an area where explosive gases may accumulate, you should use tools which are

  • A. approved by the Coast Guard
  • B. high carbon steel
  • C. fixed with a ferrous cover
  • D. non-sparking
Answer: D — non-sparking
Where explosive gas can accumulate, only non-sparking tools should be used, typically made of beryllium copper or other non-ferrous alloys. Steel tools striking steel can produce incendive sparks able to ignite a flammable gas mixture.

27. Multi-gas instruments are widely used and are usually capable of housing four different sensors. A typical configuration would comprise sensors for measuring: identify one that will be of major importance for enclosed space entry,

  • A. Hydrocarbon vapor as a % LFL (explosimeter function using a pellistor sensor).
  • B. Hydrocarbon vapor in inert gas as a % Volume (tankscope function using an infra-red sensor).
  • C. Oxygen (using an electrochemical sensor).
  • D. Hydrogen Sulfide (using an electrochemical sensor).
Answer: C — Oxygen (using an electrochemical sensor).
For enclosed space entry the first priority is confirming normal oxygen content, measured with the electrochemical oxygen sensor of a multi-gas meter. ISGOTT requires a steady 21% oxygen reading before entry, along with acceptable hydrocarbon and toxic gas levels.

28. Tanker pump room ventilation must be switched on at least how many minutes before entry ?

  • A. 10 minutes
  • B. 15 minutes
  • C. 30 minutes
  • D. One hour
Answer: C — 30 minutes
Cargo pump room ventilation must run long enough to remove accumulated vapours and give adequate air changes before anyone enters. The bank takes 30 minutes as the minimum period, after which the atmosphere is tested and the entry permit procedures under SOLAS II-2 and ISGOTT are followed.

29. Which of the following hazards is the main concern when entering a ballast tank?

  • A. toxic gases
  • B. flammable gases
  • C. infection
  • D. lack of oxygen
Answer: D — lack of oxygen
Ballast tanks are kept closed and their steel surfaces corrode, a process that consumes oxygen from the trapped air. The main entry hazard is therefore oxygen deficiency, so ventilation and oxygen testing are essential before entry.

30. A crew member is unconscious and the face is flushed. You should __________.

  • A. lay the crew member down with the head and shoulders slightly raised
  • B. administer a liquid stimulant
  • C. lay the crew member down with the head lower than the feet
  • D. attempt to stand the crew member upright to restore consciousness
Answer: A — lay the crew member down with the head and shoulders slightly raised
A flushed face suggests raised blood pressure or blood flow to the head, such as from stroke or heat stroke. The casualty should be laid down with head and shoulders slightly raised to reduce pressure in the head, never given liquids while unconscious and never stood upright.

Set 9 — 30 CHEMCO exit exam questions with answers

1. A diffuse discharge from a single sharp conductor is called

  • A. A spark
  • B. A corona
  • C. A brush discharge
  • D. A Propagating brush discharge
Answer: B — A corona
A corona is a diffuse, low-energy discharge from a single sharp conductor where the electric field is concentrated. ISGOTT notes it is usually less incendive than a spark or brush discharge, which jump between surfaces or come from rounded objects.

2. What is the type of gas detection system fitted for spaces with air?

  • A. Spot metering type fixed inside the individual insulation spaces
  • B. Infrared type using sequential measurement
  • C. Portable gas detection system due to mobility of this method
  • D. Catalytic combustion type
Answer: D — Catalytic combustion type
Spaces that normally contain air are monitored with catalytic combustion (pellistor) sensors, which burn the gas on a heated catalytic element. This needs the oxygen in air, so infrared or thermal conductivity instruments are used for inerted or oxygen-deficient spaces instead.

3. Class B fires involve

  • A. Solid cellulosic materials such as wood, paper, clothing, etc.
  • B. Vapour/air mixture over the surface of flammable liquids
  • C. Energised electrical equipment
  • D. Combustible materials such as magnesium, sodium, etc.
Answer: B — Vapour/air mixture over the surface of flammable liquids
Class B fires involve flammable liquids, where it is actually the vapour/air mixture above the liquid surface that burns. They are fought with foam, dry powder or CO2 to smother the surface, while water jets can spread the burning liquid.

4. Lower flammable limit (LFL) or Lower Explosive Limit (LEL), is usually expressed:

  • A. as a percentage of the air volume
  • B. as a percentage of hydrocarbon volume
  • C. in volume percent
  • D. as a percentage of the volume of oxygen
Answer: C — in volume percent
The lower flammable limit is the minimum concentration of a gas or vapour in air that can be ignited. It is expressed as a percentage by volume of the gas in the mixture, for example about 1% by volume for typical petroleum gases.

5. For Oxygen analyzer, identify the statement that explains the working principle

  • A. Electrochemical Sensors: Analyzers of this type determine the oxygen content of a gas mixture by measuring the output of an electrochemical cell.
  • B. Oxygen diffuses through a membrane into the cell and current flows between two special electrodes separated by a liquid or gel electrolyte.
  • C. The current flow is related to the oxygen concentration in the sample and the scale is arranged to give a direct indication of oxygen content.
  • D. The analyzer readings are directly proportional to the pressure in the measuring cell, and only small errors are caused by normal variations in atmospheric pressure.
Answer: B — Oxygen diffuses through a membrane into the cell and current flows between two special electrodes separated by a liquid or gel electrolyte.
In an electrochemical oxygen analyser, oxygen diffuses through a membrane into a cell where current flows between two electrodes separated by a liquid or gel electrolyte. The current produced is proportional to the oxygen concentration, which is then displayed directly.

6. The bypass valve on a self-contained breathing apparatus (SCBA) bypasses

  • A. a breathing bag containing excessive pressure
  • B. the regulator in an emergency
  • C. oxygen to the atmosphere
  • D. the regenerator in an emergency
Answer: B — the regulator in an emergency
The bypass valve on an SCBA lets air flow from the cylinder directly to the face mask without passing through the demand regulator. It is used in an emergency if the regulator fails or the wearer needs extra air, though it uses up the cylinder supply quickly.

7. A fuel tank is considered to be gas free when the tank is

  • A. free of most flammable gas concentrations
  • B. thoroughly ventilated for at least 24 hours
  • C. inerted with carbon dioxide for 24 hours
  • D. free of all dangerous concentrations of flammable or toxic gases
Answer: D — free of all dangerous concentrations of flammable or toxic gases
A tank is gas free when enough fresh air has been introduced to lower all flammable, toxic and inert gas levels to the required safe limits, as confirmed by testing. ISGOTT stresses that gas free status depends on measurements, not on time spent ventilating.

8. Which of the gases listed is the poisonous gas most likely to be found in a closed compartment involved in a fire?

  • A. Nitrogen
  • B. Hydrogen
  • C. Carbon dioxide
  • D. Carbon monoxide
Answer: D — Carbon monoxide
A fire in a closed compartment soon runs short of oxygen, so combustion is incomplete and carbon monoxide is produced. CO is highly toxic because it binds to haemoglobin much more readily than oxygen, and it has no smell or colour.

9. Which type of cargoes are often known as static accumulator cargoes?

  • A. Crude oil
  • B. Vegetable oil
  • C. Highly refined petroleum products
  • D. Animal oil
Answer: C — Highly refined petroleum products
Highly refined products such as gas oil, kerosene and jet fuel have very low electrical conductivity, so electrostatic charge relaxes slowly. ISGOTT calls them static accumulators, and they require reduced initial loading rates and precautions with dipping.

10. What is the priority order of a Company's on board policies and procedures?

  • A. Safety of the crew; Safe operation of the vessel; Protection of the environment
  • B. Safe operation of the vessel; Safety of the crew; Protection of the environment
  • C. Protection of the environment; Safety of the crew; Safe operation of the vessel
  • D. Protection of the environment; Safe operation of the vessel; Safety of the crew
Answer: A — Safety of the crew; Safe operation of the vessel; Protection of the environment
Company procedures under the ISM Code rank safety of life first, then safe operation of the vessel, then protection of the environment. Human life always comes first, and a safely operated ship is the best protection against pollution.

11. When preparing to pump flammable liquids with a centrifugal pump, you should

  • A. draw a small quantity of liquid to prime the pump
  • B. check for gland leakage and any fire hazard
  • C. have a standby pump running with the discharge valve closed
  • D. lift the relief valve by hand to check its operation
Answer: B — check for gland leakage and any fire hazard
Before pumping flammable liquids, the pump glands and seals should be checked for leakage and the surrounding area for any fire hazard. A leaking gland can release flammable liquid or vapour into the pump room close to hot surfaces or electrical equipment.

12. Certain operations can give rise to accumulations of electric charge which may be released suddenly in electrostatic discharges with sufficient energy to ignite

  • A. Flammable hydrocarbon gas/air mixtures
  • B. Flammable hydrocarbon gas/Nitrogen mixtures
  • C. Combustible hydrocarbon liquid
  • D. Flammable hydrocarbon gas/CO2 mixtures
Answer: A — Flammable hydrocarbon gas/air mixtures
Electrostatic discharges can ignite flammable hydrocarbon gas/air mixtures because air supplies the oxygen needed for combustion. Mixtures with nitrogen or CO2 lack enough oxygen to burn, which is the principle behind inerting cargo tanks.

13. How many portable multi – gas detectors should be carried onboard?

  • A. At least one with methane gas and one of propane gas detection capability
  • B. At least one with methane and one of carbon monoxides gas detection capability
  • C. At least one with methane gas and one of ammonia gas detection capability
  • D. At least two sets with methane gas detection capability
Answer: D — At least two sets with methane gas detection capability
Gas-fuelled and gas carrier ships use methane-type flammable gas detection, and the requirement is for at least two portable gas detectors with methane detection capability. Having two sets allows one to be used while the other is calibrated or repaired.

14. Class A fires involve

  • A. Solid cellulosic materials such as wood, paper, clothing, etc.
  • B. Vapour/air mixture over the surface of flammable liquids
  • C. Energised electrical equipment
  • D. Combustible materials such as magnesium, sodium, etc.
Answer: A — Solid cellulosic materials such as wood, paper, clothing, etc.
Class A fires involve ordinary solid combustible materials such as wood, paper, cloth and rubbish, which leave embers. They are best extinguished with water, which cools the fuel below its ignition temperature.

15. The ISM Code requires work procedures which ensures ________ performance

  • A. Superior
  • B. Profitable
  • C. Safe
  • D. Excellent
Answer: C — Safe
The ISM Code requires the company to establish procedures and instructions so that key shipboard operations are performed safely and in an environmentally sound way. Its aim is safe operation and prevention of injury, loss of life and pollution, not profit or excellence.

16. What is the procedure for checking for spinal cord damage in an unconscious patient?

  • A. Beginning at the back of the neck, and proceeding to the buttocks, press the spine to find where it hurts
  • B. Prick the skin of the hands and the soles of the feet with a sharp object to check for reaction
  • C. Selectively raise each arm and each leg and watch patient's face to see if he registers pain
  • D. Roll patient onto his stomach and prick along the length of his spine to check reaction
Answer: B — Prick the skin of the hands and the soles of the feet with a sharp object to check for reaction
In an unconscious casualty, spinal cord damage is checked by lightly pricking the skin of the hands and the soles of the feet and watching for a reflex response. No response suggests nerve damage, and the casualty must not be moved unnecessarily or rolled about.

17. The airborne concentrations of substances (such as hydrogen sulfide) under which nearly all workers may be repeatedly exposed without adverse effects are called

  • A. exposure limits
  • B. concentration limits
  • C. threshold limit values
  • D. substance limit values
Answer: C — threshold limit values
Threshold limit values are airborne concentrations of a substance to which nearly all workers may be exposed repeatedly, day after day, without adverse effects. ISGOTT and the Tanker Safety Guide express them as TWA, STEL and ceiling values.

18. Optimum Oxygen values in the inert gas for delivery into cargo tanks is between:

  • A. 1 to 2%
  • B. 3 to 4%
  • C. 5 to 6%
  • D. 9 to 10%
Answer: B — 3 to 4%
The FSS Code requires inert gas with oxygen content of 5% or less by volume to cargo tanks. A well-run flue gas system normally delivers around 3 to 4% oxygen, keeping a margin below the 8% maximum allowed in the tanks.

19. If a cargo tank has not been certified as gas free,

  • A. breathing apparatus would not be necessary in an emergency as you would only be in the tank a short time
  • B. a man may work safely without breathing apparatus in cold weather, as vapors are less volatile
  • C. entry without a breathing apparatus may be made at the top of the tank since petroleum vapors are heavier than air
  • D. breathing apparatus should always be used
Answer: D — breathing apparatus should always be used
If a cargo tank has not been certified gas free, its atmosphere may contain hydrocarbon, toxic gas or too little oxygen. Entry must not be made without breathing apparatus, even briefly or in cold weather, as dangerous concentrations may be present anywhere in the tank.

20. Cargo tank pressure is monitored on tankers:

  • A. To ensure IG backpressure is slightly positive at all times
  • B. To prevent back pressure
  • C. To ensure enough tanks are open for loading
  • D. To ensure that the loading rate is not too high
Answer: A — To ensure IG backpressure is slightly positive at all times
Cargo tank pressure is monitored to make sure inert gas pressure stays slightly positive at all times. Positive pressure stops air entering and keeps oxygen below 8%, while staying within the P/V valve and breaker settings.

21. Identify the statement that highlights the purpose of using a non-catalytic heated filament gas indicator,

  • A. The working of catalytic gas indicator depends on the property of its combustion with air.
  • B. Since the inerted atmosphere is deficient in oxygen the catalytic gas indicators cannot be used in inerted atmospheres.
  • C. Instruments used in inerted atmosphere have a filament sensitive to the variations in the heat conductivity.
  • D. Instruments used in inerted atmosphere have a filament that are good for monitoring inerting operations.
Answer: B — Since the inerted atmosphere is deficient in oxygen the catalytic gas indicators cannot be used in inerted atmospheres.
Catalytic gas indicators work by burning gas on a heated element, which needs the oxygen in air. Because inert atmospheres lack enough oxygen, catalytic instruments give false low readings, so non-catalytic heated filament or infrared instruments are used instead.

22. The highest concentration of a harmful substance to which a person may be exposed without danger to health, is termed the

  • A. vapor pressure
  • B. tolerance point
  • C. threshold limit value
  • D. odor threshold
Answer: C — threshold limit value
The threshold limit value is the highest airborne concentration of a harmful substance to which a person may be repeatedly exposed without danger to health. It is not the same as the odour threshold, as many dangerous gases cannot be smelled at harmful levels.

23. Vessel's enclosed spaces that are not to be treated as such:

  • A. Spaces which must be entered through small hatchways or access points;
  • B. Cargo tanks and holds ;
  • C. Double-bottom tanks;
  • D. Crew accommodation
Answer: D — Crew accommodation
IMO Resolution A.1050(27) lists cargo holds and tanks, double bottoms and spaces entered through small hatches as enclosed spaces. Crew accommodation is ventilated and normally occupied, so it is not treated as an enclosed space.

24. Which would be the appropriate arrangement for entering into a DB tank through the ductkeel?

  • A. Entry permit for ductkeel and standby person at the entrance
  • B. Entry permit for DB tank and standby person loacated inside ductkeel outside DB tank
  • C. Combined entry permit for both but standby person ductkeel entrance and DB entrance
  • D. Separate enclosed space entry permit for both spaces including standby person outside both
Answer: D — Separate enclosed space entry permit for both spaces including standby person outside both
The duct keel and the double-bottom tank are separate enclosed spaces with different atmospheres, so each needs its own entry permit and atmosphere testing. A standby person must be stationed outside each space, as required by IMO A.1050(27).

25. Which of the devices listed would be safe to use in a compartment with insufficient oxygen?

  • A. Wet handkerchief.
  • B. Self-contained breathing apparatus.
  • C. Dust or gas mask.
  • D. Canister type mask.
Answer: B — Self-contained breathing apparatus.
Only a self-contained breathing apparatus supplies its own air, so it is the only device safe to use where oxygen is too low. Canister, dust and gas masks merely filter the surrounding air and give no protection against oxygen deficiency.

26. Where is the electrostatic discharge plate installed?

  • A. Near the cargo manifold
  • B. At the forward end of the ship
  • C. At the accommodation entrance on upper deck
  • D. At the aft part of the ship
Answer: C — At the accommodation entrance on upper deck
An electrostatic discharge plate is fitted at the accommodation entrance on the upper deck so that personnel can discharge any static charge on their bodies by touching it before going onto the cargo deck. This stops a person becoming a spark source near flammable vapour.

27. For Oxygen analyzer, identify the key principle upon which the analyzer is working,

  • A. A Wheatstone bridge circuit is formed using the two wires. It is used to measure a resistance by balancing two legs of the circuit.
  • B. The sample of atmosphere is filtered and passed through a diffuser before reaching the two chambers.
  • C. One chamber is with a magnetic field and the other without a magnetic field.
  • D. A difference in the thermal conductivity of the oxygen with respect to air is developed and this causes an imbalance in the resistance.
Answer: D — A difference in the thermal conductivity of the oxygen with respect to air is developed and this causes an imbalance in the resistance.
A paramagnetic (magnetic wind) oxygen analyser uses a heated filament in a magnetic field. Oxygen is attracted into the field, then heated and pushed out, and this changes the thermal conductivity around the filament compared with the reference. The resulting resistance imbalance indicates oxygen content.

28. The ________ depends upon the pressure of contact exerted on live wires.

  • A. voltage
  • B. current
  • C. impedance
  • D. power
Answer: C — impedance
Contact pressure on live wires determines contact resistance, which forms part of the circuit impedance. A loose or poor connection has high impedance at the joint, which causes heating and arcing, a common cause of electrical fires.

29. What is related to the relaxation time of the material in which the electical charges are accumulated?

  • A. That material's density
  • B. That material's viscosity
  • C. That material's conductivity
  • D. That material's flammabilty
Answer: C — That material's conductivity
Relaxation time is the time taken for an accumulated electrostatic charge to dissipate, and it depends on the electrical conductivity of the material. Low-conductivity liquids such as refined products have long relaxation times, which is why ISGOTT treats them as static accumulators.

30. Operating Principle of the Infrared instrument: identify the key principle that leads to detection of hydrocarbon gas,

  • A. The amount of absorption is related to the concentration of the gas and is measured by a set of optical detectors and suitable electronic systems.
  • B. The change in the intensity of the absorbed light is measured relative to the intensity of light at a non-absorbed wavelength.
  • C. When there is no gas present the signals of reference signal detector and measurement signal detector are balanced.
  • D. When there is combustible gas present, there is a predictable drop in the output from measurement signal detector because the gas is absorbing light.
Answer: D — When there is combustible gas present, there is a predictable drop in the output from measurement signal detector because the gas is absorbing light.
An infrared gas detector compares a measurement signal at a wavelength that hydrocarbons absorb with a reference signal at a non-absorbed wavelength. When hydrocarbon gas is present, light is absorbed and the measurement signal drops predictably, and this imbalance indicates the gas concentration.

Set 10 — 30 CHEMCO exit exam questions with answers

1. When using a permit to work system one must make how many copies of the permit ?

  • A. One copy
  • B. Two copies
  • C. Three copies
  • D. Four copies
Answer: B — Two copies
A permit to work is normally made in two copies: one kept at the work site with the person in charge of the job and one held by the officer who issued it, usually in the control room or on the bridge. This lets both parties track the work and its closure.

2. A method NOT usually allowed for cleaning up oil spills would be the use of _________.

  • A. skimmers
  • B. dispersants
  • C. straw
  • D. sawdust
Answer: B — dispersants
Chemical dispersants break oil into droplets that mix into the water column, which can harm marine life. Their use is restricted and needs prior approval from the coastal state, whereas mechanical recovery with skimmers or sorbents such as straw and sawdust is normally permitted.

3. A liquid-filled pressure vacuum breaker

  • A. is fitted on the tank dome
  • B. is fitted on the main deck a tanker
  • C. is fitted on the inert gas main line of a tanker
  • D. is fitted in the pump room
Answer: C — is fitted on the inert gas main line of a tanker
The liquid-filled pressure/vacuum breaker is fitted on the inert gas main of a tanker. It protects the cargo tanks from excessive pressure or vacuum if the P/V valves fail, with relief happening when the liquid seal is blown out, as required by SOLAS II-2 and the FSS Code chapter 15.

4. A thermoelectric detector:

  • A. Uses a heat sensor uses a fixed temperature stop
  • B. converts heat to electrical energy
  • C. detects a rise in tempetrature
  • D. uses a fixed temperature stop
Answer: B — converts heat to electrical energy
A thermoelectric detector uses a thermocouple, which converts heat directly into electrical energy. When heated, the junction of two dissimilar metals produces a voltage, and the detector circuit uses this to trigger the alarm.

5. The vacuum strip system was developed on oil tankers to

  • A. remove all hydrocarbon gases from the tanks after discharging
  • B. prevent cavitation in centrifugal cargo pumps
  • C. quickly remove rain water collecting on deck
  • D. discharge cargo without any human intervention
Answer: B — prevent cavitation in centrifugal cargo pumps
Vacuum stripping systems remove vapour and gas from the suction of centrifugal cargo pumps as tank levels fall. This keeps the pumps primed and prevents cavitation, so tanks can be discharged and stripped by the main pumps at a good rate.

6. Gas Dispersion through tank vents; There is a potential danger of fire and explosion if the flammable zone with emitted vapor reaches any location where there may be sources of ignition such as the follows; which one of these can be prevented easily by onboard systems?

  • A. Superstructures and accommodation blocks into which the gas can enter through doors, ports or ventilation intakes.
  • B. The cargo deck which, although it is usually regarded as free of sources of ignition, is a work area and thoroughfare.
  • C. An adjacent jetty which, although it is usually regarded as free of sources of ignition, is a work area and thoroughfare.
  • D. Adjacent vessels such as lightering ships, bunker and stores craft, pilot and crew transfer boats.
Answer: A — Superstructures and accommodation blocks into which the gas can enter through doors, ports or ventilation intakes.
Vapour entering superstructures and accommodation through doors, ports and ventilation intakes can be prevented by onboard measures. These include keeping doors and ports closed and setting air conditioning to recirculation, while the deck, jetty and nearby craft are outside the ship's direct control.

7. A stripping pump is fitted in the pump room so that

  • A. the last remaining traces of liquid can be pumped out from the tanks, pipelines and pumps
  • B. cargo from the tanks can be discharged if the main pumps should fail
  • C. the liquids collected in the bilge can be pumped out
  • D. slops can be discharged overboard at a slow rate
Answer: A — the last remaining traces of liquid can be pumped out from the tanks, pipelines and pumps
A stripping pump is a small positive-displacement or eductor-type pump. It removes the last remaining liquid from tanks, lines and pumps after the main centrifugal pumps lose suction, and is essential for clean discharge on chemical and product tankers.

8. Tanks of tankers do not exceed:

  • A. 0.1 of ship’s length
  • B. 0.15 of ship’s length
  • C. 0.2 of ship’s length
  • D. 0.25 of ship’s length
Answer: C — 0.2 of ship’s length
Under MARPOL Annex I regulation 26, cargo tank length is limited to reduce outflow if a tank is damaged. The maximum permitted length of any cargo tank is 0.2 of the ship's length, with smaller values set according to the bulkhead arrangement.

9. What do you understand from the term "Bleed off COW" ?

  • A. The process of pressure testing the COW lines onboard
  • B. The process of diverting part of cargo discharged for reducing rate
  • C. The process of diverting part of cargo discharged for crude oil washing
  • D. The process of draining oil from the COW lines after washing
Answer: C — The process of diverting part of cargo discharged for crude oil washing
Bleed-off crude oil washing takes part of the cargo being discharged by the main cargo pumps and diverts it to the COW lines and tank washing machines. This allows tanks to be washed while discharge goes on, under the MARPOL Annex I COW specifications.

10. The pipeline system that has valves fitted on bulkheads is called:

  • A. The direct line system
  • B. The free flow system
  • C. The ring main system
  • D. The free line system
Answer: B — The free flow system
In a free flow system, sluice valves fitted in the tank bulkheads let cargo flow aft from tank to tank, normally towards the pump room, by gravity and trim. It is mainly found on large crude carriers carrying one grade, as it allows very fast discharge with few pipelines.

11. Before gas freeing operations the hydrocarbon content is reduced to:

  • A. to 15% or less by volume
  • B. to 10% or less by volume
  • C. to 8% or less by volume
  • D. to 2% or less by volume
Answer: D — to 2% or less by volume
ISGOTT requires inerted tanks to be purged with inert gas until hydrocarbon content is 2% or less by volume before gas freeing with air. This keeps the tank atmosphere out of the flammable range as air is brought in during ventilation.

12. Turbidity:

  • A. is an optical characteristic that indicates the degree of clarity of a liquid
  • B. is a motion characteristic that indicates the degree of clarity of a liquid
  • C. is a refractive characteristic that indicates the degree of clarity of a liquid
  • D. is a characteristic that indicates the degree of clarity of a liquid
Answer: A — is an optical characteristic that indicates the degree of clarity of a liquid
Turbidity is an optical property showing how clear a liquid is. It is caused by suspended particles that scatter and absorb light, and it is measured by shining light through the sample, for example in cargo quality checks.

13. Tank bulkheads on a tanker are strengthened using:

  • A. Web frames, transverse webs and stringers.
  • B. Longitudinals, transverse webs and stringers.
  • C. Web frames, transverse webs and gusset plates.
  • D. Gusset plates, transverse webs and longitudinals
Answer: A — Web frames, transverse webs and stringers.
Tanker bulkheads are stiffened by a framework of web frames, transverse webs and horizontal stringers. These primary members support the stiffeners and plating against hydrostatic and sloshing loads from the cargo.

14. What is LEAST likely to be used to strip a cargo tank?

  • A. Centrifugal pump
  • B. Eductor
  • C. Rotary pump
  • D. Reciprocating pump
Answer: A — Centrifugal pump
Centrifugal pumps lose suction and cavitate when liquid levels are low, so they are least suited to stripping. Positive-displacement pumps such as reciprocating and rotary pumps, and eductors, keep working with low levels and vapour, so they are used to strip tanks.

15. Deep tanks on oil tankers are used normally to carry

  • A. nothing at all
  • B. additional ballast in bad weather
  • C. extra bunkers for long international voyages
  • D. more cargo for increasing freight
Answer: C — extra bunkers for long international voyages
On oil tankers deep tanks are normally used to carry extra bunker fuel. This gives the endurance needed for long international voyages without taking cargo space.

16. The main purpose of introducing double hull design in tankers was

  • A. to offer an extra layer of protection against environmental pollution
  • B. to increase the light weight of ship and reduce ballast required
  • C. to allow ships to navigate with reduced UKC without worrying about pollution
  • D. to increase the cargo carrying capacity of the ship with same dimensions
Answer: A — to offer an extra layer of protection against environmental pollution
Double hulls were made mandatory for new oil tankers by MARPOL Annex I regulation 19, introduced after the Exxon Valdez grounding. The main aim is an extra protective barrier so that minor groundings or collisions breach the outer hull and wing ballast tanks without spilling cargo.

17. Quick Closing Valve: identify the purpose of such a valve,

  • A. Fuel oil gravity tanks must be fitted with valves that can be closed rapidly and remotely in the event of an emergency such as a fire.
  • B. Quick closing valves can be wire operated mechanically from outside the engineroom
  • C. Quick closing valves can behydraulically or pneumaticallyoperated from outside the engineroom
  • D. Quick closing valves are not usedfor throttle purpose
Answer: A — Fuel oil gravity tanks must be fitted with valves that can be closed rapidly and remotely in the event of an emergency such as a fire.
Quick-closing valves are fitted on fuel oil tank outlets located above the double bottom, such as gravity and settling tanks. Under SOLAS II-2 they can be closed rapidly from outside the space so that fuel does not feed a fire after a pipe failure or engine room fire.

18. Which of the following is true about eductors?

  • A. They can be used only when there is a good level of liquid in the tank to be pumped out
  • B. Sea water can be used as drive and crude oil pumped out from the tanks
  • C. They sometimes make high vibrations and even lead to pipeline and gauge damage
  • D. A long preparation is required before eductor can be put to use
Answer: C — They sometimes make high vibrations and even lead to pipeline and gauge damage
Eductors work by passing high-velocity driving fluid through a nozzle. Under unsuitable flow conditions, such as excessive drive pressure or air entrainment, they can cause severe vibration and hammering that damage pipelines and gauges, so drive pressure must be watched.

19. Which one of the following is not a piping system found on an oil tanker?

  • A. Ring main system
  • B. Integrated system
  • C. Direct line system
  • D. Free flow system
Answer: B — Integrated system
The standard tanker cargo piping arrangements are the direct line system, the ring main system and the free flow system. An integrated system is not a recognised type of cargo piping arrangement.

20. The purpose of a cofferdam between two compartments is to

  • A. store tools and equipment that are necessary for the adjacent compartments
  • B. give access to the bulkhead for inspection and repairs when the tanks are full with liquid
  • C. keep a reserve space if capacity of either compartment needs to be increased
  • D. prevent different liquids from the two tanks coming in contact in case of a leak
Answer: D — prevent different liquids from the two tanks coming in contact in case of a leak
A cofferdam is an empty void space between two compartments. It ensures that a leak from one tank cannot directly reach the other, keeping incompatible liquids such as cargo and fuel oil or fresh water apart, as required by SOLAS and the IBC Code.

21. Prior to entering a cargo pump room, you should ensure that

  • A. the forced ventilating system is operating
  • B. the cargo pumps are secured
  • C. no mono carbon gases are present
  • D. the oily water separator is de-energized
Answer: A — the forced ventilating system is operating
Before entering a cargo pump room, the mechanical ventilation must be running to remove any hydrocarbon or toxic vapour. SOLAS II-2 requires pump room ventilation to be operating before entry and throughout occupation, followed by atmosphere testing as ISGOTT advises.

22. The complete details of a crude oil washing system aboard your vessel, including the operating sequences and procedures, design characteristics, a description of the system, and required personnel will be found in the

  • A. Oil Transfer Procedures Manual
  • B. Crude Oil Washing Operations and Equipment Manual
  • C. Code of Federal Regulations
  • D. Crude Oil Washing addendum to the Certificate of Inspection
Answer: B — Crude Oil Washing Operations and Equipment Manual
MARPOL Annex I requires every tanker with crude oil washing to carry an approved Crude Oil Washing Operations and Equipment Manual. It describes the system, design features, operating sequences and procedures, and the qualified personnel required.

23. You are testing a tank that contained gasoline by using a combustible gas indicator. Under testing, the tank sample caused the needle to move rapidly to 100 on the dial then fall to zero. What is the concentration of flammable gas?

  • A. Less than the flammable range
  • B. Within the flammable range
  • C. Over the flammable range
  • D. The explosimeter is defective and giving a false reading.
Answer: C — Over the flammable range
When a catalytic combustible gas indicator needle jumps above full scale and then falls back to zero, the sample is too rich. There is not enough oxygen for combustion on the filament, so the concentration is above the upper flammable limit and an inert gas instrument should be used.

24. Which of the following documents carried by a ship is not issued under the MARPOL convention?

  • A. IOPP certificate
  • B. Oil Record Book
  • C. SOPEP
  • D. Safety Management Certificate
Answer: D — Safety Management Certificate
The IOPP Certificate, Oil Record Book and SOPEP are all required by MARPOL Annex I. The Safety Management Certificate is issued under the ISM Code, which is made mandatory by SOLAS chapter IX, not by MARPOL.

25. Which of the following conditions need NOT be satisfied while discharging oil or oil mixtures from ships into the sea?

  • A. The ship must be proceeding en route
  • B. The ship must be at a distance of 12 nautical miles from the nearest land
  • C. The oily mixture is processed through an oil filtering equipment as per Reg. 14 of Annex-1
  • D. The oil content of the effluent without dilution does not exceed 15 ppm
Answer: B — The ship must be at a distance of 12 nautical miles from the nearest land
Discharge of oily bilge water from machinery spaces under MARPOL Annex I regulation 15 outside special areas needs the ship en route, processing through approved filtering equipment and an oil content of 15 ppm or less. There is no minimum distance from land, so the 12-mile condition does not apply.

26. Which tanker discharge pattern would be the safest and most efficient?

  • A. Empty the forward tanks and start working aft, emptying each tank in sequence
  • B. Start discharging with most of the discharge coming from forward, but include some from midships and after tanks
  • C. Start pumping from forward, midships, and aft with the discharge distributed equally among the tanks
  • D. Start pumping from midships and then work forward and aft simultaneously as the midships tank is emptied
Answer: B — Start discharging with most of the discharge coming from forward, but include some from midships and after tanks
Discharging mostly from the forward tanks while taking some cargo from midships and aft tanks keeps the ship trimmed by the stern, which helps drainage and stripping. It also keeps longitudinal stresses within limits by not emptying one end entirely while the other stays full.

27. Ballast water exchange should be done:

  • A. at least 100 nautical miles from the nearest land and in waters at least 100 metres in depth.
  • B. at least 200 nautical miles from the nearest land and in waters at least 100 metres in depth.
  • C. at least 200 nautical miles from the nearest land and in waters at least 200 metres in depth.
  • D. at least 100 nautical miles from the nearest land and in waters at least 200 metres in depth.
Answer: C — at least 200 nautical miles from the nearest land and in waters at least 200 metres in depth.
Under the BWM Convention regulation B-4, ballast water exchange should be done at least 200 nautical miles from the nearest land in water at least 200 metres deep. If this is not possible, 50 nautical miles and 200 metres depth is the minimum.

28. As per requirements of Marpol, Annex 1, all ships delivered on or after 1st Aug. 2010 with an aggregate oil fuel capacity 600 m3 and above, the oil fuel can be carried in

  • A. Any of the tanks without any restriction
  • B. Deep tanks and Double bottom tanks
  • C. Deep tanks in protective locations
  • D. Double bottom tanks not extending upto the ship's side
Answer: C — Deep tanks in protective locations
MARPOL Annex I regulation 12A requires ships delivered on or after 1 August 2010 with total oil fuel capacity of 600 m3 or more to carry fuel in protected locations. Fuel tanks must be set at specified distances from the bottom and side shell plating to reduce pollution if the hull is damaged.

29. The atmosphere in a tank is too rich when it is

  • A. incapable of supporting combustion because the hydrocarbon vapor content
  • B. makes the atmosphere below the LFL (Lower Flammable Level) capable of supporting combustion
  • C. in a noncombustible state which can be relied on to occur naturally on a regular basis
  • D. incapable of supporting combustion because the hydrocarbon vapor content makes the atmosphere above the UFL (Upper Flammable Limit)
Answer: D — incapable of supporting combustion because the hydrocarbon vapor content makes the atmosphere above the UFL (Upper Flammable Limit)
A tank atmosphere is too rich when hydrocarbon vapour concentration is above the upper flammable limit. There is then not enough oxygen for combustion, but it becomes flammable if diluted with air, for example during gas freeing.

30. Reid vapor pressure is __________.

  • A. exerted by liquid cargo on the sides of a tank
  • B. exerted by liquid cargo on a cargo hose body
  • C. the lowest temperature and pressure that will cause a flammable liquid to give off vapors
  • D. a measurement of the amount of flammable vapors given off by a liquid at a certain temperature
Answer: D — a measurement of the amount of flammable vapors given off by a liquid at a certain temperature
Reid vapour pressure is measured in a standard test at 37.8°C (100°F). It shows the volatility of a petroleum liquid, that is, its tendency to give off flammable vapour, and is used to assess evaporation losses and gas evolution during loading.

Set 11 — 30 CHEMCO exit exam questions with answers

1. The fitting at the end of a cargo line in a tank that allows suction to be taken close to the bottom of a tank is a ___________.

  • A. suction end
  • B. strainer
  • C. bell-mouth
  • D. vacuum valve
Answer: C — bell-mouth
A bell-mouth is the flared fitting on the end of a cargo suction line inside a tank, placed close to the tank bottom. Its shape reduces entry losses and lets the pump take suction from as low a level as possible.

2. The use of sinking and dispersing chemical agents for removal of surface oil is

  • A. the most common method used
  • B. too expensive for common use
  • C. generally safe to sea life
  • D. authorized only with prior approval
Answer: D — authorized only with prior approval
Sinking and dispersing agents only move oil from the surface into the water column or onto the seabed, and can harm marine life. Their use is permitted only with prior approval from the relevant pollution authority, in line with the national contingency plan.

3. High level and overfill tank alarms are set:

  • A. as per the ships cargo system
  • B. to values as recommended by the manufacturer
  • C. to values depending on cargo type
  • D. to values as recommended by the ISGOTT guide
Answer: B — to values as recommended by the manufacturer
High level and overfill alarms are independent level sensors. They are set at the values recommended by the equipment manufacturer and the approved system documentation, typically 95% for high level and 98% for overfill, then tested before every loading.

4. You are planning to use a crude oil washing system. What precaution must be taken with the source tank for the washing machines?

  • A. At least one meter must be decanted from the source tank.
  • B. The oil in the source tank must be sampled for compatibility.
  • C. The source tank must have been crude oil washed at least once in the past 150 days.
  • D. The inert gas system must lower the oxygen content in the source tank to a maximum of 12%.
Answer: A — At least one meter must be decanted from the source tank.
Before oil from a source tank is used for crude oil washing, at least one metre of cargo is decanted from it. This removes any free water and sediment that has settled at the bottom, so that wet crude is not used for washing, as the MARPOL COW specifications require.

5. As per definition of MARPOL Annex-1, a Crude oil tanker means a tanker designed to carry

  • A. Crude oil and other dirty oils
  • B. Crude oil alongwith some refined products
  • C. Crude oil only
  • D. Crude oil, but alternatively may carry at times dirty and clean oil products also
Answer: C — Crude oil only
MARPOL Annex I regulation 1 defines a crude oil tanker as an oil tanker engaged in the trade of carrying crude oil. A product carrier is defined separately as one carrying oil other than crude oil.

6. The atmosphere in a tank is too lean if it is

  • A. incapable of supporting combustion because the hydrocarbon content is below the LFL (LowerFlammable Limit)
  • B. capable of supporting combustion because the hydrocarbon content is above the UFL (UpperFlammable Limit)
  • C. capable of supporting a fire once started
  • D. not safe for ballasting
Answer: A — incapable of supporting combustion because the hydrocarbon content is below the LFL (LowerFlammable Limit)
A tank atmosphere is too lean when hydrocarbon vapour concentration is below the lower flammable limit. There is then too little fuel to support combustion, which is the aim of gas freeing a tank with fresh air.

7. While testing a cargo tank, your oxygen indicator reads 25% oxygen in the tank. You would then

  • A. enter the tank safely
  • B. suspect the accuracy of the reading
  • C. ventilate the tank
  • D. test for nitrogen
Answer: B — suspect the accuracy of the reading
Normal air contains about 20.9% oxygen, and a cargo tank cannot reasonably contain 25% unless pure oxygen has been introduced. A reading of 25% suggests a faulty or wrongly calibrated meter, so the instrument should be checked and recalibrated in fresh air before relying on it.

8. As per the definition of MARPOL, Annex-1, a combination carrier means a ship designed to carry

  • A. Crude oil and refined oil products at the same time in different tanks
  • B. Refined oil products and chemical products at the same time in different tanks
  • C. A combination of different products at the same time, sometimes also known as a parcel tanker
  • D. Either oil or solid cargoes in bulk
Answer: D — Either oil or solid cargoes in bulk
MARPOL Annex I regulation 1 defines a combination carrier as a ship designed to carry either oil or solid cargoes in bulk, such as an OBO or ore/oil carrier. Ships carrying several liquid grades at once are parcel or product tankers, not combination carriers.

9. The main function of a stripping system is to

  • A. maintain the temperature of the cargo throughout the vessel
  • B. dispose of dangerous vapors within the cargo tanks
  • C. increase the loading rate of the shoreside pumps
  • D. discharge liquid left in the cargo tanks after the main pumps have discharged the bulk
Answer: D — discharge liquid left in the cargo tanks after the main pumps have discharged the bulk
The stripping system removes the liquid left in cargo tanks, lines and pumps once the main cargo pumps have discharged the bulk and lost suction. It uses positive-displacement pumps or eductors that can handle low levels and vapour.

10. Pollution regulations require that each scupper in an enclosed deck area have a

  • A. wooden plug
  • B. soft rubber plug
  • C. two-piece soft patch
  • D. mechanical means of closing
Answer: D — mechanical means of closing
US pollution regulations (33 CFR 155) require each scupper in an enclosed deck area to have a mechanical means of closing. This lets oil spilled on deck during transfer be contained on board instead of draining overboard, while loose plugs are only a temporary measure.

11. During loading and discharging operation in addition o when the cargo tanks have been properly filled each inert gas system must be capable of maintaining a minimum gas pressure of

  • A. 50 millimeters of water pressure
  • B. 25 millimeters of water pressure
  • C. 100 millimeters of water pressure
  • D. 5 millimeters of water pressure
Answer: C — 100 millimeters of water pressure
Inert gas systems under the FSS Code chapter 15 and the matching US rules must be able to keep a positive pressure of at least 100 mm water gauge in cargo tanks. This keeps air out during loading, discharging and when tanks are full.

12. When authorized to use chemical agents on an oil spill they would

  • A. absorb the oil for easy removal
  • B. dissolve the oil in the water
  • C. facilitate the removal of the pollutant from the water
  • D. sink the oil
Answer: C — facilitate the removal of the pollutant from the water
Chemical agents such as dispersants or gelling agents, when authorised, are used to make it easier to remove or break down the pollutant from the water surface. Approval is needed because their own toxicity and effects must be weighed against the harm from the oil.

13. In developing the stability booklet, consideration must be given to including the following information: which one of these will be most important prior sailing out?

  • A. Tank sounding tables showing capacities, vertical centers of gravity, and longitudinal centers of gravity in graduated intervals and showing free surface data for each tank.
  • B. Information on maximum KG or minimum GM curve that can be used to determine compliance with applicable intact and damage stability criteria.
  • C. A rapid and simple means for evaluating other loading conditions.
  • D. A brief description of the stability calculations done including assumptions.
Answer: C — A rapid and simple means for evaluating other loading conditions.
Before sailing the master must quickly confirm that the actual loading condition is safe. A rapid and simple means of evaluating loading conditions, such as stability software or a simplified worksheet, is therefore the most useful practical item in the stability booklet.

14. One of the requirements of a vessel’s intact stability criteria is that:

  • A. The GZ should be at least 0.15 metres at an angle of 25 degrees or more
  • B. The GZ should be at least 0.15 metres at an angle of 30 degrees or more
  • C. The GZ should be at least 0.20 metres at an angle of 25 degrees or more
  • D. The GZ should be at least 0.20 metres at an angle of 30 degrees or more
Answer: D — The GZ should be at least 0.20 metres at an angle of 30 degrees or more
The IMO Intact Stability Code 2008 requires the righting lever GZ to be at least 0.20 m at an angle of heel of 30° or more. It also sets minimum areas under the GZ curve, a maximum GZ at not less than 25° and an initial GM of at least 0.15 m.

15. As regulation 12 of Annex 1 of MARPOL, all ships of __________ gross tonnage and above shall be provided with a sludge tank for collection of oil residues

  • A. 150 tonnes deadweight
  • B. 150 gross tonnage
  • C. 400 tonnes deadweight
  • D. 400 gross tonnage
Answer: D — 400 gross tonnage
MARPOL Annex I regulation 12 requires every ship of 400 gross tonnage and above to have a sludge tank of adequate capacity. The tank receives oil residues such as purifier sludge and leakage, which cannot be dealt with otherwise.

16. The lowest temperature at which a liquid will give off sufficient vapors to form a flammable mixture with air is known as the _________.

  • A. fire point
  • B. flash point
  • C. lower explosive limit
  • D. threshold limit value
Answer: B — flash point
Flash point is the lowest temperature at which a liquid gives off enough vapour to form a flammable mixture with air near its surface, which ignites momentarily when a flame is applied. The fire point is slightly higher, where burning continues.

17. The high-level overfill tank alarm, installed in the on-board monitoring system, must

  • A. operate in unison with other alarms
  • B. be both audible and visual
  • C. be the same as the overfill alarm
  • D. sound when the tank is 90% full
Answer: B — be both audible and visual
Tank high level and overfill alarms must give both audible and visual signals, so that cargo control room and deck personnel notice them at once. ISGOTT and the SOLAS and IBC requirements for overflow control call for clear warning before a tank overflows.

18. What is NOT a precaution to be taken when topping off?

  • A. Reduce the loading rate.
  • B. Notify the engine room of the procedure.
  • C. Maintain communications with the dock man.
  • D. Give the operation your undivided attention.
Answer: B — Notify the engine room of the procedure.
Topping off is the most critical stage of loading. It requires a lower loading rate, close communication with the terminal and the full attention of the person in charge. Notifying the engine room is not a specific topping-off precaution.

19. The minimum concentration of a vapor in air which can form an explosive mixture is called the

  • A. auto-ignition point
  • B. flash point
  • C. lower explosive limit (LEL)
  • D. threshold limit value (TLV)
Answer: C — lower explosive limit (LEL)
The lower explosive (flammable) limit is the minimum concentration of a vapour in air that can form an ignitable mixture. Below the LEL the mixture is too lean to burn, which is why gas measuring instruments display readings as a percentage of the LEL.

20. What is the material used in cargo pump?

  • A. EN 8
  • B. Bronze
  • C. Aluminium
  • D. Stainless steel
Answer: D — Stainless steel
Cargo pumps on chemical tankers are generally made of stainless steel because it resists corrosion from a wide range of chemicals and is easy to clean between grades. Bronze, aluminium and ordinary carbon steel are attacked by many IBC Code cargoes.

21. What happens in the volute casing of the centrifugal pump?

  • A. Pressure energy converted into Kinetic energy
  • B. Velocity of the liquid increases
  • C. Kinetic energy converted into pressure energy
  • D. Air bubbles are produced, creating cavitation
Answer: C — Kinetic energy converted into pressure energy
In a centrifugal pump the impeller gives the liquid high velocity. The volute casing then gradually widens, slowing the liquid and converting this kinetic energy into pressure energy at the discharge.

22. What type of pump, the FRAMO system uses for liquid chemical cargo?

  • A. Reciprocating pump
  • B. Variable delivery axial flow pump
  • C. Centrifugal pump
  • D. Gear pump
Answer: C — Centrifugal pump
The FRAMO system uses a hydraulically driven submerged centrifugal pump in each cargo tank. Each tank therefore has its own pump and line, which suits segregated chemical cargoes and allows efficient stripping.

23. Each inert gas system gas main must have an automatic shut down valve at the outlet of the gas production plant.

  • A. cargo pump failure
  • B. blower failure
  • C. deck seal low water level
  • D. low inert gas temperature
Answer: B — blower failure
The FSS Code chapter 15 requires the inert gas supply to shut down automatically on certain faults. Failure of the blowers is one such fault, because flue gas can no longer be delivered at the right pressure and quality.

24. Cargoes carried by a tanker as miscellaneous liquids are

  • A. Palm oil, molasses, tallow
  • B. Soybean oil, Sunflower oil, Other vegetable oils
  • C. Animals oils, Grease
  • D. Freshwater, Wine, Beer
Answer: D — Freshwater, Wine, Beer
Tankers may also carry miscellaneous liquids that are neither petroleum, chemicals nor vegetable or animal oils. Examples are fresh water, wine and beer, which require very clean tanks and suitable coatings.

25. The organic chemical liquids are

  • A. Phosphoric acid, Hydrochloric acid, Molten sulfur
  • B. Tallow and greases, Molasses, Wine
  • C. Boric acid, Sulfuric acid, Caustic soda
  • D. Vinyl chloride, Acetone, Acetic acid
Answer: D — Vinyl chloride, Acetone, Acetic acid
Organic chemicals are carbon-based compounds such as vinyl chloride, acetone and acetic acid. Phosphoric, sulphuric and hydrochloric acids, caustic soda, boric acid and sulphur are inorganic, while tallow, molasses and wine are natural products.

26. The chemical liquids may be categorized as

  • A. Organic or Inorganic
  • B. Volatile or Non-volatile
  • C. Flammable or combustible
  • D. Petroleum or special
Answer: A — Organic or Inorganic
Chemical cargoes are broadly divided into organic chemicals, which are based on carbon compounds, and inorganic chemicals such as acids, alkalis and salts. The other classifications listed apply to petroleum or fire hazards rather than chemical composition.

27. Why personal protective equipment may be required when a chemical tanker carry high vapor pressure cargo?

  • A. Because high vapor pressure releases more vapor
  • B. Because high vapor pressure releases less vapor
  • C. Because high vapor pressure releases hot vapor
  • D. Because high vapor pressure releases cold vapor
Answer: A — Because high vapor pressure releases more vapor
A cargo with high vapour pressure evaporates readily and releases more vapour at normal temperatures. This increases the risk of crew exposure to toxic or flammable vapour during sampling, gauging or line work, so suitable personal protective equipment and respiratory protection may be needed.

28. Molarity = Number of moles of solute per

  • A. Solvent in kilograms
  • B. Solution in litres
  • C. Mililitres
  • D. Litres
Answer: B — Solution in litres
Molarity is the number of moles of solute dissolved in one litre of solution, in mol/L. It differs from molality, which is moles of solute per kilogram of solvent.

29. Vegetable and animal oils may vary in composition and the most important factor is their free fatty acid content, which greatly affects

  • A. The carriage pressure
  • B. The cargo pumping rate
  • C. The suitability of coatings
  • D. The cargo tank atmosphere
Answer: C — The suitability of coatings
Free fatty acids in vegetable and animal oils are corrosive and can attack tank coatings, especially zinc silicate. The FFA content therefore largely determines which coatings are suitable for carrying the oil.

30. What is the effect of intermolecular forces on vapor pressure?

  • A. Relatively strong force will increase vapor pressure
  • B. Relatively strong force will decrease vapor pressure
  • C. Relatively weak force will decrease vapor pressure
  • D. Relatively weak force does not have any effect on vapor pressure
Answer: B — Relatively strong force will decrease vapor pressure
Strong intermolecular forces hold liquid molecules together, so fewer molecules escape into the vapour phase and vapour pressure is lower. Liquids with weak intermolecular forces evaporate more readily and have higher vapour pressures.

Set 12 — 30 CHEMCO exit exam questions with answers

1. Specific gravity is used by the American Petroleum Institute (API) to classify various

  • A. Viscosities of oil
  • B. Vapor densities of oil
  • C. Weights of oil
  • D. Volumes of oil
Answer: C — Weights of oil
API gravity is a scale based on specific gravity that the American Petroleum Institute uses to classify oils as light or heavy. It reflects the weight of the oil relative to water, so it is used in weight and volume conversions for cargo calculations.

2. Vegetable and animal oils may vary in composition. The most important factor is their

  • A. Alkalinity content
  • B. Hydrocarbon content
  • C. Composition
  • D. Free fatty acid content
Answer: D — Free fatty acid content
The free fatty acid content is the most important variable in vegetable and animal oils. It indicates cargo quality and deterioration, and it affects corrosion and the choice of tank coating.

3. System in which both matter and energy can be exchanged with the surroundings is

  • A. Open system
  • B. Closed system
  • C. Surrounding
  • D. Isolated system
Answer: A — Open system
An open system can exchange both matter and energy with its surroundings. A closed system exchanges only energy, and an isolated system exchanges neither matter nor energy.

4. Combustion of carbon is an example for

  • A. Exothermic reaction
  • B. Endothermic reaction
  • C. Reversible reaction
  • D. Irreversible reaction
Answer: A — Exothermic reaction
When carbon burns it combines with oxygen to form carbon dioxide and releases heat to the surroundings. Any reaction that gives out heat is exothermic.

5. Sublimation is the transition of a substance directly from

  • A. Liquid to the gas phase & Vice versa
  • B. Solid to the Liquid phase & Vice versa
  • C. Gas to the super heated gas phase & Vice versa
  • D. Solid to the gas phase & Vice versa
Answer: D — Solid to the gas phase & Vice versa
Sublimation is the change of a substance directly from solid to gas without passing through the liquid phase. The reverse change, from gas directly to solid, is deposition, and dry ice and iodine are common examples.

6. The change in the internal energy is represented as

  • A. ∆U
  • B. ∆H
  • C. ∆G
  • D. ∆T
Answer: A — ∆U
The change in internal energy of a system is written as ΔU, while ΔH is the change in enthalpy and ΔG the change in Gibbs free energy. According to the first law of thermodynamics, ΔU equals heat added minus work done.

7. Bottle A contains a dilute solution of vinegar and bottle B contains sodium carbonate solution, the colours seen in pH paper dipped in A and B are :

  • A. orange, blue
  • B. green, blue
  • C. blue, orange
  • D. orange, green
Answer: A — orange, blue
Vinegar is a dilute acid, so it turns universal pH paper orange-red. Sodium carbonate solution is alkaline, so it turns the paper blue, showing a pH well above 7.

8. Which process does not result in the formation of both carbon dioxide and water?

  • A. addition of a dilute acid to a carbonate
  • B. burning ethanol
  • C. burning methane
  • D. heating crystals of hydrated sodium carbonate
Answer: D — heating crystals of hydrated sodium carbonate
Heating crystals of hydrated sodium carbonate only drives off water of crystallisation, because sodium carbonate does not decompose at normal heating temperatures and no carbon dioxide forms. An acid reacting with a carbonate, and burning ethanol or methane, all produce both carbon dioxide and water.

9. In a volumetric experiment involving the addition of hydrochloric acid to 25.0 cm3 of aqueous sodium hydroxide it is necessary to determine when the reaction is just complete. Which piece of apparatus could be used to determine the end-point of the reaction

  • A. balance
  • B. gas syringe
  • C. stop watch
  • D. thermometer
Answer: D — thermometer
Neutralising sodium hydroxide with hydrochloric acid is exothermic. The temperature rises as acid is added and is highest at the point where the reaction is just complete, so a thermometer can be used to find the end-point.

10. Which compound in a 1 mol/dm3 solution has the lowest pH value?

  • A. ethanoic acid
  • B. hydrogen chloride
  • C. sodium chloride
  • D. sodium hydroxide
Answer: B — hydrogen chloride
Hydrogen chloride is a strong acid that dissociates completely in water. A 1 mol/dm3 solution therefore has a pH close to zero, lower than ethanoic acid, which is weak and only partly dissociated.

11. In a binary homogeneous solution the component present in a _____ amount is called a solute.

  • A. smaller
  • B. Larger
  • C. fixed
  • D. miscible
Answer: A — smaller
In a binary solution the component present in the smaller amount is called the solute and the one in the larger amount is the solvent. For example, in salt water the salt is the solute and the water is the solvent.

12. The energy possesed by all the molecules or atoms is called

  • A. Internal energy
  • B. Enthalpy
  • C. Gibbs energy
  • D. Free energy
Answer: A — Internal energy
Internal energy is the total energy of all the molecules or atoms in a system, including their kinetic and potential energies. Enthalpy and Gibbs energy are separate thermodynamic quantities derived from it.

13. Indicators used in acid-base titrations are

  • A. strong organic acids
  • B. strong organic bases
  • C. weak organic acids or weak organic bases
  • D. non electrolysis
Answer: C — weak organic acids or weak organic bases
Acid-base indicators such as phenolphthalein and methyl orange are weak organic acids or weak organic bases. Their ionised and un-ionised forms have different colours, so they change colour over a particular pH range.

14. A bee sting is acidic. Which household substance will neutralise a bee sting?

  • A. damp bicarbonate of soda pH8
  • B. damp common salt pH7
  • C. lemon juice pH5
  • D. vinegar pH4
Answer: A — damp bicarbonate of soda pH8
A bee sting is acidic, so it is neutralised by a mild alkali. Damp bicarbonate of soda, at about pH 8, is suitable, whereas salt is neutral and lemon juice and vinegar are acids that would not neutralise it.

15. The complex group of liquid cargoes that includes alcohols, ketones, glycols, esters, ethers, aromatic hydrocarbons, chlorinated hydrocarbons, etc. are known as

  • A. Solvents and Chemicals
  • B. White Oil
  • C. Non-petroleum oil
  • D. Other chemicals
Answer: A — Solvents and Chemicals
Alcohols, ketones, glycols, esters, ethers and aromatic and chlorinated hydrocarbons form the large, varied group carried on chemical tankers as solvents and chemicals. Many are flammable or toxic, and they come under the IBC Code.

16. In solid solution, solute can be _______

  • A. Liquid and Gas
  • B. Liquid or gas
  • C. Only solid
  • D. Only liquid
Answer: A — Liquid and Gas
In a solid solution the solvent is a solid, while the dissolved solute may be another solid, a liquid or a gas. Examples are hydrogen gas in palladium and mercury in amalgams. The bank stresses the liquid and gas cases.

17. Mixture of two or more substance in which composition can vary within a limit is called -------------------solution.

  • A. Homogenous
  • B. Heterogenous
  • C. Nonvenomous
  • D. Colloids are homogeneous mixtures where the particles are small enough that they stay suspended.
Answer: A — Homogenous
A solution is a homogeneous mixture whose composition can vary within certain limits, such as the solubility limit, while remaining uniform throughout. Heterogeneous mixtures are not uniform, and colloids are not true solutions.

18. Which statement does not describe a property of a weak acid in solution?

  • A. It forms a salt with sodium hydroxide.
  • B. It has a pH of between 8 and 9.
  • C. It is only partly dissociated into ions.
  • D. It reacts with sodium carbonate to give off carbon dioxide.
Answer: B — It has a pH of between 8 and 9.
A weak acid in solution has a pH below 7, typically about 3 to 6. A pH of 8 to 9 is alkaline, so it does not describe a weak acid. Weak acids still form salts with alkalis, release carbon dioxide from carbonates and are only partly dissociated.

19. Lube oils and additives group of cargoes (excluding halogenated, phosphated, and ester types) usually poses no problems for carriage in coated cargo tanks, but contamination of cargo may be a problem which requires

  • A. Thorough venting of tanks during carriage
  • B. Thorough cleaning and drying of tanks after discharging
  • C. Thorough inerting of tanks before loading
  • D. Thorough cleaning and drying of tanks before loading
Answer: D — Thorough cleaning and drying of tanks before loading
Lube oils and additives are not usually aggressive to coatings, but they are very sensitive to contamination. Tanks must therefore be thoroughly cleaned and dried before loading so that residues of previous cargo or water do not spoil the product.

20. The reaction which absorbs the chemical energy is,

  • A. Forward reaction
  • B. Reverse reaction
  • C. Exothermic reaction
  • D. Endothermic reaction
Answer: D — Endothermic reaction
An endothermic reaction absorbs energy from its surroundings and stores it as chemical energy in the products, so the surroundings cool. Examples are dissolving ammonium nitrate and photosynthesis.

21. Cargoes should not be loaded into a tank that is not specially for that purpose; if it exceeds normal atmospheric pressure at

  • A. 60.0 Deg C (140 Deg F)
  • B. 15.6 Deg C (60 Deg F)
  • C. 25.0 Deg C (77 Deg F)
  • D. 37.8 Deg C (100 Deg F)
Answer: D — 37.8 Deg C (100 Deg F)
The IBC Code requires cargoes with a vapour pressure above atmospheric pressure at 37.8°C to be carried in tanks designed for the purpose, such as pressure tanks or tanks with suitable venting or cooling. Otherwise the tanks could be overpressurised at normal temperatures.

22. Colder liquids hold more _________ than warmer liquid.

  • A. Gases
  • B. Liquid
  • C. Pressure
  • D. Water
Answer: A — Gases
Gases dissolve better in cold liquids than in warm ones, because gas solubility decreases as temperature rises. This is why warming a cargo can release dissolved gases such as H2S into the tank ullage space.

23. In exothermic reactions heat is released due to ______ taking place in them.

  • A. Cyclic reaction
  • B. Irreversible reaction
  • C. Physical reaction
  • D. Chemical reaction
Answer: D — Chemical reaction
In an exothermic reaction, heat is released because a chemical reaction takes place. The bonds formed in the products store less energy than the bonds broken in the reactants, and the difference is given off as heat.

24. The system which contains uniform or same physical state of its matter is a

  • A. Homogeneous system
  • B. Hetrogeneous system
  • C. Mixture
  • D. Unisystem
Answer: A — Homogeneous system
A homogeneous system has uniform composition and the same physical state throughout, with no visible boundaries between parts. A heterogeneous system contains distinct phases, such as oil floating on water.

25. In exothermic reactions, the amount of energy required for a chemical reaction is

  • A. Equal to the the total energy released
  • B. Greater than the total energy released
  • C. Less than the total energy released
  • D. Zero
Answer: C — Less than the total energy released
In an exothermic reaction, the energy needed to break the bonds in the reactants is less than the energy released when the new bonds in the products form. The excess is given off as heat, so the enthalpy change is negative.

26. The colour of the pH paper strip turned red when it was dipped into a sample. The sample could be:

  • A. dil. Na2CO3 solution
  • B. tap water
  • C. dil. NaOH solution
  • D. dil. HCI acid
Answer: D — dil. HCI acid
pH paper turns red in a strongly acidic solution. Dilute hydrochloric acid is a strong acid, while sodium carbonate and sodium hydroxide are alkaline (blue or purple) and tap water is close to neutral (green).

27. Which reactants could be used safely to prepare potassium chloride?

  • A. aqueous potassium hydroxide and dilute hydrochloric acid
  • B. aqueous potassium sulphate and aqueous sodium chloride
  • C. potassium and aqueous sodium chloride
  • D. potassium and dilute hydrochloric acid
Answer: A — aqueous potassium hydroxide and dilute hydrochloric acid
Potassium chloride is prepared safely by neutralising aqueous potassium hydroxide with dilute hydrochloric acid, which gives KCl and water. Potassium metal reacts violently with water and acids, and mixing potassium sulphate with sodium chloride produces no product that can be separated.

28. Modified epoxy or zinc silicate coated tanks may be required to carry some

  • A. Lub oils
  • B. Vegitable oils
  • C. Unleaded Gasolines
  • D. Animal oils
Answer: C — Unleaded Gasolines
Some unleaded gasolines contain additives or components that can attack ordinary coatings, so modified epoxy or zinc silicate coatings may be specified. The coating resistance list determines which tanks are acceptable for each grade.

29. The product of coefficient of viscosity, surface area and the velocity difference between layers of flowing liquid is

  • A. Viscosity of Liquid
  • B. Force of friction between liquid layers
  • C. Velocity of the fluid
  • D. Vapor pressure of liquid
Answer: B — Force of friction between liquid layers
According to Newton's law of viscosity, the frictional force between layers of a flowing liquid equals the coefficient of viscosity multiplied by the contact area and the velocity gradient between the layers. This product is the force of friction between the liquid layers.

30. The reaction which releases the chemical energy is

  • A. Forward reaction
  • B. Reverse reaction
  • C. Exothermic reaction
  • D. Endothermic reaction
Answer: C — Exothermic reaction
An exothermic reaction releases stored chemical energy to the surroundings as heat. Combustion of hydrocarbons and neutralisation of acids by alkalis are common examples of such reactions.

Set 13 — 30 CHEMCO exit exam questions with answers

1. Some of these Solvents and Chemicals products require extreme care in the choice of

  • A. Tank material
  • B. Tank construction
  • C. Tank coating and cargo handling
  • D. Type of cargo pumps
Answer: C — Tank coating and cargo handling
Many solvents and chemicals react with or soften certain coatings, or are contaminated by traces of previous cargo. Careful choice of tank coating and cargo handling methods, checked against the coating manufacturer's resistance list and the IBC Code, is therefore essential.

2. What is auto-ignition?

  • A. The ignition of a combustible material without initiation by a spark or flame, when the material has been raised to a temperature at which self-sustaining combustion occurs
  • B. Automatic ignition of material in a hot atmosphere
  • C. Ignition of materials when they come in contact with each other
  • D. Ignition caused by a mixture of vapours given off by cargoes
Answer: A — The ignition of a combustible material without initiation by a spark or flame, when the material has been raised to a temperature at which self-sustaining combustion occurs
ISGOTT defines auto-ignition as ignition of a combustible material without any external spark or flame once it has been heated to its auto-ignition temperature. Hot surfaces such as exhaust manifolds or steam pipes can therefore ignite oil vapour or spray without any open flame being present.

3. What is the limitation of a catalytic combustion type combustible gas detector (explosimeter)?

  • A. It cannot be used for measurement in air
  • B. It cannot be used for measurement in an inert (oxygen-deficient) atmosphere such as nitrogen
  • C. It cannot be used for measuring methane
  • D. It cannot be used in an atmosphere containing 21% oxygen
Answer: B — It cannot be used for measurement in an inert (oxygen-deficient) atmosphere such as nitrogen
A catalytic filament reads gas by burning it, so it needs enough oxygen. In nitrogen or other inert atmospheres it gives false low readings. ISGOTT requires non-catalytic instruments such as infrared sensors or a tankscope for hydrocarbon measurement in inerted tanks.

4. Small oil spills on deck can be kept from going overboard by ____.

  • A. Driving wooden plugs into the vents
  • B. Closing the lids on the vents
  • C. Plugging the scuppers
  • D. Plugging the sounding pipes
Answer: C — Plugging the scuppers
Before and during oil transfer, MARPOL Annex I and SOPEP procedures require deck scuppers to be plugged. Any small spill is then contained on deck and can be cleaned up with absorbents instead of going overboard.

5. During ship-to-ship (STS) transfer operations, the manoeuvring vessel normally berths ____.

  • A. Either side to
  • B. Port side to
  • C. Starboard side to
  • D. As instructed by the mother vessel
Answer: B — Port side to
Under the OCIMF/ICS STS Transfer Guide, the constant heading ship usually keeps a steady course and speed and offers her starboard side. The manoeuvring ship comes alongside port side to, which suits right-handed propeller turning effects.

6. As required by MARPOL Annex I Regulation 31, the ODMCS shall be fitted with a recording device giving a ____ record of the discharge in litres per nautical mile and the total quantity discharged. This record shall be kept on board for at least ____.

  • A. Intermittent, 1 year
  • B. Continuous, 1 year
  • C. Intermittent, 3 years
  • D. Continuous, 3 years
Answer: D — Continuous, 3 years
MARPOL Annex I Reg. 31 requires the oil discharge monitoring and control system to have a recording device giving a continuous record of discharge rate in litres per nautical mile and total quantity discharged. The record must be retained for at least three years.

7. Each ship fitted with an inert gas system must carry a portable instrument for measuring hydrocarbon vapour concentration in inert atmospheres, and an instrument for measuring ____.

  • A. Nitrogen
  • B. Oxygen
  • C. Carbon dioxide
  • D. Hydrogen sulphide
Answer: B — Oxygen
SOLAS II-2/4.5.7 and the FSS Code require tankers with inert gas systems to carry portable instruments for oxygen and for hydrocarbon vapour in inert atmospheres. These confirm the cargo tanks stay at 8% oxygen or less and allow gas-freeing to be checked.

8. How is intrinsic safety achieved for electrical circuits used in hazardous areas?

  • A. By limiting the ignition energy and surface temperature that can arise during operation
  • B. By limiting the number of items of equipment used in a space
  • C. By increasing mechanical ventilation to the area
  • D. By installing higher-powered machinery so that operating time is shorter
Answer: A — By limiting the ignition energy and surface temperature that can arise during operation
Intrinsic safety (Ex i) limits the electrical and thermal energy in a circuit so that any spark or hot surface produced, normally or under fault, is incapable of igniting the surrounding flammable atmosphere.

9. What is the gas group classification of an LNG carrier, based on the gas likely to be present in its hazardous spaces?

  • A. Group IIC
  • B. Group IIB
  • C. Group I
  • D. Group IIA
Answer: D — Group IIA
LNG is mainly methane, which is classified in apparatus gas group IIA under IEC 60079. Group IIB covers gases such as ethylene and IIC covers hydrogen and acetylene; Group I is reserved for mining (firedamp).

10. Which international bodies provide regulatory standards for electrical equipment certification for hazardous areas?

  • A. IEEC and CENELEC
  • B. IEC and CENELEC
  • C. IEEC and ISO
  • D. IMO and ISO
Answer: B — IEC and CENELEC
The International Electrotechnical Commission (IEC) publishes the IEC 60079 series and the European Committee for Electrotechnical Standardization (CENELEC) issues equivalent EN standards used to certify explosion-protected electrical equipment.

11. What should the Master of an LNG carrier do if the Custody Transfer System (CTS) fails?

  • A. Use the gauging reports of the shore receiving tanks
  • B. Inform the company and receivers, and use manual gauging with the tank tables
  • C. Inform the terminal and activate the ESD button
  • D. Suspend cargo operations until the CTS is repaired
Answer: B — Inform the company and receivers, and use manual gauging with the tank tables
If the CTS fails, the cargo quantity must still be determined using backup or manual gauging with the calibrated tank tables, and all interested parties such as the company and receivers must be informed so the custody transfer figures remain accepted.

12. The location of electrical equipment is classified by zones. What does Zone 1 mean?

  • A. Flammable material is under control and explosion or fire can never occur
  • B. Flammable material is under control and an explosive mixture can occur only in abnormal conditions
  • C. Flammable material is present continuously within the LEL and UEL
  • D. Flammable material is present and an explosive mixture is likely to form in normal operation
Answer: D — Flammable material is present and an explosive mixture is likely to form in normal operation
Under IEC 60079-10 / IEC 60092-502, Zone 1 is an area in which an explosive gas atmosphere is likely to occur in normal operation. Zone 0 is continuous presence and Zone 2 is presence only in abnormal conditions for short periods.

13. A radar tank gauge is stamped Ex ia IIC T4. What is the maximum surface temperature allowed?

  • A. 450°C
  • B. 135°C
  • C. 85°C
  • D. 200°C
Answer: B — 135°C
The temperature class T4 limits the maximum surface temperature of the apparatus to 135°C. T1 is 450°C, T3 is 200°C and T6 is 85°C, so the gauge may only be used with gases whose auto-ignition temperature exceeds 135°C.

14. Which IEC symbol denotes explosion-proof (flameproof) electrical protection?

  • A. Ex e
  • B. Ex d
  • C. Ex n
  • D. Ex p
Answer: B — Ex d
Ex d is the flameproof or explosion-proof enclosure, which can withstand an internal explosion and prevent its transmission to the outside atmosphere. Ex e is increased safety, Ex p pressurised and Ex n non-sparking protection.

15. Why is the maximum surface temperature identified for electrical equipment used in hazardous areas onboard LNG carriers?

  • A. The limit is on minimum surface temperature on LNG carriers, as the cargo is cryogenic
  • B. Equipment should operate within these limits to reduce power and boil-off consumption
  • C. Equipment should operate within these limits to prevent a hot surface becoming a source of ignition
  • D. Equipment should operate within these limits to reduce heat transfer to the cryogenic cargo
Answer: C — Equipment should operate within these limits to prevent a hot surface becoming a source of ignition
The temperature class marks the highest surface temperature the equipment can reach. Keeping it below the auto-ignition temperature of the gas present ensures the hot surface cannot ignite a flammable atmosphere.

16. What happens when certain synthetic polymers are vigorously rubbed together and then separated?

  • A. Electrical charge separation occurs
  • B. Electrical charge accumulation occurs
  • C. Electrostatic discharge occurs
  • D. None of the above
Answer: A — Electrical charge separation occurs
Rubbing and separating dissimilar materials transfers electrons from one surface to the other, producing charge separation. This is the first of the three stages of a static hazard; accumulation and discharge may follow only if conditions allow.

17. Before entering a fuel tank that has been cleaned, it should be checked with an oxygen indicator and a/an ____.

  • A. halide torch
  • B. flame safety lamp
  • C. Orsat apparatus
  • D. combustible gas indicator
Answer: D — combustible gas indicator
Before entry an enclosed space must be tested for oxygen content and for flammable vapours. A combustible gas indicator (explosimeter) measures flammable gas as a percentage of the LEL; the space should read 21% oxygen and not more than 1% LEL.

18. What is the typical measuring range of a portable oxygen analyser?

  • A. 0 to 10 ppm oxygen by volume in air
  • B. 0 to 25% oxygen by volume in air
  • C. 0 to 5% oxygen by volume in air
  • D. 0 to 100% oxygen by volume in air
Answer: B — 0 to 25% oxygen by volume in air
Portable oxygen analysers used on tankers typically read 0 to 25% by volume, covering both inerted tanks (8% or less) and normal air (20.9%), which is what is needed for inerting checks and enclosed space entry.

19. A tank or compartment is "gas free" when there is an absence of dangerous concentrations of ____.

  • A. any combustible liquid
  • B. flammable or toxic gases
  • C. all flammable liquids
  • D. residues from cargo oil
Answer: B — flammable or toxic gases
ISGOTT defines gas free as a condition in which sufficient fresh air has been introduced to lower flammable, toxic or inert gas levels to those required for a specific purpose, i.e. no dangerous concentrations of flammable or toxic gases.

20. For what minimum duration must an EEBD be capable of being used?

  • A. 5 minutes
  • B. 10 minutes
  • C. 15 minutes
  • D. 20 minutes
Answer: B — 10 minutes
The FSS Code, Chapter 3, requires an Emergency Escape Breathing Device to have a service duration of at least 10 minutes, as it is intended only for escape from a hazardous atmosphere, not for fire fighting or entry.

21. When entering the pump room of a tanker to rescue an unconscious person, which equipment are you required to use?

  • A. Protective clothing and an explosion-proof flashlight
  • B. Self-contained breathing apparatus and lifelines
  • C. Combustible gas indicator and canister gas mask
  • D. Flame safety lamp and resuscitation equipment
Answer: B — Self-contained breathing apparatus and lifelines
An unconscious person in a pump room indicates a toxic or oxygen-deficient atmosphere. Rescuers must wear SCBA, never filter masks, and use a lifeline so they can be tracked and withdrawn, as recommended by ISGOTT and the enclosed space entry procedures.

22. What are the three basic stages that lead to a potential static hazard and are necessary for an electrostatic ignition?

  • A. Viscosity, charge separation and temperature
  • B. Charge accumulation, velocity and density
  • C. Charge separation, charge accumulation and electrostatic discharge
  • D. Flammable gas, air and heat source
Answer: C — Charge separation, charge accumulation and electrostatic discharge
ISGOTT explains that static electricity presents an ignition hazard only when charge is separated, then accumulates on an insulated object or liquid, and finally discharges as a spark of sufficient energy in a flammable atmosphere.

23. A permit to work should not be valid for more than ____.

  • A. 12 hours
  • B. 24 hours
  • C. 36 hours
  • D. 48 hours
Answer: B — 24 hours
Permits to work are issued for a specific task and limited period, and normally should not exceed 24 hours. If work continues, conditions must be re-checked and a new permit issued, so that changes in the atmosphere or ship condition are caught.

24. A cargo tank should be considered an enclosed space ____.

  • A. if the previous cargo was flammable
  • B. always, irrespective of the nature of the cargo previously carried
  • C. if the previous cargo was toxic
  • D. if the chief officer declares it to be so after testing
Answer: B — always, irrespective of the nature of the cargo previously carried
Cargo tanks have limited openings and inadequate natural ventilation, so they meet the definition of an enclosed space in IMO Resolution A.1050(27) and ISGOTT regardless of the previous cargo, and full entry procedures apply every time.

25. Which of the following current levels can stop the heart functioning and blood circulation?

  • A. 0.01 A
  • B. 0.015 A
  • C. 0.5 A
  • D. 0.10 A
Answer: D — 0.10 A
A current through the body of about 100 mA, i.e. 0.1 A, is generally accepted as sufficient to cause ventricular fibrillation, stopping effective heart action and circulation. Around 10 to 15 mA causes painful muscular contraction and inability to let go.

26. If there has been a fire in a closed, unventilated compartment, it may be unsafe to enter because of ____.

  • A. excess hydrogen
  • B. unburned carbon particles
  • C. excess nitrogen
  • D. a lack of oxygen
Answer: D — a lack of oxygen
A fire in a closed space consumes the available oxygen and produces toxic combustion gases such as carbon monoxide. The atmosphere is likely to be oxygen-deficient, so entry without SCBA after testing is unsafe.

27. When the oxygen content is between ____, a person may experience fainting, nausea and vomiting.

  • A. 19.5% and 16%
  • B. 16% and 12%
  • C. 12% and 10%
  • D. 10% and 8%
Answer: D — 10% and 8%
As oxygen falls, effects worsen progressively: below about 16% breathing and pulse increase and judgement suffers, and by around 10% and below nausea, vomiting, fainting and loss of consciousness occur, with death following at lower levels.

28. Which of the following is required to be included in the fireman's outfit?

  • A. Chemical protection face shield
  • B. Approved work vest
  • C. Self-contained breathing apparatus
  • D. Five-cell approved flashlight
Answer: C — Self-contained breathing apparatus
SOLAS II-2/10 and the FSS Code Chapter 3 define the fireman's outfit as personal equipment (protective clothing, boots, gloves, helmet, safety lamp and axe) plus a self-contained compressed-air breathing apparatus with a fireproof lifeline.

29. A man has suffered a burn on the arm with extensive skin damage and charring. How is this injury classified in standard medical terminology?

  • A. Dermal burn
  • B. Third-degree burn
  • C. Major burn
  • D. Lethal burn
Answer: B — Third-degree burn
A third-degree (full-thickness) burn destroys the entire skin thickness and may extend into deeper tissue. It appears charred, white or leathery and is often painless because the nerve endings have been destroyed.

30. To detect the presence of explosive gases in any space, tank or compartment, you should use a ____.

  • A. flame scanner
  • B. halide torch
  • C. combustible gas indicator
  • D. detector filament
Answer: C — combustible gas indicator
A combustible gas indicator (explosimeter) uses a catalytic filament to measure flammable vapour in air as a percentage of the lower explosive limit. Halide torches detect refrigerant leaks and flame scanners monitor boiler flames.

Set 14 — 30 CHEMCO exit exam questions with answers

1. What is an EEBD used for?

  • A. For escape from machinery or accommodation spaces in the event of a fire
  • B. For safety when entering a tank
  • C. For rescuing a person from a tank
  • D. For supplying oxygen to a victim
Answer: A — For escape from machinery or accommodation spaces in the event of a fire
An Emergency Escape Breathing Device, required by SOLAS II-2/13, is a short-duration supplied-air or oxygen device used only for escape from a compartment with a hazardous atmosphere. It must not be used for fire fighting, tank entry or rescue.

2. What is a particular advantage of using a positive-pressure self-contained breathing apparatus in an atmosphere immediately dangerous to life or health?

  • A. The equipment is compact and the wearer can work in confined spaces without difficulty
  • B. The equipment is lightweight and reduces physical strain on the wearer
  • C. The average operating time of most air cylinders is over an hour
  • D. The positive pressure in the face piece prevents contaminated air from entering it
Answer: D — The positive pressure in the face piece prevents contaminated air from entering it
In a positive-pressure SCBA the pressure inside the face mask is kept slightly above ambient, so any leak around the seal results in air flowing outward. Contaminated air therefore cannot leak in, giving greater protection in an IDLH atmosphere.

3. Experience indicates that hazardous static potentials do not occur, once the inlet is submerged, if the loading velocity of the liquid in the pipeline is ____.

  • A. below 7 m/s
  • B. above 7 m/s
  • C. above 10 m/s
  • D. below 3 m/s
Answer: A — below 7 m/s
ISGOTT recommends an initial loading rate of 1 m/s until the tank inlet is well covered, after which the flow velocity of a static accumulator may be increased, but should not exceed 7 m/s, as experience shows hazardous charges do not develop below this.

4. What should you do when the low-pressure alarm on a self-contained breathing apparatus sounds?

  • A. Immediately evacuate the contaminated area
  • B. Open the bypass valve on the regulator and continue working
  • C. Move the cylinder selector lever to the full cylinder position and reset the alarm
  • D. Move the reserve lever to the reserve position and reset the alarm so you can leave when it sounds again
Answer: A — Immediately evacuate the contaminated area
The low-pressure warning whistle indicates that only the reserve air supply remains, typically enough for about 10 minutes. The wearer must stop work and leave the hazardous area immediately by the shortest safe route.

5. Is an enclosed space entry permit required for entering a cargo pump room?

  • A. The Master will decide based on the findings of the chief officer
  • B. The chief officer will assess the situation and decide
  • C. Yes, the checklist, permit and other entry procedures apply as for all enclosed spaces
  • D. No, the pump room has a fixed ventilation fan and is frequently visited
Answer: C — Yes, the checklist, permit and other entry procedures apply as for all enclosed spaces
Cargo pump rooms can accumulate hydrocarbon and toxic vapours and present a particular hazard. ISGOTT requires controlled entry procedures with ventilation, atmosphere testing, communication and permit, so frequent visits or fixed fans do not remove the need for them.

6. Which of the following current levels leads to muscular contraction?

  • A. 0.01 A
  • B. 0.015 A
  • C. 0.5 A
  • D. 0.10 A
Answer: B — 0.015 A
A current of about 10 to 15 mA through the body causes painful muscular contraction, and the victim may be unable to let go of the conductor. Higher currents around 100 mA can cause ventricular fibrillation.

7. Which instrument is used to measure hydrocarbon gas in an inert atmosphere?

  • A. Explosimeter
  • B. Draeger tube instrument
  • C. Multi-gas detector
  • D. Tankscope
Answer: D — Tankscope
A catalytic explosimeter needs oxygen to work and gives false readings in inerted tanks. ISGOTT recommends a non-catalytic heated filament or infrared instrument such as a Tankscope, which reads hydrocarbon content as % by volume in inert gas.

8. A crew member suffering from hypothermia should be given ____.

  • A. a small dose of alcohol
  • B. treatment for shock
  • C. a large meal
  • D. a brisk rub-down
Answer: B — treatment for shock
Hypothermia victims should be handled gently, kept horizontal and rewarmed gradually while being treated for shock. Alcohol causes vasodilation and further heat loss, and vigorous rubbing can drive cold blood to the core and trigger cardiac arrest.

9. The reading of a combustible gas indicator shows the percentage of the ____.

  • A. lower explosive limit of a flammable gas concentration
  • B. upper explosive limit of a flammable gas concentration
  • C. concentration of flammable gas in a compartment by volume
  • D. concentration by weight of non-flammable gas in a compartment
Answer: A — lower explosive limit of a flammable gas concentration
A combustible gas indicator is calibrated to read the flammable gas concentration as a percentage of its lower explosive (flammable) limit, so 100% LEL means the atmosphere has reached the lower limit of flammability.

10. Which step is NOT generally taken when gas-freeing a tank?

  • A. Washing the tank interior with sea water
  • B. Application of degreasing solvents
  • C. Removal of corrosion products and sludge
  • D. Fresh air ventilation
Answer: B — Application of degreasing solvents
Gas freeing normally follows water washing and removal of sludge and scale, and is achieved by ventilating with fresh air. Applying solvents is not part of the process and would itself introduce flammable or toxic vapour into the tank.

11. For a sequential sampling gas detection system, what is the maximum interval between sampling and analysing each sampling head location?

  • A. Not exceeding 50 minutes
  • B. Not exceeding 40 minutes
  • C. Not exceeding 30 minutes
  • D. Not exceeding 60 minutes
Answer: C — Not exceeding 30 minutes
The IGC Code (Chapter 13) allows gas detection by sequential sampling provided each sampling point is sampled and analysed at intervals not exceeding 30 minutes, so that a developing leak is detected in good time.

12. What is flash point?

  • A. The lowest temperature at which a liquid gives off sufficient gas to form a flammable gas mixture near the surface of the liquid
  • B. The temperature at which the gas is not flammable
  • C. The temperature at which the liquid stops emitting gas
  • D. The temperature at which an explosion is not possible
Answer: A — The lowest temperature at which a liquid gives off sufficient gas to form a flammable gas mixture near the surface of the liquid
ISGOTT defines flash point as the lowest temperature at which a liquid gives off enough gas to form a flammable mixture near its surface, which flashes when an ignition source is applied under standardised test conditions.

13. Which of the following is a supporter of combustion?

  • A. Cooking gas
  • B. Oxygen gas
  • C. Nitrogen gas
  • D. Producer gas
Answer: B — Oxygen gas
Oxygen is the supporter of combustion in the fire triangle. Cooking gas and producer gas are fuels, while nitrogen is inert and is used to suppress combustion by diluting oxygen.

14. What is the lower flammable limit?

  • A. The concentration of hydrocarbon gas in air below which there is insufficient hydrocarbon to support combustion
  • B. The limit at which there is insufficient oxygen to support combustion
  • C. The limit at which there is too much oxygen to support combustion
  • D. The limit for entry of personnel into tanks
Answer: A — The concentration of hydrocarbon gas in air below which there is insufficient hydrocarbon to support combustion
ISGOTT defines the lower flammable limit as the concentration of hydrocarbon gas in air below which the mixture is too lean, containing insufficient hydrocarbon to support and propagate combustion.

15. What is bonding?

  • A. Connecting together cargo pipeline flanges
  • B. Connecting together metal parts to ensure electrical continuity
  • C. Making a ship-to-shore cable connection
  • D. Connecting together flexible couplings on deck
Answer: B — Connecting together metal parts to ensure electrical continuity
ISGOTT defines bonding as the connecting together of metal parts to ensure electrical continuity, so that no potential difference can build up between them and cause a static spark.

16. What factor mainly affects the dilution rate of a vapour cloud?

  • A. Quantity of spill
  • B. Weather conditions
  • C. Thermal inversion only
  • D. Diameter of the vapour cloud
Answer: B — Weather conditions
Dispersion of a vapour cloud depends mainly on weather conditions: wind speed and direction, atmospheric stability and temperature govern how quickly it mixes with air and falls below flammable or toxic concentrations.

17. Which of the following is a non-accumulator of static charge?

  • A. Toluene
  • B. Cyclohexane
  • C. Ketones such as acetone
  • D. Benzene
Answer: C — Ketones such as acetone
Polar liquids such as ketones and alcohols have high conductivity, so charge relaxes quickly and they are non-accumulators. Low-conductivity hydrocarbons such as toluene, benzene and cyclohexane are static accumulators, as ISGOTT explains.

18. What is the Time Weighted Average (TWA)?

  • A. A single instantaneous exposure
  • B. The short-term exposure limit over 15 minutes
  • C. The highest exposure reached
  • D. The average exposure concentration over an 8-hour working day
Answer: D — The average exposure concentration over an 8-hour working day
TLV-TWA is the time-weighted average concentration for a normal 8-hour working day and 40-hour week to which nearly all workers may be repeatedly exposed without adverse effect. The 15-minute limit is the separate STEL.

19. What is toxicity?

  • A. The degree to which a substance or mixture of substances can harm humans
  • B. A substance that is poisonous only when swallowed
  • C. A substance that is acidic
  • D. None of the above
Answer: A — The degree to which a substance or mixture of substances can harm humans
Toxicity is the degree to which a substance can harm humans or animals. Harm can result from inhalation, skin or eye contact and ingestion, so it is not limited to oral intake and is unrelated to acidity.

20. Sublimation is the phase transition of a substance ____.

  • A. from the liquid to the solid phase
  • B. from the solid to the liquid phase
  • C. from the gas phase to the solid phase
  • D. from the solid to the gas phase
Answer: D — from the solid to the gas phase
Sublimation is the direct change from solid to gas without passing through the liquid phase, as seen with dry ice (solid CO2). The reverse change from gas directly to solid is called deposition.

21. Substances which catch fire are called ____.

  • A. acids
  • B. bases
  • C. combustible
  • D. burners
Answer: C — combustible
Materials that can burn when heated in the presence of oxygen are termed combustible. Acids and bases are chemical classifications based on pH and do not describe a substance's ability to burn.

22. What is purging?

  • A. The introduction of inert gas into a tank already in the inert condition to further reduce the oxygen or hydrocarbon content to a level below which combustion cannot take place if air is introduced
  • B. Introducing oxygen into a tank to a high level
  • C. Using blowers to push oxygen into a tank
  • D. Using natural ventilation to gas free a tank
Answer: A — The introduction of inert gas into a tank already in the inert condition to further reduce the oxygen or hydrocarbon content to a level below which combustion cannot take place if air is introduced
ISGOTT defines purging as introducing inert gas into an already inerted tank to reduce the hydrocarbon content further, so that the tank atmosphere will not pass through the flammable range when air is later introduced for gas freeing.

23. What is non-volatile petroleum?

  • A. Petroleum having a flash point of 60°C or above
  • B. Petroleum having a flash point of 60°C or below
  • C. Petroleum having a flash point of 100°C or above
  • D. Petroleum having a flash point of 100°C or below
Answer: A — Petroleum having a flash point of 60°C or above
ISGOTT classifies petroleum with a closed-cup flash point of 60°C or above as non-volatile, as its vapour normally cannot form a flammable mixture at ambient temperature. Volatile petroleum has a flash point below 60°C.

24. What is hot work?

  • A. Work carried out in high ambient temperatures
  • B. Work involving sources of ignition or temperatures sufficiently high to cause ignition of a flammable gas mixture
  • C. Work in a place where the temperature is very high
  • D. Work carried out using hot material
Answer: B — Work involving sources of ignition or temperatures sufficiently high to cause ignition of a flammable gas mixture
ISGOTT defines hot work as any work involving sources of ignition or temperatures high enough to ignite a flammable gas mixture, such as welding, burning, grinding or use of non-certified electrical equipment, and it requires a hot work permit.

25. What is a Material Safety Data Sheet (MSDS)?

  • A. A document used only to find out the dangers of skin contact
  • B. A document used only to find out the effects of inhalation
  • C. A document identifying a substance and its constituents together with their hazards
  • D. A document giving only the chemical name of the product
Answer: C — A document identifying a substance and its constituents together with their hazards
An MSDS (now SDS) identifies the product and its hazardous constituents and gives their physical, health and fire hazards, handling precautions, PPE and first aid. SOLAS VI/5-1 requires it to be provided before loading MARPOL Annex I cargoes and bunkers.

26. As required by SOLAS, how many sets of full protective clothing resistant to chemical attack must be provided, in addition to the firefighters' outfits, on ships carrying dangerous goods?

  • A. 2 sets
  • B. 3 sets
  • C. 4 sets
  • D. 5 sets
Answer: C — 4 sets
SOLAS II-2/19.3.6.1 requires four sets of full protective clothing, resistant to chemical attack and selected according to the hazards of the chemicals carried, in addition to the firefighters' outfits required elsewhere in Chapter II-2.

27. Where is smoking permitted on board a tanker while at a berth?

  • A. Only in designated smoking rooms
  • B. Anywhere on the ship
  • C. In the engine room
  • D. In the cargo control room
Answer: A — Only in designated smoking rooms
ISGOTT and the Ship/Shore Safety Checklist require smoking to be restricted, at a terminal, to designated smoking rooms agreed between the Master and the terminal, located away from the cargo area with doors and ports kept closed.

28. What is cathodic protection?

  • A. Cathodes placed on the hull of a ship
  • B. Anodes placed only at the stern of a ship
  • C. Any protection of the hull of a ship
  • D. The prevention of corrosion by electrochemical techniques
Answer: D — The prevention of corrosion by electrochemical techniques
Cathodic protection prevents corrosion electrochemically by making the protected steel the cathode, either with sacrificial anodes of zinc or aluminium or with an impressed current system. ISGOTT notes aluminium anodes in tanks can cause incendive sparks if dropped.

29. What is the upper flammable limit?

  • A. The limit for entry of personnel into tanks
  • B. The concentration of hydrocarbon gas in air above which there is insufficient oxygen to support combustion
  • C. The limit at which there is insufficient inert gas to support combustion
  • D. The limit at which there is too much inert gas to support combustion
Answer: B — The concentration of hydrocarbon gas in air above which there is insufficient oxygen to support combustion
ISGOTT defines the upper flammable limit as the concentration of hydrocarbon gas in air above which the mixture is too rich, containing insufficient oxygen to support and propagate combustion.

30. A liquid is considered to be flammable when its flash point is at or below ____.

  • A. 50°F
  • B. 60°F
  • C. 70°F
  • D. 80°F
Answer: D — 80°F
Under the US Coast Guard tank vessel classification, flammable liquids are those with an open-cup flash point of 80°F, i.e. 26.7°C, or below; liquids with a flash point above 80°F are classed as combustible.

Set 15 — 30 CHEMCO exit exam questions with answers

1. What is pour point?

  • A. The temperature at which oil becomes frozen solid
  • B. The lowest temperature at which a petroleum oil will remain fluid
  • C. The temperature at which oil cannot be discharged
  • D. The temperature at which oil needs to be heated
Answer: B — The lowest temperature at which a petroleum oil will remain fluid
Pour point is the lowest temperature at which an oil will still flow under standard test conditions. Cargoes carried near their pour point must be heated to prevent them solidifying and leaving excessive residues in tanks.

2. How are Threshold Limit Values (TLVs) of gases normally specified?

  • A. In ppm by volume of gas in air
  • B. As a percentage of the LEL
  • C. As a percentage by weight of liquid
  • D. As a percentage of total tank volume
Answer: A — In ppm by volume of gas in air
TLVs are normally expressed as parts per million (ppm) by volume of the gas or vapour in air, or as mg/m3. Percentage LEL relates to flammability, not toxicity, and toxic limits are far below the levels an explosimeter can detect.

3. What is a hot work permit?

  • A. A document used for carrying out repairs under supervision
  • B. A document issued by a responsible person permitting specific hot work to be done during a particular time interval in a defined space
  • C. A document used only for work in dry dock
  • D. A document valid for 7 days for carrying out tank cleaning
Answer: B — A document issued by a responsible person permitting specific hot work to be done during a particular time interval in a defined space
ISGOTT describes a hot work permit as a document issued by a responsible person permitting specific hot work in a defined area for a specified period, after gas testing, isolation and fire precautions have been verified.

4. What is meant by "intrinsically safe"?

  • A. Equipment that can be used in any atmosphere without precautions
  • B. An electrical circuit in which any spark or thermal effect produced, normally or accidentally, is incapable of igniting a given gas mixture
  • C. There is no danger if sparks are produced in an unsafe atmosphere
  • D. Equipment fitted inside a gas-tight enclosure
Answer: B — An electrical circuit in which any spark or thermal effect produced, normally or accidentally, is incapable of igniting a given gas mixture
ISGOTT defines an intrinsically safe circuit as one in which any spark or thermal effect, produced normally or accidentally under specified fault conditions, cannot ignite a prescribed gas mixture, because circuit energy is limited.

5. What is cold work?

  • A. Carrying out work in a cold atmosphere
  • B. Work that cannot create a source of ignition
  • C. Carrying out work on reefer containers
  • D. Work that can be done only in cold temperatures
Answer: B — Work that cannot create a source of ignition
ISGOTT defines cold work as work that cannot create a source of ignition, such as routine maintenance with hand tools that do not produce sparks. It is still controlled by a permit to work in hazardous areas.

6. What is an inert condition?

  • A. When all oxygen has been eliminated from a tank
  • B. When the oxygen content is 10% by volume in a tank
  • C. A condition in which the oxygen content throughout the tank atmosphere has been reduced to 8% or less by volume by the addition of inert gas
  • D. When the oxygen content is 21% by volume in a tank
Answer: C — A condition in which the oxygen content throughout the tank atmosphere has been reduced to 8% or less by volume by the addition of inert gas
SOLAS II-2 and ISGOTT define the inert condition as the oxygen content throughout the tank atmosphere reduced to 8% or less by volume by adding inert gas, a level at which hydrocarbon gas cannot burn.

7. What is the open-cup flash point of petroleum liquids classified as combustible liquids?

  • A. Above 80°F (26.7°C)
  • B. Above 60°F (15.6°C)
  • C. Below 80°F (26.7°C)
  • D. Below 60°F (15.6°C)
Answer: A — Above 80°F (26.7°C)
In the US Coast Guard grading system, liquids with an open-cup flash point above 80°F, i.e. 26.7°C, are combustible (Grades D and E), while those at or below 80°F are flammable (Grades A, B and C).

8. The IMDG Code became mandatory on ____.

  • A. 1 January 2000
  • B. 1 January 2002
  • C. 1 January 2004
  • D. 1 January 2006
Answer: C — 1 January 2004
Amendments to SOLAS Chapter VII adopted in 2002 made the IMDG Code mandatory from 1 January 2004. Before that date it was a recommendatory code that most administrations applied voluntarily.

9. Animal and vegetable oils carried in tankers are classified as ____.

  • A. Chemical liquids
  • B. Special liquids
  • C. Non-volatile liquids
  • D. Non-flammable liquids
Answer: B — Special liquids
Tanker cargoes are broadly grouped into petroleum liquids, chemical liquids and special liquids. Animal fats and vegetable oils, together with miscellaneous liquids such as molasses, fall into the special liquids group.

10. Grade A flammable liquids such as natural gasoline have a Reid vapour pressure of ____.

  • A. more than 8.5 but less than 14 psi
  • B. 14 psi and above
  • C. 8.5 psi and below
  • D. more than 24.6 psi only
Answer: B — 14 psi and above
In the US Coast Guard grading of flammable liquids, Grade A liquids such as natural gasoline have a Reid vapour pressure of 14 psia or more, Grade B between 8.5 and 14 psia, and Grade C 8.5 psia or less.

11. What are the three broad classifications of cargoes transported in tankers?

  • A. Liquefied natural gas, liquefied petroleum gas and liquefied nitrogen
  • B. Petroleum liquids, chemical liquids and special liquids
  • C. Container, dry bulk and refrigerated cargo
  • D. General cargo, dry break bulk and frozen cargo
Answer: B — Petroleum liquids, chemical liquids and special liquids
Liquid bulk cargoes in tankers are broadly classified as petroleum liquids, chemical liquids and special liquids such as animal and vegetable oils and molasses. The other groupings describe gas or dry cargo trades.

12. Petroleum liquids that have closed-cup flash points below 60°C (140°F) are considered ____.

  • A. Non-volatile liquids
  • B. Non-flammable liquids
  • C. Volatile liquids
  • D. Combustible liquids
Answer: C — Volatile liquids
ISGOTT classifies petroleum with a flash point below 60°C as volatile, because its vapour can form flammable mixtures at normal temperatures. Petroleum with a flash point of 60°C or above is non-volatile.

13. Volume 2 of the IMDG Code contains which part?

  • A. Part 1 - General provisions, definitions and training
  • B. Part 2 - Classification
  • C. Part 3 - The Dangerous Goods List (DGL)
  • D. Part 4 - Packing and tank provisions
Answer: C — Part 3 - The Dangerous Goods List (DGL)
Volume 2 of the IMDG Code contains Part 3, the Dangerous Goods List with special provisions and limited quantity exceptions, plus Appendices A and B and the index. Parts 1, 2 and 4 to 7 are in Volume 1.

14. ____ is the process of separating a dissolved substance from its solution by removing the water.

  • A. Distillation
  • B. Evaporation
  • C. Filtration
  • D. Decantation
Answer: B — Evaporation
Evaporation removes the solvent (water) by heating, leaving the dissolved solid behind. Filtration only separates insoluble solids, decantation separates settled solids or immiscible liquids, and distillation recovers the solvent itself by condensing it.

15. In a liquid solution, the solvent is a ____.

  • A. solid
  • B. liquid
  • C. gas
  • D. plasma
Answer: B — liquid
A liquid solution is one in which the solvent, the component present in the greater amount that dissolves the other, is a liquid; the solute may be a solid, liquid or gas, as with salt, alcohol or CO2 in water.

16. When CO2 is passed through lime water, the milkiness formed is due to ____.

  • A. CaCO3 - calcium carbonate
  • B. Ca(OH)2 - calcium hydroxide
  • C. Ca(HCO3)2 - calcium bicarbonate
  • D. CaSO4 - calcium sulphate
Answer: A — CaCO3 - calcium carbonate
Lime water is a solution of calcium hydroxide. Carbon dioxide reacts with it to form insoluble calcium carbonate, which appears as a white precipitate; excess CO2 converts it to soluble calcium bicarbonate and the milkiness clears.

17. When four components are present in a solution, it is called a ____ solution.

  • A. ternary
  • B. quaternary
  • C. primary
  • D. binary
Answer: B — quaternary
Solutions are named by the number of components: binary for two, ternary for three and quaternary for four. Primary is not a term used for classifying solutions by their number of components.

18. Which process separates a pure solid, in the form of its crystals, from a solution?

  • A. Crystallisation
  • B. Sublimation
  • C. Chromatography
  • D. Distillation
Answer: A — Crystallisation
Crystallisation separates a pure solid from its solution by cooling or concentrating the solution so the solute forms crystals, leaving soluble impurities behind in the remaining liquid.

19. The quantitative relationship between pressure and the solubility of a gas in a solvent is known as ____.

  • A. Henry's law
  • B. Boyle's law
  • C. Charles's law
  • D. Raoult's law
Answer: A — Henry's law
Henry's law states that at constant temperature the amount of gas dissolved in a liquid is proportional to the partial pressure of that gas above the liquid. Boyle's and Charles's laws relate gas volume to pressure and temperature.

20. What is the purpose of the seals in a Framo submerged cargo pump?

  • A. To prevent hydraulic oil seeping to the cargo side only
  • B. To prevent cargo seeping to the hydraulic oil side only
  • C. To prevent cargo and hydraulic oil leaking into each other's side
  • D. To prevent sea water entering the pump
Answer: C — To prevent cargo and hydraulic oil leaking into each other's side
A Framo pump has seals on both the cargo and hydraulic sides with a cofferdam between them. They prevent cargo and hydraulic oil from contaminating each other, and any leakage collects in the cofferdam where purging reveals seal condition.

21. How can the speed of the cargo pump in a Framo system be varied?

  • A. The speed of a Framo cargo pump cannot be varied
  • B. By controlling the amount of hydraulic oil supplied to the hydraulic motor
  • C. By controlling the amount of hydraulic oil supplied to the cargo side of the pump
  • D. By throttling the cargo discharge valve only
Answer: B — By controlling the amount of hydraulic oil supplied to the hydraulic motor
Each Framo pump is driven by a hydraulic motor in the pump head. Its speed and capacity are varied by regulating the hydraulic oil flow and pressure supplied to that motor through the local or remote control valve.

22. To allow for the rise and fall of tide and changes in draft of a tanker during cargo transfer, cargo hoses must be suspended with ____.

  • A. slings or saddles placed at 8-metre intervals
  • B. enough slack in their bight
  • C. topping lifts and runners tied off to winches
  • D. lashings holding them tight to the ship's rail
Answer: B — enough slack in their bight
Hoses must have enough slack to accommodate tidal range, changes in draft and ship movement within the mooring limits without being stretched or kinked, while being properly supported to avoid strain on the manifold connection.

23. Which statement about the pressure in a tank inerted by an inert gas system is TRUE?

  • A. The maximum pressure permitted is 8 psi
  • B. A positive pressure should be maintained at all times
  • C. The pressure must remain within the limits of +5 psi to -1 psi
  • D. Pressure should be kept below atmospheric to prevent gas leakage
Answer: B — A positive pressure should be maintained at all times
SOLAS II-2/4.5.5 and ISGOTT require cargo tanks to be kept in an inert condition with a positive pressure at all times, so that air cannot leak into the tank and raise the oxygen content.

24. In a float gauge, the float is connected to the indicating device by a ____.

  • A. rope
  • B. tape
  • C. tube
  • D. hydraulic line
Answer: B — tape
In a float-type tank gauge the float rides on the liquid surface and is connected by a perforated stainless steel tape to a constant-tension spring drum in the gauge head, which turns the counter to indicate ullage.

25. Which of these statements about primary cells is correct?

  • A. Used primary cells can be recharged
  • B. Used primary cells can be refilled and reused
  • C. Used primary cells have to be discarded
  • D. Used primary cells regain capacity if left idle for a week
Answer: C — Used primary cells have to be discarded
Primary cells such as zinc-carbon and alkaline batteries rely on an irreversible chemical reaction, so once discharged they cannot be recharged or refilled and must be disposed of properly. Rechargeable batteries are secondary cells.

26. How should steam pipes be protected in machinery spaces?

  • A. They should be painted in different colours
  • B. They should have placards to warn personnel
  • C. They should be lagged
  • D. They should be kept wet to cool them
Answer: C — They should be lagged
Steam pipes are lagged (insulated) to protect personnel from burns, reduce heat loss and keep hot surfaces away from oil leaks. SOLAS II-2/4.2 requires hot surfaces over 220°C that could be contacted by oil to be insulated.

27. What is the bare minimum that should be done before working on electrical equipment?

  • A. Complete the electrical isolation checklist
  • B. Switch off the mains and start working
  • C. Open the equipment and commence work
  • D. Inform the bridge and start working
Answer: A — Complete the electrical isolation checklist
Before electrical work the circuit must be isolated, locked and tagged out, and proved dead under the permit and isolation checklist. Simply switching off is not enough, as the supply could be restored by someone else or another feed may exist.

28. Dry chemical powder extinguishes a fire mainly by ____.

  • A. heat removal or cooling
  • B. smothering or oxygen exclusion
  • C. flame inhibition (breaking the chain reaction)
  • D. diluting the fuel vapour with water
Answer: C — flame inhibition (breaking the chain reaction)
Dry chemical powder works mainly by interrupting the chemical chain reaction of combustion, known as flame inhibition. It has little cooling effect, so re-ignition is possible if hot surfaces remain.

29. Foam extinguishes a fire mainly by ____.

  • A. heat removal or cooling
  • B. smothering or oxygen exclusion
  • C. flame inhibition
  • D. chemical reaction with the fuel
Answer: B — smothering or oxygen exclusion
Foam forms a blanket over the burning liquid that excludes oxygen and suppresses the release of flammable vapour, extinguishing the fire mainly by smothering, with some secondary cooling from its water content.

30. What precaution should be taken while lifting heavy loads in the engine room?

  • A. All personnel should stand under the load
  • B. All personnel should stand clear of the load being lifted
  • C. All personnel should operate the controls
  • D. Personnel should steady the load by holding it from below
Answer: B — All personnel should stand clear of the load being lifted
No one should stand under or near a suspended load, because a failure of slings, shackles or the lifting appliance could cause it to fall or swing. Only the signaller and operator are needed, and tag lines are used to steady the load.

Set 16 — 30 CHEMCO exit exam questions with answers

1. Glass and iron are examples of ____ materials.

  • A. combustible
  • B. non-combustible
  • C. flammable
  • D. indicator
Answer: B — non-combustible
Glass and iron do not burn or release flammable vapours when heated to normal fire temperatures, so they are non-combustible. Steel is used for SOLAS fire-rated A-class divisions for this reason.

2. Ignition temperature is the ____.

  • A. lowest temperature at which a substance will catch fire
  • B. highest temperature at which a substance will catch fire
  • C. any temperature at which a substance is heated
  • D. temperature at which a liquid boils
Answer: A — lowest temperature at which a substance will catch fire
Ignition temperature is the lowest temperature to which a substance must be heated for it to catch fire and sustain combustion; the auto-ignition temperature is the lowest at which it ignites without any external flame or spark.

3. The oxygen level in a cargo tank is reduced by the ____.

  • A. Inert gas system
  • B. High-expansion foam system
  • C. CO2 system
  • D. Water spray system
Answer: A — Inert gas system
The inert gas system supplies low-oxygen gas into cargo tanks, keeping the tank atmosphere below 8% oxygen by volume (SOLAS II-2/4.5.5 and the FSS Code Ch. 15) so that it cannot support combustion.

4. By which adjustment does the air flow controller regulate the combustion air flow to the boiler?

  • A. Forced draught fan speed
  • B. Damper movement
  • C. Boiler water test
  • D. Fuel pump discharge pressure
Answer: B — Damper movement
In a conventional automatic combustion control system the air flow controller positions the air register or damper on the forced draught fan, varying the combustion air supplied to suit the firing rate while the fan runs at constant speed.

5. Blowing through the water level gauge glass of a boiler on board is carried out ____.

  • A. Once a week
  • B. Every day
  • C. Once a month
  • D. Only at the annual survey
Answer: B — Every day
Gauge glasses should be blown through at least daily (normally every watch) to clear the steam and water connections of sediment, so that the indicated water level is true and a false reading does not lead to low water or priming.

6. Periodic blow-down of boiler water is based on ____.

  • A. Boiler water tests
  • B. Boiler smoke
  • C. Flame control
  • D. Feed pump pressure
Answer: A — Boiler water tests
Blow-down removes concentrated dissolved solids and sludge from the boiler water. Its frequency and amount are decided from routine boiler water tests such as chloride, TDS and alkalinity, keeping values within the limits set by the treatment supplier.

7. Why does a rotary cup burner not require a high-pressure fuel supply for atomisation?

  • A. The rotary cup rotates at a high speed
  • B. The fuel is heated to a very high temperature
  • C. Steam is used to atomise the fuel
  • D. The fuel is supplied through a very small orifice
Answer: A — The rotary cup rotates at a high speed
In a rotary cup burner the fuel flows at low pressure onto the inside of a cup spinning at several thousand rpm. Centrifugal force spreads it into a thin film that is thrown off the rim and broken up by primary air, so high pump pressure is not needed.

8. In automatic boiler combustion control, the master signal is generated by the computing relay based on the requirement of ____.

  • A. Fuel
  • B. Steam
  • C. Air
  • D. Feed water
Answer: B — Steam
The master signal comes from the steam pressure (steam demand) controller. A fall in steam pressure raises the master signal, which is then passed to the fuel and air controllers so that the firing rate matches the steam demand.

9. On a rise in steam demand, to which controller does the high signal selector first pass the master signal?

  • A. Fuel controller
  • B. Air controller
  • C. Flame controller
  • D. Feed water controller
Answer: B — Air controller
Cross-limiting control makes air lead fuel when load increases. The high signal selector sends the increased demand to the air controller first, and fuel is increased only after air flow has risen, preventing a fuel-rich mixture and black smoke.

10. The air vent valve on top of the boiler shall be kept ____.

  • A. Open for a while during raising steam from cold
  • B. Closed while the boiler is shut down for maintenance
  • C. Closed at all times
  • D. Open continuously while the boiler is on load
Answer: A — Open for a while during raising steam from cold
When raising steam from cold, the air vent is kept open until a steady jet of steam issues, so that air is expelled from the steam space. It is then closed. It is also opened when shutting down to prevent a vacuum forming.

11. Scum blowing of a boiler is meant for draining boiler water from the ____.

  • A. Bottom
  • B. Top (water surface)
  • C. Middle
  • D. Furnace
Answer: B — Top (water surface)
The scum valve draws off from just below the normal water level, removing oil, foam and floating impurities from the water surface. Bottom blow-down removes sludge that settles at the lowest part of the boiler.

12. What is normally observed through the inspection hole of the boiler furnace while firing?

  • A. Furnace refractory
  • B. Flame condition
  • C. Boiler smoke
  • D. Water level
Answer: B — Flame condition
The sight or inspection port lets the watchkeeper check the flame shape, colour and stability, which shows whether atomisation and the air-fuel ratio are correct and whether the flame is impinging on the refractory or tubes.

13. How is the air for combustion supplied to a marine boiler?

  • A. The forced draught fan supplies air for combustion to the boiler
  • B. Air for combustion flows due to the natural draught of the boiler
  • C. The rotary cup draws in all the air needed
  • D. Compressed air from the main air receiver is used
Answer: A — The forced draught fan supplies air for combustion to the boiler
Marine auxiliary boilers use a forced draught fan to deliver combustion air through the air register to the burner. Natural draught from the funnel is insufficient to give controlled, complete combustion at the required firing rates.

14. Which is the most accurate instrument for measuring the amount of oxygen in the atmosphere of a confined space?

  • A. Combustible gas indicator
  • B. Oxygen analyser
  • C. Flame safety lamp
  • D. Toxic gas detector tube
Answer: B — Oxygen analyser
Only an oxygen analyser gives a direct, reliable reading of oxygen content in percent by volume. ISGOTT requires a steady 21% oxygen reading before entry; a combustible gas indicator and detector tubes measure other gases.

15. A catalytic combustible gas indicator will operate correctly ONLY when the ____.

  • A. Hydrocarbon content of the atmosphere is less than the UEL
  • B. Atmosphere is deficient in oxygen
  • C. Compartment to be tested is free of CO2
  • D. Ambient temperature is below 0°C
Answer: A — Hydrocarbon content of the atmosphere is less than the UEL
A catalytic filament instrument needs sufficient oxygen to burn the sample gas. Above the upper explosive limit there is too little oxygen, so the reading falls and may falsely appear safe; in oxygen-deficient or inerted atmospheres it is likewise unreliable.

16. Gauging devices that release a small amount of cargo liquid or vapour to the atmosphere while in use are known as ____ devices.

  • A. Restricted
  • B. Detection
  • C. Hydraulic
  • D. Closed
Answer: A — Restricted
The IBC Code (Ch. 13) classifies gauging as open, restricted or closed. Restricted devices, such as sounding pipes or ullage tubes, penetrate the tank and expose only a small amount of vapour or liquid when in use; closed devices release none.

17. Continuous exposure of the float of a float gauge to liquid movement caused by the ship's motion at sea can damage the ____.

  • A. Tape tensioning device
  • B. Diaphragm
  • C. Sensors
  • D. Ullage port cover
Answer: A — Tape tensioning device
The float is connected by a tape to a spring-loaded tensioning drum in the gauge head. Constant surging of the liquid at sea makes the float move continuously and wears or damages the tape and tensioning device, so floats are normally raised and secured when not in use.

18. Which statement about a centrifugal cargo pump is TRUE?

  • A. It is a positive displacement pump.
  • B. It must have a positive suction.
  • C. Increasing the rotation speed will decrease the discharge pressure.
  • D. It can run dry for long periods without damage.
Answer: B — It must have a positive suction.
A centrifugal pump is not self-priming; it needs a flooded or positive suction head, which is why stripping is done with eductors or positive displacement pumps. Increasing speed raises the discharge head, and running dry damages seals and bearings.

19. Segregated ballast tanks are required to be fitted on ____.

  • A. Every crude oil and new product tanker of 20,000 dwt and above
  • B. Every new crude oil tanker of 20,000 dwt and above and every new product carrier of 30,000 dwt and above
  • C. Every crude oil and new product tanker of 30,000 dwt and above
  • D. Every oil tanker of 5,000 dwt and above
Answer: B — Every new crude oil tanker of 20,000 dwt and above and every new product carrier of 30,000 dwt and above
MARPOL Annex I (Reg. 18) requires segregated ballast tanks on new crude oil tankers of 20,000 dwt and above and on new product carriers of 30,000 dwt and above, with capacity sufficient to meet draft and trim requirements without using cargo tanks.

20. MARPOL Annex VI prohibits deliberate emissions of ____, which include halons and chlorofluorocarbons.

  • A. Ozone-depleting substances
  • B. Ozone-enhancing substances
  • C. Sulphur-sensitive substances
  • D. Particulate substances
Answer: A — Ozone-depleting substances
MARPOL Annex VI Regulation 12 prohibits deliberate emissions of ozone-depleting substances such as halons and CFCs, including those released during maintenance or servicing, and bans new installations containing them.

21. In cleaning up an oil spill, straw is an example of a ____.

  • A. Chemical agent
  • B. Sorbent
  • C. Blocker
  • D. Skimmer
Answer: B — Sorbent
Sorbents soak up or attract oil to their surface. Straw, sawdust and purpose-made pads or booms are typical sorbents used in SOPEP kits and shoreline clean-up, whereas dispersants are chemical agents and skimmers are mechanical recovery devices.

22. What marking must be clearly visible on a crane?

  • A. Manufacturer's logo
  • B. Safe working load
  • C. Make of the crane
  • D. Name of the ship operator
Answer: B — Safe working load
Lifting appliances must be clearly marked with their safe working load (SOLAS/ILO lifting gear requirements, Code of Safe Working Practices).

23. Carbon dioxide extinguishes a fire by ____.

  • A. Heat removal or cooling
  • B. Smothering or oxygen exclusion
  • C. Flame inhibition
  • D. Removal of the fuel
Answer: B — Smothering or oxygen exclusion
CO2 is an inert gas that displaces air and reduces the oxygen concentration below the level needed to sustain combustion. Its cooling effect is small, so re-ignition is possible if the space is opened too early.

24. Which of the following activities is done on completion of work in an enclosed space?

  • A. Closing and securing all openings
  • B. Ensuring satisfactory lighting
  • C. Informing all related parties about the intended entry
  • D. Testing the atmosphere before entry
Answer: A — Closing and securing all openings
Once work is finished and all personnel and equipment are accounted for, the space is closed and its openings secured against inadvertent entry, and the permit is then closed. Lighting, notification and testing are pre-entry activities.

25. What is the least you must do before entering a cofferdam in the engine room?

  • A. Open up the manhole and enter the cofferdam
  • B. Complete an enclosed space entry checklist
  • C. Enter the cofferdam and simultaneously start ventilation
  • D. Put on a dust mask and enter
Answer: B — Complete an enclosed space entry checklist
A cofferdam is an enclosed space. SOLAS XI-1/7, IMO Res. A.1050(27) and the SMS require an entry permit and checklist covering ventilation, atmosphere testing, isolation and rescue arrangements before anyone enters.

26. Water extinguishes a fire mainly by ____.

  • A. Heat removal or cooling
  • B. Smothering or oxygen exclusion
  • C. Flame inhibition
  • D. Removal of the fuel
Answer: A — Heat removal or cooling
Water has a high specific heat and latent heat of vaporisation, so it absorbs large amounts of heat and cools the burning material below its ignition temperature. The steam produced gives only a minor smothering effect.

27. Which of the following is an entry activity?

  • A. Permit closed
  • B. Confirmation of removal of all equipment
  • C. Entry permit issued
  • D. Space closed and secured
Answer: C — Entry permit issued
Issuing the entry permit, after the checklist is complete and the atmosphere has been tested, authorises entry and is part of the entry stage. Closing the permit, removing equipment and securing the space are completion activities.

28. What should be prohibited in the vicinity of battery rooms?

  • A. Painting
  • B. Smoking
  • C. Washing
  • D. Drinking water
Answer: B — Smoking
Lead-acid batteries give off hydrogen when charging, which forms flammable mixtures with air. Smoking and naked lights are therefore prohibited near battery rooms, which must be well ventilated and fitted with certified safe electrical equipment.

29. Vapours having a lower relative density than air will be found at the ____ of the enclosed space.

  • A. Middle
  • B. Top
  • C. Bottom
  • D. Access hatch only
Answer: B — Top
Gases lighter than air, such as methane or hydrogen, rise and collect in the upper part of a space. This is why atmosphere testing must be done at different levels, since heavier vapours such as hydrocarbons and H2S collect at the bottom.

30. What is the least a person should do before entering machinery spaces?

  • A. Wear appropriate personal protective equipment
  • B. Inform the bridge
  • C. Inform his superiors
  • D. Remove his safety shoes
Answer: A — Wear appropriate personal protective equipment
Machinery spaces involve noise, heat, rotating parts and slippery surfaces. As a minimum, anyone entering must wear suitable PPE such as a boiler suit, safety shoes, helmet and ear protection, as required by the Code of Safe Working Practices.

Set 17 — 30 CHEMCO exit exam questions with answers

1. For entering an enclosed space, ____ of 21% is necessary.

  • A. Oxygen
  • B. Carbon dioxide
  • C. Nitrogen
  • D. Argon
Answer: A — Oxygen
Before entry the atmosphere must show a steady oxygen reading of 21% by volume, along with hydrocarbons below 1% LFL and toxic gases below their OEL, as recommended by ISGOTT and IMO Res. A.1050(27).

2. What is a corona discharge?

  • A. A diffuse discharge from a single sharp conductor that slowly releases some of the available energy; on its own it is generally incapable of igniting a gas
  • B. A diffuse discharge from a single sharp conductor that slowly releases some of the available energy; on its own it is generally capable of igniting a gas
  • C. A diffuse discharge from a single sharp conductor that is incapable of igniting a gas only if the mixture is lean
  • D. A spark between two conductors at different potentials that always ignites a flammable mixture
Answer: A — A diffuse discharge from a single sharp conductor that slowly releases some of the available energy; on its own it is generally incapable of igniting a gas
ISGOTT describes corona as a diffuse discharge from a single sharp conductor that releases energy slowly. Because its energy density is low, corona on its own is generally incapable of igniting hydrocarbon gas, unlike sparks and brush discharges.

3. Which type of anodes must not be fitted in tanks where flammable gases can be present?

  • A. Magnesium anodes
  • B. Aluminium anodes
  • C. Zinc anodes
  • D. Iron anodes
Answer: A — Magnesium anodes
Magnesium anodes produce hydrogen and can cause incendive sparks if struck, so they are prohibited in cargo tanks and tanks adjacent to them. Aluminium anodes are allowed with height and impact-energy restrictions, and zinc anodes are acceptable.

4. A substance that takes part in combustion as the fuel is called ____.

  • A. Combustible
  • B. Non-combustible
  • C. Inert
  • D. Catalyst
Answer: A — Combustible
A combustible material is one that can burn. It is the fuel side of the fire triangle, which reacts with oxygen when heated to its ignition temperature. Non-combustible and inert materials do not support or take part in burning.

5. When did Annex VI of MARPOL enter into force?

  • A. 1 July 1992
  • B. 19 May 2005
  • C. 31 December 1988
  • D. 1 January 2020
Answer: B — 19 May 2005
MARPOL Annex VI, adopted by the 1997 Protocol, entered into force on 19 May 2005. It regulates air pollution from ships, including SOx, NOx, ozone-depleting substances and VOCs. 31 December 1988 was the Annex V date.

6. Under MARPOL Annex VI, from what date were new installations containing hydrochlorofluorocarbons (HCFCs) prohibited on all ships?

  • A. 2015
  • B. 2010
  • C. 1 January 2020
  • D. 1 January 2025
Answer: C — 1 January 2020
Regulation 12 of MARPOL Annex VI prohibits new installations containing HCFCs on all ships from 1 January 2020. Installations containing other ozone-depleting substances such as halons and CFCs were banned earlier, from 19 May 2005.

7. What type of pollution is addressed by Annex II of MARPOL?

  • A. Pollution by oil
  • B. Pollution by noxious liquid substances in bulk
  • C. Pollution by garbage
  • D. Pollution by sewage
Answer: B — Pollution by noxious liquid substances in bulk
MARPOL Annex II regulates the control of pollution by noxious liquid substances carried in bulk, which is directly relevant to chemical tankers. It covers categorisation X, Y, Z and OS, prewash, discharge criteria and the Cargo Record Book.

8. Which Annex of MARPOL deals with the prevention of pollution by sewage from ships?

  • A. Annex VI
  • B. Annex IV
  • C. Annex III
  • D. Annex V
Answer: B — Annex IV
MARPOL Annex IV covers sewage, including sewage treatment plants, comminuting and holding tanks, and the ISPP certificate. Annex III covers harmful substances in packaged form, Annex V covers garbage and Annex VI covers air pollution.

9. Which part of the Oil Record Book deals with machinery space operations?

  • A. Part I
  • B. Part II
  • C. Part III
  • D. Cargo Record Book
Answer: A — Part I
Under MARPOL Annex I, Oil Record Book Part I records machinery space operations on all ships, such as sludge, bilge and bunkering. Part II is carried by oil tankers of 150 GT and above for cargo and ballast operations.

10. Under which Annex of MARPOL is the Garbage Record Book required?

  • A. Annex II
  • B. Annex V
  • C. Annex VI
  • D. Annex IV
Answer: B — Annex V
MARPOL Annex V, Regulation 10, requires a Garbage Record Book on ships of 400 GT and above and on ships certified to carry 15 or more persons. It records every discharge, incineration or delivery of garbage to reception facilities.

11. Which ships have to carry a Shipboard Marine Pollution Emergency Plan (SMPEP) for noxious liquid substances?

  • A. Ships of 400 GT or more carrying 15 persons or more
  • B. Ships of 150 GT or more carrying oil cargoes
  • C. Ships of 150 GT or more certified to carry noxious liquid substances in bulk
  • D. All ships of 500 GT and above
Answer: C — Ships of 150 GT or more certified to carry noxious liquid substances in bulk
MARPOL Annex II Regulation 17 requires every ship of 150 GT and above certified to carry noxious liquid substances in bulk to carry an approved shipboard marine pollution emergency plan for NLS. On chemical tankers this is usually combined with the SOPEP as an SMPEP.

12. Under the MARPOL Annex I single-hull tanker phase-out, what is a Category 2 oil tanker?

  • A. Any oil tanker of 5,000 tonnes deadweight and above
  • B. A crude tanker of 20,000 dwt and above (product tanker 30,000 dwt and above) without protectively located SBTs
  • C. A crude tanker of 20,000 dwt and above (product tanker 30,000 dwt and above) that complies with the SBT/PL requirements
  • D. Any oil tanker below 5,000 tonnes deadweight
Answer: C — A crude tanker of 20,000 dwt and above (product tanker 30,000 dwt and above) that complies with the SBT/PL requirements
For the phase-out of single-hull tankers, Category 1 covered pre-MARPOL tankers of 20,000/30,000 dwt and above without protectively located SBTs. Category 2 covered tankers of the same size that met the MARPOL SBT/PL requirements, and Category 3 covered smaller tankers of 5,000 dwt and above.

13. What is the requirement for ships to carry a SOPEP on board?

  • A. SOPEP should be carried on board oil tankers of 150 GT or more and other ships of 400 GT or more
  • B. SOPEP should be carried on board oil tankers of 150 GT or more and on all other ships irrespective of size
  • C. SOPEP should be carried only on board tankers of 400 GT or more
  • D. SOPEP is required only on ships trading to US ports
Answer: A — SOPEP should be carried on board oil tankers of 150 GT or more and other ships of 400 GT or more
MARPOL Annex I Regulation 37 requires every oil tanker of 150 GT and above and every other ship of 400 GT and above to carry an approved Shipboard Oil Pollution Emergency Plan.

14. What does SECA stand for?

  • A. SOx Elimination Control Area
  • B. SOx Emission Control Area
  • C. SOx Escalation Control Area
  • D. Sulphur Exhaust Clean Air
Answer: B — SOx Emission Control Area
A SECA (SOx Emission Control Area) is a designated sea area under MARPOL Annex VI where a stricter fuel sulphur limit applies, currently 0.10% m/m, for example the Baltic, North Sea and North American ECAs.

15. What is the minimum requirement for carrying a Garbage Management Plan on board a ship?

  • A. Every ship of 100 GT and above, and every ship certified to carry 15 persons or more
  • B. Any ship which is 12 metres or more in length
  • C. All ships irrespective of size and length
  • D. Only ships of 400 GT and above
Answer: A — Every ship of 100 GT and above, and every ship certified to carry 15 persons or more
Revised MARPOL Annex V Regulation 10, in force from 2013, requires a Garbage Management Plan on every ship of 100 GT and above, ships certified to carry 15 or more persons, and fixed or floating platforms. Placards are required on ships of 12 m and above.

16. Outside Emission Control Areas, what is the current global maximum sulphur content of fuel oil used on board ships?

  • A. 0.50% m/m
  • B. 1.50% m/m
  • C. 3.50% m/m
  • D. 4.50% m/m
Answer: A — 0.50% m/m
Since 1 January 2020, MARPOL Annex VI Regulation 14 limits the sulphur content of fuel oil used outside ECAs to 0.50% m/m. The earlier global limit was 4.50% until 2012 and 3.50% until 2019, and within ECAs the limit is 0.10% m/m.

17. What is the main requirement of OPA 90?

  • A. New tankers and tank barges should have double hulls
  • B. New tankers and tank barges should not ply in US waters
  • C. New tankers and tank barges with single hulls can ply in US ports
  • D. New tankers must carry a US pilot at all times
Answer: A — New tankers and tank barges should have double hulls
The US Oil Pollution Act of 1990, passed after the Exxon Valdez spill, requires new tankers and tank barges trading in US waters to be double-hulled and phased out single-hull tankers. It also requires vessel response plans and certificates of financial responsibility.

18. After connecting the snap-on hydraulic couplings of a portable Framo pump, when is the arrangement considered safe?

  • A. Only after the couplings are secured with the locking ring
  • B. As soon as the coupling halves click together
  • C. Only after the hydraulic pressure is raised to maximum
  • D. Only after the couplings are wrapped with tape
Answer: A — Only after the couplings are secured with the locking ring
Snap-on hydraulic couplings can release under high hydraulic pressure or vibration. The manufacturer requires each coupling to be secured with its locking ring before pressurising, to prevent sudden disconnection and spraying of high-pressure hydraulic oil.

19. Which of the following is a type of closed tank gauging equipment fitted on tankers?

  • A. Radar gauge
  • B. Ullage tape through an open ullage port
  • C. Sounding rod
  • D. Hydrometer
Answer: A — Radar gauge
Radar gauges measure ullage by timing microwave reflections from the liquid surface through a sealed antenna, so no vapour escapes. The IBC Code classes them as closed gauging, whereas tapes and sounding rods used through open ports are open or restricted methods.

20. The hydrostatic pressure exerted by LNG at the bottom of a cargo tank is a function of ____.

  • A. Liquid density and liquid level
  • B. Tank volume only
  • C. Vapour temperature only
  • D. Tank surface area
Answer: A — Liquid density and liquid level
Hydrostatic pressure is the product of liquid density, gravity and liquid height (p = ρgh). Differential pressure level gauges use this principle, so the pressure at the tank bottom depends on the density and level of the LNG, not on tank volume or area.

21. When a flammable mixture ignites in an enclosed space, what is developed?

  • A. A rapid rise in pressure
  • B. A vacuum
  • C. No change in pressure
  • D. A drop in temperature
Answer: A — A rapid rise in pressure
Combustion of a confined flammable mixture rapidly raises temperature, and the gases expand, causing a sudden pressure rise of several times atmospheric. This explosion pressure can rupture tanks and structures, which is why tank atmospheres are kept inerted or below the LFL.

22. Intrinsically safe electrical equipment is designed so that ____.

  • A. Any spark or thermal effect it produces is incapable of igniting the flammable mixture
  • B. It can contain an internal explosion without rupturing
  • C. It is pressurised with air to keep gas out
  • D. It may only be used in gas-free areas
Answer: A — Any spark or thermal effect it produces is incapable of igniting the flammable mixture
Intrinsically safe circuits limit electrical energy and surface temperature so that no spark or thermal effect, in normal use or under specified fault conditions, can ignite the gas. Containing an internal explosion describes flameproof equipment, and pressurisation is a separate protection method.

23. In an electrical circuit, resistors are used to ____.

  • A. Limit the current flow
  • B. Store electrical charge
  • C. Increase the supply voltage
  • D. Convert AC to DC
Answer: A — Limit the current flow
A resistor opposes current flow (Ohm's law, I = V/R). In intrinsically safe barriers, resistors limit the current, and Zener diodes limit the voltage, so the energy reaching the hazardous area is too low to cause ignition.

24. In a flameproof (Ex d) enclosure, the narrow gap between flanged joints serves to ____.

  • A. Cool escaping hot gases so that they cannot ignite the outside atmosphere
  • B. Trap the hot gases permanently inside the enclosure
  • C. Allow fresh air to ventilate the enclosure
  • D. Drain condensed water from the enclosure
Answer: A — Cool escaping hot gases so that they cannot ignite the outside atmosphere
A flameproof enclosure can withstand an internal explosion. Hot gases do escape through the long, narrow flame path between the flanges, but they are cooled below the ignition temperature of the surrounding gas, so the explosion is not passed to the outside atmosphere.

25. During night helicopter operations, deck floodlights should be ____.

  • A. Directed so as not to dazzle the pilot
  • B. Pointed directly at the approaching helicopter
  • C. Switched off completely
  • D. Flashed on and off to signal the pilot
Answer: A — Directed so as not to dazzle the pilot
The ICS Guide to Helicopter/Ship Operations requires the operating area and obstructions to be well lit at night, but floodlights must be shielded and directed away from the helicopter so that the pilot's night vision is not impaired.

26. Putrefaction of cargoes such as animal and vegetable oils in a tank can result in ____.

  • A. Evolution of toxic gases and oxygen depletion
  • B. An increase in the oxygen content
  • C. Release of pure nitrogen that makes the tank safe
  • D. Formation of a breathable atmosphere
Answer: A — Evolution of toxic gases and oxygen depletion
As organic cargo residues decompose they consume oxygen and can give off toxic gases such as hydrogen sulphide and carbon dioxide. Tanks that have carried such cargoes must therefore be ventilated and tested for oxygen and toxic gases before entry.

27. Before entering a cargo tank, the presence of which of the following should always be suspected?

  • A. Cargo vapour or inert gas
  • B. Excess oxygen only
  • C. Steam
  • D. Fresh air
Answer: A — Cargo vapour or inert gas
Even after gas freeing, cargo tanks may hold pockets of hydrocarbon or toxic vapour and inert gas behind structures, in pipelines or released from residues and sludge. ISGOTT advises that these hazards always be suspected and the atmosphere tested at several levels.

28. Before testing the atmosphere of an enclosed space, ventilation should be stopped about ____ before the tests.

  • A. 10 minutes
  • B. 10 hours
  • C. 24 hours
  • D. 1 minute
Answer: A — 10 minutes
ISGOTT recommends stopping ventilation about 10 minutes before testing, so that the atmosphere settles and readings represent the true condition of the space rather than the diluting effect of the incoming fresh air.

29. In chemical tanker operations, what does the term PPE stand for?

  • A. Process Parameter Enhancement
  • B. Productivity and Profit Evaluation
  • C. Personal Protective Equipment
  • D. Production Planning Efficiency
Answer: C — Personal Protective Equipment
PPE stands for Personal Protective Equipment, such as chemical suits, gloves, goggles, face shields and breathing apparatus. The IBC Code Ch. 14 requires suitable protective equipment for crew engaged in cargo operations on chemical tankers.

30. Which safety measure is crucial when working with reactive chemicals?

  • A. Increased temperature
  • B. Adequate ventilation
  • C. Minimal PPE usage
  • D. Rapid handling
Answer: B — Adequate ventilation
Reactive chemicals may give off toxic or flammable vapours, so adequate ventilation, together with full PPE and careful handling, keeps vapour concentrations below exposure and flammable limits. Raising the temperature or rushing the job increases the hazard.

Set 18 — 30 CHEMCO exit exam questions with answers

1. What is the purpose of a Safety Data Sheet (SDS) for a chemical cargo?

  • A. Employee performance evaluation
  • B. Product advertising
  • C. Providing information on chemical hazards
  • D. Financial statement disclosure
Answer: C — Providing information on chemical hazards
An SDS (or MSDS) gives the hazards, safe handling, PPE, first aid, fire-fighting and spill measures for a product. SOLAS VI/5-1 requires an MSDS to be provided for MARPOL Annex I cargoes and fuel oil, and cargo information is mandatory for IBC Code products.

2. Which hazard symbol represents a substance that can catch fire easily?

  • A. Flame
  • B. Skull and crossbones
  • C. Exclamation mark
  • D. Corrosion
Answer: A — Flame
The flame pictogram, as used in GHS and the IMDG flammable classes, identifies flammable gases, liquids and solids. The skull and crossbones indicates acute toxicity, the exclamation mark indicates harmful or irritant substances, and the corrosion symbol indicates corrosives.

3. What is the primary function of a scrubber in air pollution control?

  • A. Increase emissions
  • B. Remove pollutants from exhaust gases
  • C. Enhance visibility in the environment
  • D. Produce harmful by-products
Answer: B — Remove pollutants from exhaust gases
An exhaust gas cleaning system (scrubber) washes exhaust gas, usually with seawater or caustic solution, to remove sulphur oxides and particulates. MARPOL Annex VI Reg. 4 accepts it as an equivalent means of meeting the sulphur limits.

4. In chemical storage and carriage, what is the purpose of segregating incompatible chemicals?

  • A. Simplify inventory management
  • B. Enhance colour coding
  • C. Prevent accidental reactions
  • D. Facilitate rapid disposal
Answer: C — Prevent accidental reactions
Incompatible products can react violently, producing heat, toxic gases or pressure, if they mix through leaks or common lines. The IBC Code and the USCG compatibility chart therefore require segregation, such as separate tanks, piping and venting, or cofferdams.

5. Which hazard symbol represents a substance that poses an immediate (acute) toxic health hazard?

  • A. Flame
  • B. Skull and crossbones
  • C. Exclamation mark
  • D. Corrosion
Answer: B — Skull and crossbones
The skull and crossbones pictogram indicates acute toxicity, meaning a substance that can cause death or serious harm after short exposure by swallowing, skin contact or inhalation, as with IMDG Class 6.1 toxic substances.

6. What does the term 'hazardous area classification' refer to?

  • A. Identifying areas with high productivity
  • B. Designating areas with potential fire or explosion risks
  • C. Analysing areas with minimal chemical exposure
  • D. Classifying areas based on marketing strategies
Answer: B — Designating areas with potential fire or explosion risks
Hazardous area classification divides spaces into zones 0, 1 and 2 according to how likely a flammable atmosphere is to be present (IEC 60092-502, IBC/IGC Codes). This determines which certified safe electrical equipment may be installed there.

7. What is the primary purpose of a chemical spill response plan?

  • A. Minimise public awareness
  • B. Maximise chemical production
  • C. Ensure rapid disposal of spilled chemicals
  • D. Minimise environmental and health risks
Answer: D — Minimise environmental and health risks
A spill response plan, such as the shipboard SMPEP, sets out reporting, containment and clean-up actions and the responsibilities of each crew member, so that a spill is dealt with quickly to reduce harm to people and the marine environment.

8. Under the IBC Code, cargo tanks of a ship type 1 must be located inboard from the side shell plating, at the summer load line, by at least:

  • A. B/5 or 11.5 m, whichever is less
  • B. B/15 or 2 m, whichever is less
  • C. 760 mm only
  • D. B/10 or 8 m, whichever is greater
Answer: A — B/5 or 11.5 m, whichever is less
IBC Code 2.6 requires type 1 ship cargo tanks to be at least B/5 or 11.5 m (whichever is less) inboard of the side shell, and never less than 760 mm from the shell plating, giving maximum protection against collision damage.

9. For both ship type 1 and ship type 2, the IBC Code requires cargo tanks to be located above the moulded line of the bottom shell plating at centreline by not less than:

  • A. B/15 or 6 m, whichever is less
  • B. B/5 or 11.5 m, whichever is less
  • C. 2 m in all cases
  • D. 760 mm in all cases
Answer: A — B/15 or 6 m, whichever is less
IBC Code 2.6 places type 1 and type 2 cargo tanks at least B/15 or 6 m (whichever is less) above the bottom shell at centreline, protecting them against grounding damage. Type 3 ships have no such location requirement.

10. For a ship type 2, the minimum distance of cargo tanks from the side shell plating required by the IBC Code is:

  • A. 760 mm
  • B. B/5
  • C. 11.5 m
  • D. No requirement
Answer: A — 760 mm
IBC Code 2.6.1.2 requires type 2 ship cargo tanks to be not less than 760 mm from the shell plating, plus the bottom clearance of B/15 or 6 m. The larger B/5 or 11.5 m side clearance applies only to type 1 ships.

11. Which IBC ship type is intended to carry products with sufficiently severe environmental and safety hazards that require the maximum preventive measures against cargo escape?

  • A. Ship type 1
  • B. Ship type 2
  • C. Ship type 3
  • D. Ship type 4
Answer: A — Ship type 1
IBC Code 2.1.2 defines a type 1 ship as a chemical tanker for products with very severe environmental and safety hazards requiring maximum preventive measures. Type 2 covers appreciably severe hazards and type 3 sufficiently severe hazards needing a moderate degree of containment.

12. Where in the IBC Code chapter 17 table is the minimum ship type for a product indicated?

  • A. Column e
  • B. Column c
  • C. Column f
  • D. Column k
Answer: A — Column e
In the IBC Code chapter 17 summary of minimum requirements, column e gives the ship type (1, 2 or 3). Column c gives the MARPOL pollution category, column f the tank type and column k the vapour detection requirement.

13. Under the IBC Code, the quantity of a product required to be carried in a ship type 1 must not exceed how much in any one tank?

  • A. 1,250 m3
  • B. 3,000 m3
  • C. 5,000 m3
  • D. 700 m3
Answer: A — 1,250 m3
IBC Code 16.1 limits a product required to be carried in a type 1 ship to 1,250 m3 in any one tank, and a product required to be carried in a type 2 ship to 3,000 m3 in any one tank, limiting the quantity released if a tank is breached.

14. A product whose chapter 17 entry requires ship type 2 is to be loaded. What is the largest volume of it the IBC Code permits in a single cargo tank?

  • A. 3,000 m3
  • B. 1,250 m3
  • C. 10,000 m3
  • D. 2,000 m3
Answer: A — 3,000 m3
IBC Code 16.1 limits products requiring a type 2 ship to 3,000 m3 in any one tank (1,250 m3 for type 1 products), so that the potential outflow from a damaged tank is restricted.

15. According to the IBC Code, a gravity tank is a tank having a design pressure at the top of the tank not greater than:

  • A. 0.07 MPa gauge
  • B. 0.7 MPa gauge
  • C. 0.007 MPa gauge
  • D. 0.25 MPa gauge
Answer: A — 0.07 MPa gauge
IBC Code chapter 4 defines a gravity tank as one with a design pressure not greater than 0.07 MPa gauge at the top of the tank; a pressure tank has a design pressure greater than 0.07 MPa gauge. Tank type is shown in column f of chapter 17.

16. Which description correctly defines an integral tank in the IBC Code?

  • A. A tank forming part of the ship's hull and stressed with the adjacent hull structure
  • B. A self-supporting tank not contributing to hull strength
  • C. A cylindrical pressure vessel mounted on deck
  • D. A tank used only for cargo residues and slops
Answer: A — A tank forming part of the ship's hull and stressed with the adjacent hull structure
IBC Code 4.1 defines an integral tank as a cargo containment envelope forming part of the ship's hull, stressed in the same manner and by the same loads as the contiguous hull structure. An independent tank is self-supporting and is not part of the hull structure.

17. Under the IBC Code, cargoes that react in a hazardous manner with each other must be segregated by a cofferdam, void space, pump room, empty tank or tank containing a mutually compatible cargo, and also have:

  • A. Separate pumping and piping systems and separate tank venting systems
  • B. A common vent riser fitted with a flame screen
  • C. A shared stripping line with a single blank flange
  • D. Only a portable hose connection between tanks
Answer: A — Separate pumping and piping systems and separate tank venting systems
IBC Code 3.1.4 requires mutually reactive cargoes to be separated by a cofferdam, void, pump room, empty tank or tank with a compatible cargo, and to have separate pumping, piping and venting systems so the cargoes cannot meet through shared equipment.

18. What gives stainless steel cargo tanks their resistance to corrosion?

  • A. A thin, self-healing chromium oxide passive film on the surface
  • B. A zinc-rich primer applied at the shipyard
  • C. Cathodic protection by magnesium anodes
  • D. A rubber lining bonded to the steel
Answer: A — A thin, self-healing chromium oxide passive film on the surface
Stainless steel resists corrosion because its chromium content forms a thin, invisible chromium oxide passive layer. If damaged or contaminated it must be re-passivated, typically with a nitric acid based solution, before carrying aggressive cargoes.

19. Why should seawater not be left standing in stainless steel cargo tanks for long periods?

  • A. Chlorides break down the passive film and cause pitting corrosion
  • B. Seawater hardens the steel and makes it brittle
  • C. Seawater dissolves the nickel content completely
  • D. Salt deposits increase the tank's design density
Answer: A — Chlorides break down the passive film and cause pitting corrosion
Chloride ions attack the passive chromium oxide film of stainless steel, causing localised pitting and crevice corrosion. Tanks washed with seawater are therefore given a final fresh-water rinse and dried promptly, which also prevents chloride contamination of the next cargo.

20. Which statement regarding phenolic epoxy tank coatings is correct?

  • A. They have wider chemical resistance than plain epoxy but must be checked against the coating maker's resistance list for each cargo
  • B. They are suitable for every cargo listed in the IBC Code without restriction
  • C. They cannot be used for any vegetable oils
  • D. They are the preferred coating for concentrated nitric acid
Answer: A — They have wider chemical resistance than plain epoxy but must be checked against the coating maker's resistance list for each cargo
Phenolic epoxies resist a broader range of chemicals than standard epoxy, but no coating is universal. The coating manufacturer's resistance list, including any restrictions on temperature, previous cargo and exposure time, must be checked before every cargo is accepted.

21. Under the IBC Code, cargo tanks must be segregated from machinery spaces, accommodation and service spaces and drinking-water and stores for human consumption by:

  • A. Cofferdams, void spaces, cargo pump rooms, empty tanks, oil fuel tanks or similar spaces
  • B. A single plate bulkhead only
  • C. Insulation panels with fire rating A-60 only
  • D. A water curtain system
Answer: A — Cofferdams, void spaces, cargo pump rooms, empty tanks, oil fuel tanks or similar spaces
IBC Code 3.1 requires cargo tanks (and residue and slop tanks) to be separated from machinery, accommodation and service spaces and from drinking water and stores by cofferdams, voids, cargo pump rooms, empty tanks, oil fuel tanks or similar spaces, avoiding single-bulkhead contact.

22. Mechanical ventilation of a cargo pump room on a chemical tanker under the IBC Code must provide at least:

  • A. 30 air changes per hour based on the total volume of the space
  • B. 6 air changes per hour
  • C. 2 air changes per hour
  • D. 45 air changes per hour
Answer: A — 30 air changes per hour based on the total volume of the space
IBC Code 12.1.6 requires ventilation of cargo handling spaces such as cargo pump rooms of not less than 30 changes of air per hour based on the total volume of the space, with exhaust drawn from below the floor plates where heavy vapours collect.

23. Under the IBC Code, high-velocity vent outlets of a controlled tank venting system must be at least what height above the weather deck or fore-and-aft gangway?

  • A. 3 m
  • B. 1 m
  • C. 6 m
  • D. 10 m
Answer: A — 3 m
IBC Code 8.3 requires controlled venting outlets to be at least 6 m above the weather deck or gangway, but this may be reduced to 3 m where approved high-velocity vent valves discharge vapour upward at not less than 30 m/s.

24. Under the IBC Code, controlled venting outlets must be located at least what horizontal distance from the nearest air intake or opening to accommodation, service and machinery spaces and from ignition sources?

  • A. 10 m
  • B. 3 m
  • C. 5 m
  • D. 25 m
Answer: A — 10 m
IBC Code 8.3 requires controlled venting outlets to be at least 10 m from the nearest air intake or opening to enclosed spaces containing ignition sources and from deck machinery or equipment that may be an ignition hazard.

25. What is the main advantage of fitting each cargo tank of a parcel chemical tanker with its own submerged deepwell pump and dedicated line?

  • A. Many grades can be carried and handled simultaneously with full segregation
  • B. It removes the need for any cargo tank venting
  • C. It allows cargo to be discharged without any shore manifold connection
  • D. It eliminates the need for tank cleaning between cargoes
Answer: A — Many grades can be carried and handled simultaneously with full segregation
On parcel tankers each tank normally has its own deepwell or submerged pump and a dedicated line to the manifold. This gives complete segregation between grades, reduces contamination risk and allows several parcels to be loaded or discharged at once.

26. What is the principal hazard if a shore emergency shutdown valve closes too quickly while a chemical tanker is loading at a high rate?

  • A. A pressure surge that may rupture hoses, loading arms or pipelines
  • B. Static discharge inside the cargo tank
  • C. An immediate vacuum in the cargo tank
  • D. Overheating of the cargo pump motor
Answer: A — A pressure surge that may rupture hoses, loading arms or pipelines
Rapid closure of a valve against a flowing liquid column converts the liquid's momentum into a pressure surge (liquid hammer). ESD valve closure times and loading rates must therefore be agreed between ship and terminal to keep surge pressures within hose and pipeline limits.

27. Under the IBC Code, ships carrying toxic or flammable products, or both, must be equipped with at least how many instruments designed and calibrated for testing the specific vapours?

  • A. Two
  • B. One
  • C. Three
  • D. Four
Answer: A — Two
IBC Code 13.2 requires ships carrying toxic or flammable products to carry at least two instruments designed and calibrated for testing for the specific vapours concerned. Column k of chapter 17 shows whether toxic (T) or flammable (F) vapour detection is needed.

28. In IBC Code chapter 17, the letters 'T' and 'F' in column k indicate:

  • A. Toxic and flammable vapour detection requirements
  • B. Temperature class and fire protection
  • C. Tank type and filling limit
  • D. Tripartite agreement and flag approval
Answer: A — Toxic and flammable vapour detection requirements
Column k of the IBC Code chapter 17 table gives the vapour detection requirement: T means toxic vapour detection and F means flammable vapour detection. Both may be required for the same product.

29. Why must the high-level alarm on a cargo tank be independent of the tank gauging system?

  • A. So that failure of the gauge does not also disable the overfill warning
  • B. So that it can be used instead of the gauge for cargo calculations
  • C. So that it only operates when the ship is in port
  • D. So that it can be reset by the terminal
Answer: A — So that failure of the gauge does not also disable the overfill warning
An independent high-level alarm provides a second barrier against overfilling. If the primary gauging system fails or gives a false reading, the independent alarm still warns the operator in time to stop loading or divert the flow.

30. When a chemical tanker uses a vapour emission control (vapour return) system, which monitoring arrangement is required in the vapour collection main?

  • A. A pressure sensor with high and low pressure alarms
  • B. A flow meter with a totaliser only
  • C. A temperature sensor with a high temperature trip only
  • D. A sight glass at the manifold
Answer: A — A pressure sensor with high and low pressure alarms
IMO guidance on vapour emission control systems (MSC/Circ.585) requires the vapour collection main to have a pressure sensor giving high and low pressure alarms, so that over-pressure or vacuum in the tanks is detected before the P/V valves or tanks are overstressed.

Set 19 — 30 CHEMCO exit exam questions with answers

1. How is the ship's vapour manifold connection identified to prevent it being confused with a liquid cargo connection?

  • A. Painted red/yellow/red bands with the word VAPOUR stencilled near the flange
  • B. Painted entirely green with an arrow
  • C. Fitted with a blue flange only
  • D. Marked only on the cargo plan
Answer: A — Painted red/yellow/red bands with the word VAPOUR stencilled near the flange
Under IMO vapour emission control guidance and OCIMF recommendations, the vapour manifold is marked with yellow and red bands and the word VAPOUR, and is fitted with a stud to prevent a liquid hose being connected to it by mistake.

2. During discharge of a cargo with a hydraulically driven submerged pump, which reading on the cofferdam purging of the pump indicates a possible cargo seal leak?

  • A. Cargo liquid or vapour found when the pump cofferdam is purged
  • B. Hydraulic oil pressure steady at the normal working value
  • C. Normal discharge pressure at the manifold
  • D. Ambient temperature in the cargo control room
Answer: A — Cargo liquid or vapour found when the pump cofferdam is purged
Submerged hydraulic pumps have a cofferdam between the cargo seal and hydraulic seal. Regular purging of this cofferdam, before and after operations, reveals cargo or hydraulic oil leakage early so that the pump can be repaired before cargo contaminates the hydraulic system or vice versa.

3. For a heated cargo, why is the cargo temperature monitored and recorded at regular intervals during the voyage?

  • A. To keep it within the shipper's limits and the coating and adjacent cargo limits
  • B. To calculate the ship's fuel consumption
  • C. To check the accuracy of the ullage tape only
  • D. To decide the ballast water exchange sequence
Answer: A — To keep it within the shipper's limits and the coating and adjacent cargo limits
Overheating can damage coatings, trigger polymerisation or affect adjacent heat-sensitive cargoes, while underheating can allow cargo to solidify. Regular monitoring and records of cargo temperature show that heating instructions were followed and protect the ship in claims.

4. What should be done before cargo operations start regarding the emergency shutdown arrangements between ship and shore?

  • A. Test the ESD system and agree its activation method and closure times
  • B. Disconnect the ESD link to avoid spurious trips
  • C. Leave the ESD for the terminal to operate alone
  • D. Test the ESD only after the first hour of loading
Answer: A — Test the ESD system and agree its activation method and closure times
The ship/shore safety checklist requires the emergency shutdown procedures and system to be agreed and tested before transfer begins, including how each side will activate it and valve closure times, so that flow can be stopped safely in an emergency.

5. Which action is appropriate when the cargo tank high-level alarm sounds unexpectedly during loading?

  • A. Stop or divert the flow to that tank immediately and verify the level by an independent means
  • B. Silence the alarm and continue at the same rate
  • C. Increase the loading rate to finish the tank sooner
  • D. Open the tank's ullage port to relieve pressure
Answer: A — Stop or divert the flow to that tank immediately and verify the level by an independent means
A high-level alarm means the tank is approaching its filling limit. The flow to that tank must be stopped or diverted at once and the actual level checked independently before resuming, since a faulty gauge may already have allowed the tank to fill beyond its planned ullage.

6. What does the oxygen analyser on a nitrogen-padded chemical tank help to confirm?

  • A. That the oxygen content in the ullage space remains below the required level
  • B. That the cargo has not polymerised
  • C. That the cargo density is within specification
  • D. That the tank coating is intact
Answer: A — That the oxygen content in the ullage space remains below the required level
When a cargo requires inerting or padding, the ullage space oxygen level must be monitored to show that the nitrogen blanket is effective, preventing a flammable atmosphere or oxidation of air-sensitive cargoes. The readings should be recorded.

7. What is the purpose of a tank pressure monitoring system on a chemical tanker fitted with closed venting?

  • A. To give early warning of over-pressure or vacuum before P/V valves lift or the tank is damaged
  • B. To measure cargo density
  • C. To indicate the remaining stripping quantity
  • D. To show the hydraulic oil pressure of the pump
Answer: A — To give early warning of over-pressure or vacuum before P/V valves lift or the tank is damaged
Closed loading and discharging can quickly raise or lower tank pressure. Pressure monitoring with alarms allows the operator to adjust rates, vapour return or nitrogen supply before the pressure/vacuum valves lift or the tank structure is overstressed.

8. Which functional group is characteristic of alcohols such as methanol and ethanol?

  • A. Hydroxyl group (-OH)
  • B. Carbonyl group within a carbon chain (C=O)
  • C. Carboxyl group (-COOH)
  • D. Amino group (-NH2)
Answer: A — Hydroxyl group (-OH)
Alcohols contain the hydroxyl (-OH) group attached to a carbon atom. Ketones contain a carbonyl group, organic acids a carboxyl group and amines an amino group. The functional group largely determines the cargo's reactivity and compatibility.

9. Acetone and methyl ethyl ketone belong to which chemical group?

  • A. Ketones
  • B. Esters
  • C. Alcohols
  • D. Aldehydes
Answer: A — Ketones
Acetone and methyl ethyl ketone (MEK) are ketones, containing a carbonyl group bonded to two carbon atoms. They are widely used industrial solvents and are aggressive to some tank coatings, so coating resistance lists must be checked.

10. Benzene, toluene and xylene are classified as:

  • A. Aromatic hydrocarbons
  • B. Aliphatic alcohols
  • C. Glycols
  • D. Inorganic acids
Answer: A — Aromatic hydrocarbons
Benzene, toluene and xylene are aromatic hydrocarbons, built on the benzene ring. They are flammable, mostly insoluble in water and float on it, and have toxic effects; benzene is a recognised human carcinogen.

11. Why does methanol present a particular hazard when it burns?

  • A. It burns with a nearly invisible flame in daylight
  • B. It cannot be extinguished by any foam
  • C. It produces large quantities of black smoke
  • D. It explodes on contact with water
Answer: A — It burns with a nearly invisible flame in daylight
Methanol burns with a pale blue flame that is very hard to see in daylight, so a fire may go unnoticed and people may walk into it. Thermal imaging or heat detection is useful, and alcohol-resistant foam or water is used because methanol is water-miscible.

12. Approximately what is the relative density of concentrated (about 98%) sulphuric acid?

  • A. 1.83
  • B. 1.03
  • C. 0.79
  • D. 1.25
Answer: A — 1.83
Concentrated sulphuric acid has a relative density of about 1.83, nearly twice that of water. Such high-density cargoes usually cannot fill a tank completely without exceeding its design loading, which limits filling heights and must be checked against the loading manual.

13. Under MARPOL Annex II, a high-viscosity substance is a Category X or Y noxious liquid substance with a viscosity at the unloading temperature of:

  • A. 50 mPa·s or more
  • B. 5 mPa·s or more
  • C. 20 mPa·s or more
  • D. 500 mPa·s or more
Answer: A — 50 mPa·s or more
MARPOL Annex II regulation 1 defines a high-viscosity substance as a Category X or Y NLS with a viscosity of 50 mPa·s or more at the unloading temperature. Such substances require a prewash before the ship leaves the port of unloading.

14. Under MARPOL Annex II, a substance with a melting point below 15°C is a solidifying substance if, at the time of unloading, its temperature is:

  • A. Less than 5°C above its melting point
  • B. Less than 10°C above its melting point
  • C. More than 15°C above its melting point
  • D. Below 0°C
Answer: A — Less than 5°C above its melting point
MARPOL Annex II regulation 1 defines a solidifying substance as one with a melting point below 15°C that is less than 5°C above its melting point at unloading, or one with a melting point of 15°C or more that is less than 10°C above its melting point at unloading.

15. Paraffin wax has a melting point well above 15°C. Under MARPOL Annex II it is treated as a solidifying substance at unloading if its temperature then is:

  • A. Less than 10°C above its melting point
  • B. Less than 5°C above its melting point
  • C. Less than 2°C above its melting point
  • D. Exactly at its boiling point
Answer: A — Less than 10°C above its melting point
For a noxious liquid substance with a melting point of 15°C or above, MARPOL Annex II regulation 1 treats it as solidifying when its unloading temperature is less than 10°C above the melting point. The margin is 5°C for substances melting below 15°C.

16. Most chemical cargo vapours have a vapour density greater than 1. What is the practical consequence on deck and in enclosed spaces?

  • A. Vapours tend to sink and collect in low points such as pump room bilges and under decks
  • B. Vapours rise rapidly and disperse above the masthead
  • C. Vapours are always harmless once released
  • D. Vapours only collect near the funnel
Answer: A — Vapours tend to sink and collect in low points such as pump room bilges and under decks
A vapour heavier than air flows along the deck and gathers in low spaces, sumps, pump room bottoms and enclosed spaces. This is why pump room exhausts draw from below floor plates and gas testing must cover the lower levels of a space.

17. Which chemical cargo is fully miscible with water?

  • A. Methanol
  • B. Benzene
  • C. Toluene
  • D. Xylene
Answer: A — Methanol
Methanol mixes completely with water in all proportions, whereas benzene, toluene and xylene are practically insoluble and float. Miscibility affects spill behaviour, choice of fire-fighting medium (alcohol-resistant foam for water-miscible liquids) and tank cleaning method.

18. What does the vapour pressure of a chemical cargo indicate?

  • A. Its tendency to evaporate; the higher the vapour pressure, the more vapour it releases at a given temperature
  • B. Its resistance to flow
  • C. The temperature at which it solidifies
  • D. Its density compared with water
Answer: A — Its tendency to evaporate; the higher the vapour pressure, the more vapour it releases at a given temperature
Vapour pressure is the pressure exerted by the vapour in equilibrium with the liquid at a given temperature. Cargoes with high vapour pressure evaporate readily, producing more vapour that may be toxic or flammable and placing greater demand on venting and vapour return systems.

19. How does the viscosity of most liquid chemical cargoes change when they are heated?

  • A. It decreases, making the cargo easier to pump
  • B. It increases sharply
  • C. It remains unchanged
  • D. It falls to zero above 40°C
Answer: A — It decreases, making the cargo easier to pump
Heating reduces the viscosity of most liquids, which is why viscous cargoes are heated before and during discharge to improve pumping and stripping. Heating must stay within the shipper's instructions and the coating and adjacent-cargo limits.

20. Which hazard grouping on the IBC Code chapter 17 table is shown by the letter 'S' in column d?

  • A. Safety hazard
  • B. Solidifying cargo
  • C. Special area restriction
  • D. Stainless steel tank required
Answer: A — Safety hazard
Column d of IBC Code chapter 17 shows the hazard basis for the product's requirements: S for safety hazards, P for pollution hazards, and S/P for both. This drives whether full safety provisions or mainly pollution provisions apply.

21. Which group of substances includes caustic soda solution and aqueous ammonia?

  • A. Alkalis (bases)
  • B. Mineral acids
  • C. Aromatic hydrocarbons
  • D. Esters
Answer: A — Alkalis (bases)
Caustic soda (sodium hydroxide) solution and aqueous ammonia are alkalis, with a pH above 7. They are corrosive to skin and eyes, react exothermically with acids and attack certain metals such as aluminium, zinc and copper alloys.

22. Which statement about esters such as vinyl acetate and ethyl acetate is correct?

  • A. They are formed from an acid and an alcohol and are generally flammable solvents
  • B. They are inorganic acids
  • C. They are non-flammable inert gases
  • D. They are always solid at ambient temperature
Answer: A — They are formed from an acid and an alcohol and are generally flammable solvents
Esters are organic compounds formed by reacting an acid with an alcohol. Ethyl acetate and vinyl acetate are flammable liquids with low flash points; vinyl acetate monomer can also polymerise and is shipped with an inhibitor.

23. Which property mainly determines whether a cargo spilled in water will float, sink or dissolve?

  • A. Its density and solubility in water
  • B. Its flash point alone
  • C. Its auto-ignition temperature
  • D. Its colour on the Pt-Co scale
Answer: A — Its density and solubility in water
A spilled chemical that is insoluble and lighter than water floats, one that is denser sinks, and a soluble one dissolves. These properties, shown in the SDS and used in GESAMP hazard profiles, determine spill behaviour and response.

24. Phenol, paraffin wax and some fatty acids are carried heated mainly because they have:

  • A. High melting points and solidify at ambient temperature
  • B. Very low flash points
  • C. Very high vapour pressures
  • D. Low densities
Answer: A — High melting points and solidify at ambient temperature
Cargoes with high melting points solidify in the tank and lines if not kept above their melting point. They are carried heated within the shipper's instructions and, under MARPOL Annex II, may be solidifying substances requiring a prewash if unloaded too close to the melting point.

25. Which organisation's hazard evaluation of substances forms the basis for assigning MARPOL Annex II pollution categories?

  • A. GESAMP (Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection)
  • B. OCIMF
  • C. SIGTTO
  • D. Chemical Distribution Institute
Answer: A — GESAMP (Joint Group of Experts on the Scientific Aspects of Marine Environmental Protection)
The GESAMP Evaluation of the Hazards of Harmful Substances Carried by Ships produces hazard profiles covering bioaccumulation, toxicity and effects on human health and amenities. MARPOL Annex II Appendix I uses these profiles to assign categories X, Y and Z.

26. Why should a tank of inhibited styrene monomer not be stowed adjacent to a tank carrying a cargo heated to a high temperature?

  • A. Heat speeds up polymerisation and depletes the inhibitor, which can lead to a runaway reaction
  • B. Heat raises the flash point of styrene above the safe limit
  • C. Heat causes styrene to separate into water and hydrocarbon layers
  • D. Heat makes styrene incompatible with stainless steel
Answer: A — Heat speeds up polymerisation and depletes the inhibitor, which can lead to a runaway reaction
Polymerisation is exothermic and self-accelerating; heat transferred from an adjacent hot cargo increases the reaction rate and consumes the inhibitor faster, so heat-sensitive monomers must be kept away from heated tanks and their temperature monitored.

27. Some inhibitors used in monomer cargoes are oxygen-dependent. What does this mean for the atmosphere in the cargo tank?

  • A. A minimum oxygen level must be kept in the vapour space, so the tank must not be fully inerted
  • B. The tank must be inerted to below 1% oxygen before loading
  • C. The tank must be ventilated continuously with fresh air during the voyage
  • D. The cargo must be padded with carbon dioxide instead of nitrogen
Answer: A — A minimum oxygen level must be kept in the vapour space, so the tank must not be fully inerted
An oxygen-dependent inhibitor needs a small amount of dissolved oxygen to work. The IBC Code (15.13) requires the inhibitor certificate to state the minimum oxygen level needed in the vapour space, so complete inerting could make the inhibitor ineffective.

28. Isocyanates such as TDI and MDI are carried under dry nitrogen mainly because they:

  • A. React with water or moist air, forming solids and carbon dioxide that can pressurise the tank
  • B. Are pyrophoric and ignite spontaneously in air
  • C. Polymerise only when exposed to nitrogen-free atmospheres
  • D. Have a flash point below ambient temperature
Answer: A — React with water or moist air, forming solids and carbon dioxide that can pressurise the tank
Isocyanates react with water, including moisture in air, producing insoluble ureas and carbon dioxide gas. This contaminates the cargo and can build pressure in a closed tank, so tanks and lines must be perfectly dry and the cargo kept under dry nitrogen padding.

29. Which pair of cargoes would be shown as incompatible on a cargo compatibility chart and must not be stowed in adjacent tanks without proper segregation?

  • A. Sulphuric acid and caustic soda solution
  • B. Toluene and xylene
  • C. Methanol and ethanol
  • D. Palm oil and soybean oil
Answer: A — Sulphuric acid and caustic soda solution
A strong mineral acid and a strong alkali react violently with the release of a great deal of heat. Compatibility charts such as the USCG chart (46 CFR Part 150) mark such reactive group combinations as unsafe, requiring segregation by cofferdam or other approved separation.

30. Why must acrylic acid be prevented from freezing during the voyage?

  • A. When it freezes, the inhibitor separates from the crystals and the thawed liquid may be uninhibited and polymerise
  • B. Frozen acrylic acid expands and ruptures stainless steel tanks
  • C. Freezing converts acrylic acid into a toxic gas
  • D. Frozen acrylic acid cannot be tested for inhibitor content
Answer: A — When it freezes, the inhibitor separates from the crystals and the thawed liquid may be uninhibited and polymerise
Acrylic acid freezes at about 13°C. On freezing the inhibitor concentrates in the remaining liquid, leaving crystals with little protection; careless or local overheating during thawing can then start violent polymerisation, so temperature is kept within the shipper's range.

Set 20 — 30 CHEMCO exit exam questions with answers

1. Why are zinc and aluminium unsuitable materials for tanks and fittings in caustic soda (sodium hydroxide) service?

  • A. Strong alkalis attack these metals and generate flammable hydrogen gas
  • B. They catalyse polymerisation of caustic soda
  • C. They become electrostatically charged by the cargo
  • D. They absorb the cargo and change its concentration
Answer: A — Strong alkalis attack these metals and generate flammable hydrogen gas
Sodium hydroxide solution reacts with amphoteric metals such as zinc and aluminium, dissolving them and releasing hydrogen. This damages zinc silicate coatings and fittings and can create a flammable atmosphere, so stainless steel, mild steel or a suitable coating is used instead.

2. Concentrated sulphuric acid can be carried in mild steel tanks, but dilution with water is dangerous because:

  • A. Diluted acid attacks mild steel rapidly and releases hydrogen, besides the heat generated on mixing
  • B. Diluted acid becomes flammable
  • C. Diluted acid polymerises and solidifies in the lines
  • D. Diluted acid stops conducting electricity, causing static build-up
Answer: A — Diluted acid attacks mild steel rapidly and releases hydrogen, besides the heat generated on mixing
Concentrated sulphuric acid forms a protective iron sulphate layer on mild steel, but when water is added the diluted acid becomes highly corrosive to steel, producing hydrogen gas. Mixing is also strongly exothermic, so water must be kept out of tanks and lines.

3. Aqueous ammonia should not be handled with fittings made of which material?

  • A. Copper and copper alloys such as brass
  • B. Stainless steel
  • C. Mild steel
  • D. Polytetrafluoroethylene (PTFE) gaskets
Answer: A — Copper and copper alloys such as brass
Ammonia solutions attack copper, brass and zinc-containing alloys, causing corrosion and cargo contamination. Cargo-handling equipment for ammonia solutions is therefore made of steel or stainless steel, and the material compatibility tables of the cargo information must be checked.

4. Nitric acid must be kept well segregated from organic cargoes such as alcohols, oils and solvents mainly because it is:

  • A. A strong oxidising agent that can react violently or ignite organic materials
  • B. A polymerising cargo that needs an inhibitor
  • C. Heavier-than-air flammable vapour
  • D. Water-reactive, releasing hydrogen
Answer: A — A strong oxidising agent that can react violently or ignite organic materials
Concentrated nitric acid is a powerful oxidiser. In contact with organic substances it can cause vigorous exothermic reactions, toxic nitrous fumes and fire, so compatibility charts list it as incompatible with most organic cargo groups and spills must not be absorbed with sawdust or rags.

5. A cargo tank has a total capacity of 1,000 m3 and may be filled to 98% at the highest temperature expected on passage, 50°C. The cargo density is 0.900 t/m3 at the loading temperature of 20°C and 0.876 t/m3 at 50°C. What is the maximum volume that may be loaded at 20°C?

  • A. About 954 m3
  • B. 980 m3
  • C. About 1,007 m3
  • D. About 931 m3
Answer: A — About 954 m3
The maximum volume at 50°C is 0.98 × 1,000 = 980 m3, a mass of 980 × 0.876 = 858.5 t. At 20°C this mass occupies 858.5 / 0.900 = 953.9 m3, so about 954 m3 may be loaded to leave room for thermal expansion.

6. A cargo tank holds 2,500 m3 of cargo at standard temperature (15°C) with a density at 15°C of 0.8500 t/m3. Using the usual air buoyancy deduction of 0.0011, what is the weight of cargo in air?

  • A. 2,122.25 t
  • B. 2,125.00 t
  • C. 2,127.75 t
  • D. 2,941.18 t
Answer: A — 2,122.25 t
Weight in air is the standard volume multiplied by the density in vacuum minus 0.0011: 2,500 × (0.8500 − 0.0011) = 2,500 × 0.8489 = 2,122.25 t. Multiplying by the vacuum density alone gives the mass in vacuum, which is slightly greater.

7. The gross observed volume in a cargo tank is 1,200 m3 at 30°C and the volume correction factor for that temperature is 0.9850. What is the volume at standard temperature?

  • A. 1,182 m3
  • B. 1,218 m3
  • C. 1,200 m3
  • D. 1,170 m3
Answer: A — 1,182 m3
Volume at standard temperature equals the observed volume multiplied by the volume correction factor: 1,200 × 0.9850 = 1,182 m3. The factor is less than 1 because the cargo is warmer than 15°C and has expanded.

8. A shipper nominates 1,500 t of a chemical with a density of 1.250 t/m3 at the loading temperature. What volume will this cargo occupy in the tank?

  • A. 1,200 m3
  • B. 1,875 m3
  • C. 1,250 m3
  • D. 1,500 m3
Answer: A — 1,200 m3
Volume equals mass divided by density: 1,500 / 1.250 = 1,200 m3. For high-density cargoes the tank may be well below its normal filling limit while still carrying its maximum permitted mass, so both volume and mass must be checked.

9. 1,000 m3 of cargo is loaded at 20°C. Its coefficient of cubical expansion is 0.0010 per °C and it will be heated to 40°C on passage. Approximately what volume will it occupy when heated?

  • A. 1,020 m3
  • B. 1,002 m3
  • C. 1,200 m3
  • D. 980 m3
Answer: A — 1,020 m3
Expanded volume = original volume × (1 + coefficient × temperature rise) = 1,000 × (1 + 0.0010 × 20) = 1,020 m3. This is why the ullage left at loading must allow for the temperature the cargo will reach during heating.

10. A rectangular slack cargo tank is 20 m long and 10 m wide and contains a liquid of density 1.0 t/m3. The ship's displacement is 10,000 t. What is the virtual loss of GM due to free surface?

  • A. About 0.17 m
  • B. About 0.02 m
  • C. About 0.67 m
  • D. About 1.67 m
Answer: A — About 0.17 m
Free surface moment = density × l × b³ / 12 = 1.0 × 20 × 1,000 / 12 = 1,666.7 t·m. The loss of GM is this moment divided by displacement: 1,666.7 / 10,000 = 0.167 m, about 0.17 m.

11. Under MARPOL Annex I regulation 27, which applies to oil tankers of 5,000 dwt and above including product/chemical tankers certified for oil, what minimum initial metacentric height, corrected for free surface, is required in port?

  • A. 0.15 m
  • B. 0.05 m
  • C. 0.30 m
  • D. 0.50 m
Answer: A — 0.15 m
Regulation 27 requires that in port the initial metacentric height GMo, corrected for free surface measured at 0° heel, shall be not less than 0.15 m, and that the IS Code criteria be met at sea in every loading condition, including intermediate stages of liquid transfer.

12. Under the 2014 amendments to MARPOL Annex I and the IBC Code, chemical tankers constructed on or after 1 January 2016 must be fitted with:

  • A. A stability instrument capable of verifying compliance with intact and damage stability requirements
  • B. A ballast water treatment system with cargo tank monitoring
  • C. A fixed cargo vapour recovery plant
  • D. A hull stress monitoring system with strain gauges on deck
Answer: A — A stability instrument capable of verifying compliance with intact and damage stability requirements
Resolutions MSC.369(93) and MEPC.248(66) require oil and chemical tankers to carry a stability instrument able to verify intact and damage stability, applying to new ships from 1 January 2016 and to existing ships by their first renewal survey after that date, and not later than 1 January 2021.

13. When a high-density cargo such as concentrated sulphuric acid is to be carried in a tank designed for a lower cargo density, what is the correct approach?

  • A. Fill the tank only partially so the cargo mass stays within the design limit, checking any sloshing restrictions
  • B. Fill the tank to 98% as with any other cargo
  • C. Dilute the cargo with water to reduce its density
  • D. Carry the cargo only in deck tanks
Answer: A — Fill the tank only partially so the cargo mass stays within the design limit, checking any sloshing restrictions
Tank structure is designed for a maximum cargo density at full filling. A heavier cargo must be loaded to a reduced level so its weight does not overstress the tank, and the approved loading manual's limits on partial filling and sloshing must be observed.

14. How do the permissible shear force and bending moment limits for harbour conditions normally compare with the seagoing limits shown in the loading manual?

  • A. Harbour limits are higher, because wave-induced loads are not present in port
  • B. Harbour limits are lower, because the ship is moored
  • C. Both are always identical
  • D. Harbour limits apply only when ballasting
Answer: A — Harbour limits are higher, because wave-induced loads are not present in port
Seagoing limits allow for additional wave bending and shear loads, so the permissible still-water values in port are generally higher. The ship must, however, be within seagoing limits before departure and at every intermediate stage of a loading or discharge sequence planned for sea.

15. Loading heavy cargo in the end tanks while the midship tanks are left empty will tend to make the ship:

  • A. Hog
  • B. Sag
  • C. List to port
  • D. Trim by the head only
Answer: A — Hog
Concentrating weight at the ends while buoyancy remains greatest amidships causes the hull to bend with the middle higher than the ends, which is hogging. The loading computer is used to keep bending moments and shear forces within limits at every stage.

16. Why must the loading sequence of a chemical tanker be checked on the loading computer for intermediate stages and not only for the final condition?

  • A. Stress, stability and trim limits can be exceeded at an intermediate stage even when the final condition is acceptable
  • B. The loading computer can only calculate intermediate stages
  • C. The final condition never affects stresses
  • D. It is required only for ships carrying Category X cargoes
Answer: A — Stress, stability and trim limits can be exceeded at an intermediate stage even when the final condition is acceptable
Parcel tankers load and discharge many tanks in sequence, often with slack tanks and ballast changes. Shear forces, bending moments, free surface and GM can pass through critical values during the operation, so each stage must be verified before it is carried out.

17. According to the IBC Code, a ship type 3 chemical tanker is intended to carry products with:

  • A. Sufficiently severe environmental and safety hazards to require a moderate degree of containment to increase survival capability
  • B. The most severe hazards requiring maximum preventive measures
  • C. No safety hazards at all
  • D. Only liquefied gases under pressure
Answer: A — Sufficiently severe environmental and safety hazards to require a moderate degree of containment to increase survival capability
IBC Code 2.1.2 defines ship type 3 for products with sufficiently severe hazards to require a moderate degree of containment in the damaged condition. Ship type 1 is for the most severe hazards and ship type 2 for products requiring significant preventive measures.

18. Duplex stainless steel is increasingly used for chemical tanker cargo tanks because it:

  • A. Combines austenitic and ferritic structures, giving higher strength and better resistance to chloride stress corrosion
  • B. Does not need any cleaning between cargoes
  • C. Is immune to attack by all acids
  • D. Is cheaper and lighter than mild steel
Answer: A — Combines austenitic and ferritic structures, giving higher strength and better resistance to chloride stress corrosion
Duplex grades such as 2205 have a mixed austenitic-ferritic microstructure. They offer higher strength than 316L, allowing thinner plating, and better resistance to pitting and chloride stress corrosion cracking, but they are still attacked by some cargoes and need correct cleaning.

19. After a stainless steel tank surface has been contaminated with iron particles or damaged, which treatment restores its corrosion resistance?

  • A. Pickling and passivation, usually with a nitric acid based solution
  • B. Painting with zinc silicate
  • C. Washing with hot seawater
  • D. Applying a cathodic protection anode
Answer: A — Pickling and passivation, usually with a nitric acid based solution
Pickling removes contamination and the damaged surface layer, and passivation with an oxidising acid solution rebuilds the protective chromium oxide film. Without this treatment rust spots and pitting can develop and contaminate sensitive cargoes.

20. Before a newly coated epoxy cargo tank can carry cargo, what must be ensured?

  • A. The coating has fully cured according to the manufacturer's time and temperature requirements
  • B. The tank has been filled with seawater for one week
  • C. The coating has been covered with a layer of oil
  • D. The coating is at least one year old
Answer: A — The coating has fully cured according to the manufacturer's time and temperature requirements
Epoxy and phenolic epoxy coatings achieve their chemical resistance only after full curing, which depends on time and temperature, sometimes with post-curing by heating. Loading cargo too early can soften or damage the coating and contaminate the cargo.

21. Under SOLAS chapter II-2, cargo pump rooms of tankers must be fitted with a system for continuous monitoring of hydrocarbon gas concentration, with an alarm set at not higher than:

  • A. 10% of the lower flammable limit
  • B. 50% of the lower flammable limit
  • C. 100% of the lower flammable limit
  • D. 1% by volume of oxygen
Answer: A — 10% of the lower flammable limit
SOLAS II-2/4.5.10 requires sampling points or detector heads in suitable locations in cargo pump rooms so that leakages are promptly detected, with continuous audible and visual alarms in the pump room, engine control room, cargo control room and navigation bridge at not higher than 10% LFL.

22. For cargo pumps in a pump room driven by shafts passing through the pump room bulkhead, SOLAS requires:

  • A. Temperature sensing devices for the bulkhead shaft glands, bearings and pump casings
  • B. A fixed water spray system on each pump
  • C. Pumps to be stopped every two hours for inspection
  • D. A vapour return line from each pump
Answer: A — Temperature sensing devices for the bulkhead shaft glands, bearings and pump casings
SOLAS II-2/4.5.10.1 requires temperature sensing devices on bulkhead shaft glands, bearings and pump casings, with continuous audible and visual alarm in the cargo control room or pump control station, since overheating of these parts is a known ignition source in pump rooms.

23. Which monitoring arrangement is required by SOLAS in the cargo pump room bilges of a tanker?

  • A. Bilge level monitoring devices with appropriately located alarms
  • B. An oxygen analyser in each bilge well
  • C. A sounding pipe only
  • D. A fixed CO2 nozzle in each bilge
Answer: A — Bilge level monitoring devices with appropriately located alarms
SOLAS II-2/4.5.10.1 requires bilge level monitoring devices with alarms in cargo pump rooms so that a leakage of cargo or water collecting in the bilges is detected early and can be dealt with before it becomes a fire or toxic hazard.

24. For the same liquid, how does the closed-cup flash point normally compare with the open-cup flash point?

  • A. The closed-cup value is lower
  • B. The closed-cup value is higher
  • C. They are always the same
  • D. Closed-cup values are used only for solids
Answer: A — The closed-cup value is lower
In the closed-cup test vapour is retained above the liquid, so a flammable mixture forms at a lower temperature than in the open cup, where vapour disperses. Closed-cup flash points are used for ship classification purposes because they are lower and therefore conservative.

25. A solution with a pH of 3 compared with a solution of pH 5 has a hydrogen ion concentration that is:

  • A. 100 times greater
  • B. 2 times greater
  • C. 20 times greater
  • D. 100 times smaller
Answer: A — 100 times greater
The pH scale is logarithmic: each unit decrease means a tenfold increase in hydrogen ion concentration. A difference of two units therefore means 10 × 10 = 100 times more hydrogen ions, so the pH 3 solution is much more strongly acidic.

26. Sodium hydroxide has a molar mass of 40 g/mol. What mass of sodium hydroxide is contained in 1 litre of a 1 molar (1 mol/L) solution?

  • A. 40 g
  • B. 1 g
  • C. 20 g
  • D. 400 g
Answer: A — 40 g
Molarity is the number of moles of solute per litre of solution. One litre of 1 mol/L sodium hydroxide therefore contains one mole, which is 40 g, the sum of the atomic masses of sodium (23), oxygen (16) and hydrogen (1).

27. What happens to the boiling point of a liquid cargo when the pressure above it is reduced?

  • A. It falls, so the liquid boils at a lower temperature
  • B. It rises
  • C. It does not change
  • D. It becomes equal to the flash point
Answer: A — It falls, so the liquid boils at a lower temperature
A liquid boils when its vapour pressure equals the surrounding pressure. Lowering the pressure, for example by drawing a vacuum in a tank or on a pump suction, lowers the boiling temperature, which is why volatile cargoes can flash off and cause cavitation at pump suctions.

28. When preparing a stowage plan for a parcel chemical tanker, which check must be made for every nominated product before allocating it to a tank?

  • A. That the product is listed on the ship's Certificate of Fitness and the allocated tank meets its ship type, tank coating and equipment requirements
  • B. That the product has the same flash point as the previous cargo
  • C. That the product is lighter than water
  • D. That the shipper has supplied a bill of lading in advance
Answer: A — That the product is listed on the ship's Certificate of Fitness and the allocated tank meets its ship type, tank coating and equipment requirements
A product may be carried only if it is named on the list of products attached to the Certificate of Fitness, and only in tanks meeting the chapter 17 requirements for ship type, tank type, venting, gauging and environmental control, with coating or steel compatibility confirmed.

29. In planning tank allocation, which combination should be avoided?

  • A. A heat-sensitive cargo in a tank sharing a bulkhead with a cargo that will be heated
  • B. Two compatible solvents in tanks separated by a cofferdam
  • C. A heated cargo in a tank with heating coils
  • D. A cargo that needs nitrogen padding in a tank connected to the nitrogen system
Answer: A — A heat-sensitive cargo in a tank sharing a bulkhead with a cargo that will be heated
Heat passing through a common bulkhead can raise the temperature of a heat-sensitive or self-reactive product beyond its safe limit, or damage its quality. The cargo plan must consider adjacent temperatures as well as chemical compatibility and segregation.

30. Before loading a heated cargo, why are the heating coils of the tank pressure-tested?

  • A. To ensure there are no leaks that could let cargo into the heating system or heating medium into the cargo
  • B. To calibrate the tank temperature sensors
  • C. To verify the setting of the P/V valve
  • D. To remove air from the cargo lines
Answer: A — To ensure there are no leaks that could let cargo into the heating system or heating medium into the cargo
A leaking coil can contaminate the cargo with water or thermal oil, or allow cargo to enter the heating system and condensate return, creating fire, toxicity or contamination hazards elsewhere on board. Coils are therefore tested and blanked if not to be used.

Set 21 — 30 CHEMCO exit exam questions with answers

1. What is the main purpose of taking a 'first foot' sample at the start of loading?

  • A. To check the cargo quality in the tank and line before the bulk of the parcel is loaded, so contamination is detected early
  • B. To measure the ullage after one foot of loading
  • C. To calibrate the shore flow meter
  • D. To test the high-level alarm
Answer: A — To check the cargo quality in the tank and line before the bulk of the parcel is loaded, so contamination is detected early
Loading is stopped after a small quantity, about one foot of cargo, has entered the tank, and samples are analysed. If the cargo is contaminated by the tank or lines, the problem affects only a small quantity and loading can be stopped before the whole parcel is spoiled.

2. Why is loading started at a slow rate before increasing to the agreed maximum rate?

  • A. To confirm cargo is entering the correct tank and there are no leaks before increasing flow
  • B. To allow the cargo to cool in the lines
  • C. To let the shore pumps warm up
  • D. To reduce the vapour pressure of the cargo
Answer: A — To confirm cargo is entering the correct tank and there are no leaks before increasing flow
At the initial slow rate the officer checks that the correct tank valves are open, the cargo is reaching the nominated tank, no other tank level is rising, and the manifold and lines are tight. Only then is the rate increased as agreed with the terminal.

3. For a static accumulator cargo loaded into a tank that is not inerted, what initial flow velocity limit is recommended by ISGOTT until the tank inlet is well covered?

  • A. 1 m/s in the branch line to the tank
  • B. 7 m/s
  • C. 12 m/s
  • D. No limit if the cargo is chemical
Answer: A — 1 m/s in the branch line to the tank
Splashing and high flow rates generate static charge in non-conducting cargoes. ISGOTT recommends limiting the linear velocity in the tank inlet branch to 1 m/s until the inlet is submerged and splashing has stopped, after which the rate can be increased within limits.

4. When topping off a cargo tank, which practice is correct?

  • A. Give the terminal advance notice, reduce the loading rate and never close the last valve against the full flow
  • B. Close all tank valves quickly at the same time
  • C. Increase the rate so the tank fills before the next tank is opened
  • D. Rely only on the overfill alarm to stop loading
Answer: A — Give the terminal advance notice, reduce the loading rate and never close the last valve against the full flow
Topping off is a critical stage: the terminal must be told in good time to reduce rate, tanks are topped one at a time under close watch, and valves are not closed against the flow, which could cause pressure surge or force cargo into other tanks.

5. At the end of loading, the shore line is blown clear into the ship with nitrogen or compressed air. Which precaution is most important?

  • A. Keep a receiving tank with sufficient ullage open and control the gas pressure to avoid overflow, splashing or overpressurising the tank
  • B. Close all tank valves so the gas stays in the line
  • C. Open the ullage ports of all tanks
  • D. Blow the line at maximum available pressure to finish quickly
Answer: A — Keep a receiving tank with sufficient ullage open and control the gas pressure to avoid overflow, splashing or overpressurising the tank
Line blowing pushes a slug of liquid followed by a large volume of gas into the tank. The receiving tank must have ullage and venting capacity, the gas pressure and volume must be agreed and controlled, and the operation watched to prevent overflow, cargo mist and tank overpressure.

6. During discharge of a nitrogen-padded cargo, what must be done to maintain the tank atmosphere?

  • A. Supply nitrogen into the tank to replace the volume of liquid discharged and prevent air entry or vacuum
  • B. Open the ullage port to let in fresh air
  • C. Stop the P/V valve from operating
  • D. Discharge only half the tank and leave the rest on board
Answer: A — Supply nitrogen into the tank to replace the volume of liquid discharged and prevent air entry or vacuum
As liquid leaves the tank a matching volume of gas must enter. For padded cargoes this is nitrogen from the ship's or shore supply, which keeps oxygen and moisture out and prevents the vacuum valve from drawing in air or the tank structure being exposed to vacuum.

7. Why may a high-viscosity cargo need to be heated before and during discharge?

  • A. To reduce viscosity for pumping and stripping and, under MARPOL Annex II, to keep it above the temperature at which it becomes high-viscosity or solidifying
  • B. To increase its vapour pressure for vapour return
  • C. To raise its flash point
  • D. To kill bacteria in the cargo
Answer: A — To reduce viscosity for pumping and stripping and, under MARPOL Annex II, to keep it above the temperature at which it becomes high-viscosity or solidifying
Heating lowers viscosity, improving pump performance and stripping. Under Annex II, viscosity and solidification are judged at the unloading temperature, so keeping the cargo at the required temperature can avoid it being classed as high-viscosity or solidifying and needing a mandatory prewash.

8. What should be checked daily during the passage for cargoes in transit on a chemical tanker?

  • A. Tank pressures, cargo temperatures, padding/inert pressure, cofferdam and void space condition, and inhibitor expiry for inhibited cargoes
  • B. Only the ullages of empty tanks
  • C. Only the main engine fuel consumption
  • D. The bill of lading quantities
Answer: A — Tank pressures, cargo temperatures, padding/inert pressure, cofferdam and void space condition, and inhibitor expiry for inhibited cargoes
Care of cargo in transit includes monitoring tank pressure and temperature, maintaining nitrogen padding or inerting, checking for leakage into cofferdams or adjacent spaces, and confirming inhibited cargoes remain within the inhibitor's effective life, with readings recorded.

9. Several grades are loaded at the same time through different manifolds. Which measure is most important to prevent cross-contamination?

  • A. Positive segregation of each line by blanks or double valve separation and verification of every valve before starting
  • B. Using one common line for all grades and flushing it between parcels
  • C. Loading all grades at the same rate
  • D. Keeping the crossover valves open to equalise pressure
Answer: A — Positive segregation of each line by blanks or double valve separation and verification of every valve before starting
Each parcel must follow its own line from manifold to tank. Line segregation, usually two valves or a blank between grades, is checked against the line-up drawing, and valve settings are double-checked before flow starts so that no grade can enter another grade's system.

10. Under ISGOTT, who must complete the Ship/Shore Safety Checklist?

  • A. The responsible officer of the ship and the terminal representative, jointly
  • B. The master only
  • C. The terminal representative only
  • D. The charterer's surveyor
Answer: A — The responsible officer of the ship and the terminal representative, jointly
The Ship/Shore Safety Checklist is a joint document. The responsible officer and the terminal representative check each item, agree on operational limits and communications, and sign it before transfer starts, with repetitive checks made at agreed intervals during the operation.

11. What is the purpose of the pre-transfer conference between ship and terminal before chemical cargo operations?

  • A. To agree the cargo grades, sequence, rates, pressures, emergency stop procedures and communications
  • B. To agree the freight rate
  • C. To decide which crew members may go ashore
  • D. To settle cargo quantity disputes from the previous port
Answer: A — To agree the cargo grades, sequence, rates, pressures, emergency stop procedures and communications
Before transfer the ship and terminal exchange information on cargo properties and hazards, nominated quantities, sequence and maximum rates, line and manifold pressure limits, venting or vapour return, emergency shutdown and signals, so both sides operate to one agreed plan.

12. Which information must the ship have about every cargo before it is loaded, under IBC Code 16.2?

  • A. A full description of physical and chemical properties including reactivity, actions in case of spills or leaks, countermeasures against personal contact, and fire-fighting procedures
  • B. Only the commercial name and quantity
  • C. The price of the cargo and buyer's name
  • D. The cargo's country of origin
Answer: A — A full description of physical and chemical properties including reactivity, actions in case of spills or leaks, countermeasures against personal contact, and fire-fighting procedures
IBC Code 16.2 requires that cargo information be on board and available to all concerned, including properties, reactivity, spill actions, personal contact countermeasures, fire-fighting media and procedures, and transfer, tank cleaning, gas-freeing and ballasting procedures. Cargo not accompanied by this information must not be loaded.

13. What is the correct action if, during loading, the level is found rising in a tank that is not supposed to receive cargo?

  • A. Stop loading immediately, find the cause such as an open valve or leaking valve, and correct it before restarting
  • B. Continue loading and correct it after completion
  • C. Open the tank's ullage port and monitor
  • D. Increase the rate to finish quickly
Answer: A — Stop loading immediately, find the cause such as an open valve or leaking valve, and correct it before restarting
An unexpected level rise means cargo is going to the wrong tank, possibly mixing grades or overflowing an unprepared tank. Cargo transfer must be stopped, the terminal informed, the line-up checked and the problem corrected before transfer resumes.

14. Before the first cargo enters a tank, which inspection is normally carried out by the cargo surveyor and ship's officer?

  • A. Visual inspection of the tank for cleanliness and dryness, and wall-wash results where required, followed by issue of a tank acceptance certificate
  • B. Inspection of the engine room bilges
  • C. Inspection of the crew accommodation
  • D. Testing of the lifeboat engine
Answer: A — Visual inspection of the tank for cleanliness and dryness, and wall-wash results where required, followed by issue of a tank acceptance certificate
Sensitive chemical cargoes require tanks, lines and pumps to be clean, dry and odour-free. The surveyor inspects the tanks, may take wall-wash samples for analysis and, if satisfied, issues an acceptance certificate before loading begins.

15. When ballasting a chemical tanker during cargo discharge, the main purpose of following the planned ballast sequence is to:

  • A. Keep stress, stability, trim and draught within limits throughout the operation
  • B. Wash the cargo tanks with ballast water
  • C. Avoid using the ballast pump
  • D. Increase the cargo pump discharge rate
Answer: A — Keep stress, stability, trim and draught within limits throughout the operation
As cargo leaves the ship, ballast is taken in a planned sequence so that bending moments, shear forces, GM, trim, air draft and propeller immersion remain within limits at every stage, and the ship is ready for sea at completion.

16. Under the STCW and MLC rest-hour rules, what is the minimum rest that a seafarer involved in cargo operations must have?

  • A. 10 hours in any 24-hour period and 77 hours in any 7-day period
  • B. 6 hours in any 24-hour period and 42 hours in any 7-day period
  • C. 8 hours in any 24-hour period and 56 hours in any 7-day period
  • D. 12 hours in any 24-hour period and 84 hours in any 7-day period
Answer: A — 10 hours in any 24-hour period and 77 hours in any 7-day period
STCW regulation VIII/1 and MLC 2006 standard A2.3 require at least 10 hours of rest in any 24-hour period, in no more than two periods one of which is at least 6 hours, and 77 hours in any 7-day period, which must be planned into cargo watch rotas.

17. Why should the cargo operation plan be discussed with and signed by all officers and crew involved before operations start?

  • A. So everyone understands the sequence, hazards, their responsibilities and the stop and emergency procedures
  • B. Because the terminal will not supply cargo otherwise
  • C. To satisfy the requirements of the bill of lading
  • D. So that only the chief officer needs to be present during operations
Answer: A — So everyone understands the sequence, hazards, their responsibilities and the stop and emergency procedures
Supervising personnel with cargo responsibilities includes briefing them on the plan, cargo hazards from the SDS, PPE, critical stages and emergency actions. A signed plan confirms understanding and supports safe handovers between watches.

18. What is the main reason for keeping cargo manifolds fitted with drip trays and the scuppers plugged during transfer?

  • A. To contain any leakage or spill on deck and prevent it going overboard
  • B. To collect rainwater for washing
  • C. To keep the deck dry for cargo sampling
  • D. To reduce static electricity
Answer: A — To contain any leakage or spill on deck and prevent it going overboard
Leakages are most likely at hose or arm connections. Drip trays under the manifold and plugged scuppers contain spills so they can be cleaned up and prevent pollution of the water, while spill equipment is kept ready near the manifold.

19. When connecting a cargo hose or reducer to the manifold, which practice is correct?

  • A. Use a gasket suitable for the cargo and fit bolts in every bolt hole, tightened evenly
  • B. Use any spare gasket available
  • C. Fit only half the bolts to allow quick disconnection
  • D. Use a rubber gasket for all cargoes
Answer: A — Use a gasket suitable for the cargo and fit bolts in every bolt hole, tightened evenly
The joint must be tight against the cargo and the agreed pressure. Gasket material must be compatible with the product, for example PTFE for many aggressive chemicals, and every bolt hole must be used with properly tightened bolts so the connection cannot leak.

20. During discharge, the terminal cannot accept cargo at the agreed rate and back pressure at the manifold rises. What should the ship do?

  • A. Reduce the pump rate to stay within the agreed maximum manifold pressure and consult the terminal
  • B. Increase the pump speed to overcome the back pressure
  • C. Close the manifold valve quickly while the pump runs
  • D. Open the manifold drain to relieve pressure
Answer: A — Reduce the pump rate to stay within the agreed maximum manifold pressure and consult the terminal
Exceeding the agreed manifold pressure can rupture hoses or arms. The ship must keep within the agreed pressure and rate, adjusting pump speed as necessary, and never close valves against a running pump, which would cause surge and pump damage.

21. Why is it important to record the times of starting and stopping cargo operations, rates, pressures and any stoppages during transfer?

  • A. They form the operational record needed for safety review, quantity disputes and statutory entries such as the Cargo Record Book
  • B. They are needed only for crew overtime
  • C. They are required only by the vessel's flag for ships over 20 years
  • D. They replace the ullage report
Answer: A — They form the operational record needed for safety review, quantity disputes and statutory entries such as the Cargo Record Book
Accurate cargo logs support investigation of incidents and claims, show compliance with agreed rates and pressures, and provide the information for Cargo Record Book entries, notices of protest and time sheets.

22. What is the safest method to clear cargo remaining in a deepwell pump discharge line at the end of discharge?

  • A. Use the pump's purging connection to blow the line to shore with nitrogen or air at controlled pressure
  • B. Open the line drain to deck
  • C. Leave the cargo in the line for the next voyage
  • D. Flush the line with seawater into the sea
Answer: A — Use the pump's purging connection to blow the line to shore with nitrogen or air at controlled pressure
Deepwell pumps are fitted with purging arrangements so that the riser and discharge line can be blown clear with nitrogen or compressed air towards the shore, completing discharge and reducing residues without releasing cargo on deck or overboard.

23. Before loading a cargo that requires the tank to be dry, which check is appropriate?

  • A. Confirm the tank, lines and pump are free of water and, if specified, measure the dew point of the tank atmosphere
  • B. Fill the tank with fresh water and then pump it out
  • C. Measure the cargo's flash point
  • D. Check the pH of the ballast water
Answer: A — Confirm the tank, lines and pump are free of water and, if specified, measure the dew point of the tank atmosphere
Water-sensitive cargoes require tanks and systems to be dried thoroughly, often by ventilating with dry air or nitrogen. Where 'Dry' is required in column h of chapter 17, the dew point of the inert or drying gas and tank atmosphere is checked to confirm moisture is low enough.

24. A tank's P/V valve is normally set for the venting system pressure. When a cargo requires a different setting or the vapour return line is used, what must the officer do before loading?

  • A. Confirm that the venting arrangement and settings for each tank meet the product's requirements and agree vapour pressure limits with the terminal
  • B. Close the P/V valve completely during loading
  • C. Open the tank ullage hatch for free venting
  • D. Remove the flame screens to increase venting capacity
Answer: A — Confirm that the venting arrangement and settings for each tank meet the product's requirements and agree vapour pressure limits with the terminal
The type of venting required for each product is given in column g of chapter 17. The officer must ensure the correct venting line-up, check P/V valves are free and correctly set, and when using vapour return agree the maximum loading rate and vapour pressure with the terminal.

25. What is the main hazard of loading a cargo into a tank containing residues of an incompatible previous cargo?

  • A. A dangerous reaction producing heat, gas or toxic products, as well as cargo contamination
  • B. Only a minor change in colour
  • C. Reduction in the ship's draught
  • D. Increase in the tank's design pressure
Answer: A — A dangerous reaction producing heat, gas or toxic products, as well as cargo contamination
Even small residues can react with a new cargo, for example an acid with an alkali or a monomer with a catalyst. Tanks, lines and pumps must be cleaned to the required standard and compatibility with the previous cargo checked when planning the next load.

26. Which reagent is used in the wall-wash chloride test, a white cloudiness indicating chlorides from seawater washing?

  • A. Silver nitrate solution
  • B. Potassium permanganate solution
  • C. Phenolphthalein indicator
  • D. Sodium hydroxide solution
Answer: A — Silver nitrate solution
In the chloride test, silver nitrate is added to the wall-wash sample; chloride ions form insoluble silver chloride, seen as white turbidity compared with a standard. The result shows whether seawater salt has been adequately removed by the fresh water rinse.

27. Which liquid is most commonly used as the wall-wash solvent when testing tank surfaces before loading a high-purity cargo?

  • A. High-purity methanol
  • B. Seawater
  • C. Diesel oil
  • D. Caustic soda solution
Answer: A — High-purity methanol
High-purity methanol is sprayed onto selected bulkhead areas and collected; it dissolves traces of previous cargo, hydrocarbons and chlorides. The sample is then tested for chlorides, hydrocarbons, colour and permanganate time against the specification for the next cargo.

28. In a wall-wash hydrocarbon (water miscibility) test, demineralised water is added to the methanol sample. What indicates the presence of hydrocarbons?

  • A. The mixture becomes cloudy or hazy
  • B. The mixture turns pink
  • C. Gas bubbles are given off
  • D. The mixture remains perfectly clear
Answer: A — The mixture becomes cloudy or hazy
Methanol is fully miscible with water, but hydrocarbons are not. If hydrocarbon residues are present, adding water causes them to come out of solution, producing turbidity that is compared with standards; a clear mixture indicates the tank meets the requirement.

29. Why is a final rinse with fresh or demineralised water given after washing a tank with seawater before loading a sensitive cargo?

  • A. To remove the chloride salts left by seawater, which cause wall-wash failure and pitting of stainless steel
  • B. To raise the temperature of the tank
  • C. To remove the tank coating
  • D. To inert the tank
Answer: A — To remove the chloride salts left by seawater, which cause wall-wash failure and pitting of stainless steel
Seawater leaves chloride residues on tank surfaces. These fail the chloride specification of many cargoes and attack the passive film on stainless steel. A fresh water rinse followed by drying removes the salts before inspection and wall-wash testing.

30. Which reference publication is widely used on chemical tankers for recommended tank cleaning procedures for each product?

  • A. Dr. Verwey's Tank Cleaning Guide
  • B. The IAMSAR Manual
  • C. The International Code of Signals
  • D. The Ship's Routeing guide
Answer: A — Dr. Verwey's Tank Cleaning Guide
The Tank Cleaning Guide by Dr. Verwey lists products with their properties and recommended cleaning methods, such as water temperature, use of detergents and whether a cold prewash is needed, and is used together with the P&A Manual and company procedures.

Set 22 — 33 CHEMCO exit exam questions with answers

1. Under MARPOL Annex II, which is designated as a special area for noxious liquid substances?

  • A. The Antarctic area
  • B. The Mediterranean Sea
  • C. The Red Sea
  • D. The Gulf of Aden
Answer: A — The Antarctic area
Annex II regulation 13.8 designates only the Antarctic area (south of latitude 60°S) as a special area, where any discharge into the sea of noxious liquid substances or mixtures containing them is prohibited.

2. After unloading a Category X substance, the prewash residue must be discharged to a reception facility until the concentration of the substance in the effluent is at or below:

  • A. 0.1% by weight
  • B. 1% by weight
  • C. 5% by weight
  • D. 10 ppm
Answer: A — 0.1% by weight
Annex II regulation 13.6.1 requires a prewash for Category X before the ship leaves the unloading port, with the resulting residues discharged ashore until the concentration in the effluent, as shown by surveyor's analysis, is 0.1% by weight or less.

3. Under MARPOL Annex II, cargo residues may be removed from a tank by ventilation instead of washing when the substance has a vapour pressure at 20°C greater than:

  • A. 5 kPa
  • B. 0.5 kPa
  • C. 50 kPa
  • D. 101.3 kPa
Answer: A — 5 kPa
Regulation 13.3 allows residues of substances with a vapour pressure greater than 5 kPa at 20°C to be removed by ventilation following the procedures of Appendix 7 of Annex II and the P&A Manual; any water subsequently introduced is regarded as clean.

4. For how long must the Cargo Record Book be kept on board after the last entry is made?

  • A. Three years
  • B. One year
  • C. Five years
  • D. Until the next renewal survey
Answer: A — Three years
Annex II regulation 15 requires the Cargo Record Book to be kept readily available for inspection and retained on board for a period of three years after the last entry, with each operation entered and signed by the officer in charge and each page by the master.

5. Ballast introduced into a cargo tank that has been washed so that the ballast contains less than what concentration of the previous substance may be discharged without regard to discharge rate, speed and outlet location?

  • A. 1 ppm
  • B. 10 ppm
  • C. 100 ppm
  • D. 0.1%
Answer: A — 1 ppm
Under Annex II regulation 13, ballast water in a tank washed so that it contains less than 1 ppm of the substance previously carried may be discharged without regard to discharge rate, ship speed and discharge outlet location, provided the ship is at least 12 nautical miles from land in water at least 25 m deep.

6. Since the revised MARPOL Annex II entered into force on 1 January 2007, vegetable oils such as palm oil are generally:

  • A. Category Y substances that must be carried in at least ship type 2 chemical tankers
  • B. Category Z substances carried in any tanker
  • C. Oils under MARPOL Annex I
  • D. Other Substances with no carriage requirements
Answer: A — Category Y substances that must be carried in at least ship type 2 chemical tankers
The 2007 revision reassessed vegetable oils as Category Y, with chapter 17 of the IBC Code requiring ship type 2 for most of them. Limited exemptions for certain ship type 3 or non-chemical tankers were allowed only under strict conditions set by the Administration.

7. A ship that is not self-propelled may discharge permitted Category Y or Z residue mixtures only if it is proceeding at a speed of at least:

  • A. 4 knots
  • B. 7 knots
  • C. 2 knots
  • D. 12 knots
Answer: A — 4 knots
Regulation 13.2.2 requires self-propelled ships to be en route at not less than 7 knots and ships that are not self-propelled at not less than 4 knots, discharging below the waterline through underwater outlets at no more than the design rate.

8. In which circumstance may a mandatory prewash after unloading a Category X, or a high-viscosity or solidifying Category Y substance, be exempted by the Administration's surveyor?

  • A. When the tank is to be reloaded with the same or a compatible substance and will not be washed or ballasted before loading
  • B. When the ship is in a hurry to sail
  • C. When the next port is within the same country
  • D. When the residue quantity is more than 75 litres
Answer: A — When the tank is to be reloaded with the same or a compatible substance and will not be washed or ballasted before loading
Regulation 13.4 allows exemption from prewash if the unloaded tank is to be reloaded with the same or another compatible substance, or if residues will be removed by ventilation, or if the ship will discharge to a reception facility elsewhere; the surveyor endorses the Cargo Record Book.

9. Amendments to MARPOL Annex II in force from 1 January 2021 require a prewash for certain persistent floating products when unloading in ports of which areas?

  • A. North West European waters, the Baltic Sea, Western European waters and the Norwegian Sea
  • B. The Red Sea and the Gulf of Aden
  • C. The Caribbean Sea and the Gulf of Mexico
  • D. The Arabian Sea and the Bay of Bengal
Answer: A — North West European waters, the Baltic Sea, Western European waters and the Norwegian Sea
Resolution MEPC.315(74) introduced a mandatory prewash and discharge ashore of residues of persistent floating products, high-viscosity or solidifying substances that float and persist on the sea surface, after unloading in ports within these four European sea areas.

10. Under MARPOL Annex II, a Category Z substance is one which, if discharged into the sea from tank cleaning or deballasting operations, is deemed to present:

  • A. A minor hazard to marine resources or human health, justifying less stringent restrictions
  • B. A major hazard justifying a total prohibition of discharge
  • C. No harm at all, so it falls outside all categories
  • D. A hazard only to air quality
Answer: A — A minor hazard to marine resources or human health, justifying less stringent restrictions
Regulation 6 defines Category X as a major hazard with discharge prohibited, Category Y as a hazard justifying limits on quality and quantity, and Category Z as a minor hazard with less stringent restrictions. Other Substances are considered harmless and are not subject to Annex II.

11. A shipper wishes to ship a liquid product that is not yet categorised under MARPOL Annex II or listed in the IBC Code. What is required before it can be carried?

  • A. A provisional assessment agreed between the governments of the producing or shipping country, the flag State and the receiving country (tripartite agreement)
  • B. Only the master's consent
  • C. A certificate from the charterer
  • D. Nothing, as uncategorised products are treated as Other Substances
Answer: A — A provisional assessment agreed between the governments of the producing or shipping country, the flag State and the receiving country (tripartite agreement)
Annex II regulation 6.3 requires unassessed products to be provisionally categorised by the governments concerned under a tripartite agreement, based on the guidelines, before carriage. IMO publishes these agreements annually in the MEPC.2/Circular lists.

12. Which statement about the Procedures and Arrangements Manual is correct?

  • A. It follows the standard format of Appendix 4 of Annex II, is approved by the Administration and identifies the ship's arrangements and operational procedures for cargo handling, tank cleaning, slops and ballasting
  • B. It is prepared by the master and needs no approval
  • C. It is required only on ships trading in special areas
  • D. It replaces the Cargo Record Book
Answer: A — It follows the standard format of Appendix 4 of Annex II, is approved by the Administration and identifies the ship's arrangements and operational procedures for cargo handling, tank cleaning, slops and ballasting
Regulation 14 requires every ship certified to carry noxious liquid substances in bulk to have an approved P&A Manual in the standard format. It describes the equipment and procedures needed to comply with Annex II, including stripping, prewash, ventilation and discharge of residues.

13. Which of these operations must be entered in the Cargo Record Book of a chemical tanker?

  • A. Ballasting of cargo tanks
  • B. Bunkering of fuel oil
  • C. Discharge of sewage
  • D. Disposal of food waste
Answer: A — Ballasting of cargo tanks
The Annex II Cargo Record Book (Appendix 2) covers loading, internal transfer and unloading of cargo, mandatory prewash, tank cleaning, discharge of tank washings, ballasting of cargo tanks and discharge of ballast from them, accidental discharges and surveyor control. Fuel, sewage and garbage are recorded under other annexes.

14. Where a mandatory prewash has been carried out in the unloading port, who verifies it and makes the endorsement in the Cargo Record Book?

  • A. A surveyor appointed or authorised by the Government of the receiving Party
  • B. The terminal loading master
  • C. The ship's chief engineer
  • D. The cargo owner's representative
Answer: A — A surveyor appointed or authorised by the Government of the receiving Party
Annex II regulation 16 makes the receiving Party's appointed or authorised surveyors responsible for verifying that prewash and discharge to reception facilities have been carried out as required, and for endorsing the relevant Cargo Record Book entries or granting exemptions.

15. What is the maximum period of validity of the International Certificate of Fitness for the Carriage of Dangerous Chemicals in Bulk?

  • A. Five years
  • B. Two years
  • C. Three years
  • D. One year
Answer: A — Five years
Under IBC Code 1.5, the Certificate of Fitness is issued for a period specified by the Administration not exceeding five years, subject to annual and intermediate surveys being endorsed on the certificate.

16. Which chemical tankers are required to comply with the IBC Code rather than the older BCH Code?

  • A. Ships constructed on or after 1 July 1986
  • B. Ships constructed before 1 July 1986
  • C. All ships regardless of age, from 1 January 2021 only
  • D. Only ships of 20,000 dwt and above
Answer: A — Ships constructed on or after 1 July 1986
The IBC Code is mandatory under SOLAS chapter VII and MARPOL Annex II for chemical tankers constructed on or after 1 July 1986. Ships built before that date are covered by the BCH Code.

17. In IBC Code chapter 17, what does the letter 'A' in column l (fire protection) indicate?

  • A. Alcohol-resistant foam or multi-purpose foam
  • B. Regular foam only
  • C. Water spray
  • D. Dry chemical powder only
Answer: A — Alcohol-resistant foam or multi-purpose foam
Column l shows the fire-extinguishing media: A for alcohol-resistant or multi-purpose foam, B for regular foam (including all foams not alcohol-resistant), C for water spray and D for dry chemical. Products that destroy ordinary foam, such as alcohols and ketones, need type A.

18. In IBC Code chapter 17, the entry 'C' in column j indicates that the product requires:

  • A. Closed gauging
  • B. Controlled venting
  • C. Category C pollution
  • D. Cofferdam segregation
Answer: A — Closed gauging
Column j gives the gauging requirement: O for open, R for restricted and C for closed gauging. Closed gauging, such as radar or float systems, does not allow any cargo vapour to escape and is required for toxic and certain other hazardous products.

19. In IBC Code chapter 17, the term 'Pad' in column h (tank environmental control) means:

  • A. The ullage space is filled and maintained with a liquid, gas or vapour that separates the cargo from the air
  • B. The tank must be dried to a low dew point
  • C. The tank must be ventilated with fresh air
  • D. The cargo is carried in a padded deck tank
Answer: A — The ullage space is filled and maintained with a liquid, gas or vapour that separates the cargo from the air
Column h may show Inert, Pad, Dry or Vent. Padding means filling the ullage space, and associated piping where required, with a liquid, gas or vapour that separates the cargo from the air and maintains that condition, often using nitrogen.

20. Which chapter of the IBC Code lists products to which the Code does not apply because their safety and pollution hazards are low?

  • A. Chapter 18
  • B. Chapter 17
  • C. Chapter 19
  • D. Chapter 15
Answer: A — Chapter 18
Chapter 17 is the summary of minimum requirements, chapter 18 lists products to which the Code does not apply, though some are still subject to MARPOL Annex II as Category Z or OS, and chapter 19 is the index of product names with their synonyms.

21. For ships carrying products for which column n of chapter 17 shows 'Yes', IBC Code 14.3 requires emergency escape respiratory and eye protection for every person on board. What minimum duration must it provide?

  • A. At least 15 minutes
  • B. At least 5 minutes
  • C. At least 30 minutes
  • D. At least 60 minutes
Answer: A — At least 15 minutes
IBC Code 14.3.1 requires respiratory and eye protection for emergency escape for every person on board, with self-contained sets normally giving at least 15 minutes of service; filter types are accepted only when one filter suits all cargoes listed on the Certificate of Fitness.

22. According to IBC Code chapter 14, where must decontamination showers and an eyewash be provided on chemical tankers carrying products that require them?

  • A. On deck in suitably marked convenient locations, operable in all ambient conditions
  • B. Only in the ship's hospital
  • C. Only in the engine room
  • D. Only inside the accommodation entrance
Answer: A — On deck in suitably marked convenient locations, operable in all ambient conditions
IBC Code 14.3.3 requires suitably marked decontamination showers and an eyewash on deck in convenient locations, depending on the size and layout of the ship, and they must be operable in all ambient conditions so contaminated persons can be washed immediately.

23. What does the attachment to the International Certificate of Fitness of a chemical tanker contain?

  • A. The list of products the ship is permitted to carry with their conditions of carriage and tanks
  • B. The crew list and their certificates
  • C. The cargo manifest of the current voyage
  • D. The ship's radio licence
Answer: A — The list of products the ship is permitted to carry with their conditions of carriage and tanks
The Certificate of Fitness is supplemented by a list of products the ship is certified to carry, with any conditions such as allowed tanks, ship type and special requirements. Only products named in that list may be loaded.

24. Which chapter of the IBC Code contains the criteria for assigning carriage requirements to products, used when evaluating new products?

  • A. Chapter 21
  • B. Chapter 11
  • C. Chapter 16
  • D. Chapter 4
Answer: A — Chapter 21
IBC Code Chapter 21 sets out the criteria for assigning carriage requirements for products subject to the Code.

25. In IBC Code chapter 17, what does 'Yes' in column i''' indicate?

  • A. The product has a flash point exceeding 60°C (closed cup test)
  • B. The product requires electrical equipment of group IIC
  • C. The product is toxic
  • D. The product must be inhibited
Answer: A — The product has a flash point exceeding 60°C (closed cup test)
Column i gives electrical equipment requirements: i' temperature class, i'' apparatus group, and i''' whether the flash point exceeds 60°C closed cup. Where it is 'Yes', the product does not require the electrical equipment provisions for flammable cargoes, unless heated close to its flash point.

26. Under IBC Code 15.13, before a product requiring inhibition is shipped, the manufacturer's certificate of protection must state, among other things:

  • A. The name and amount of inhibitor added, the date added and its normally expected duration of effectiveness, and any temperature limitations
  • B. Only the price of the cargo
  • C. Only the cargo quantity loaded
  • D. The name of the ship's chief officer
Answer: A — The name and amount of inhibitor added, the date added and its normally expected duration of effectiveness, and any temperature limitations
IBC Code 15.13.3 requires a certificate from the manufacturer kept on board giving the name and amount of inhibitor, date added, expected duration of effectiveness, temperature limitations affecting it and the action to be taken if the voyage exceeds its effective lifetime, plus oxygen requirements where relevant.

27. Under the ISM Code, how often must the company carry out internal safety audits on board and ashore?

  • A. At intervals not exceeding 12 months
  • B. Every 5 years
  • C. Every 30 months
  • D. Only after an accident
Answer: A — At intervals not exceeding 12 months
ISM Code element 12.1 requires the company to carry out internal safety audits on board and ashore at intervals not exceeding twelve months to verify that safety and pollution prevention activities comply with the SMS; in exceptional circumstances this may be exceeded by not more than three months.

28. What is the role of the Designated Person Ashore under the ISM Code?

  • A. To provide a link between the company and those on board, with direct access to the highest level of management
  • B. To command the ship in emergencies
  • C. To act as the terminal's representative
  • D. To issue the ship's statutory certificates
Answer: A — To provide a link between the company and those on board, with direct access to the highest level of management
ISM Code element 4 requires the company to designate a person or persons ashore with direct access to the highest level of management, responsible for monitoring the safety and pollution prevention aspects of each ship and ensuring adequate resources and shore support are provided.

29. In the hierarchy of risk controls used in shipboard risk assessment, which control is considered most effective?

  • A. Eliminating the hazard
  • B. Issuing personal protective equipment
  • C. Posting warning signs
  • D. Training the crew to be more careful
Answer: A — Eliminating the hazard
The hierarchy runs from elimination and substitution through engineering controls and administrative controls to PPE as the last line of defence. Removing the hazard altogether, for example avoiding tank entry by remote inspection, is the most effective option.

30. In a positive tanker safety culture, what is the expected response when any crew member sees an unsafe condition during cargo operations?

  • A. Use the stop-work authority, stop the job and report it without fear of blame
  • B. Continue the work and mention it at the next monthly meeting
  • C. Report it only if an accident occurs
  • D. Ignore it if a senior officer is present
Answer: A — Use the stop-work authority, stop the job and report it without fear of blame
Stop-work authority empowers every person on board to halt an operation they believe is unsafe. A just culture supports this by encouraging open reporting without fear of punishment for honest mistakes, so that hazards are corrected before they cause harm.

31. Why does the safety management system encourage the reporting of near misses on chemical tankers?

  • A. Analysing near misses reveals hazards and system weaknesses so corrective action can be taken before an accident happens
  • B. To identify crew members for disciplinary action
  • C. Because near misses must be reported to the flag State within 24 hours
  • D. To reduce the number of drills required
Answer: A — Analysing near misses reveals hazards and system weaknesses so corrective action can be taken before an accident happens
ISM Code element 9 requires reporting and analysis of non-conformities, accidents and hazardous occurrences. Near-miss reports show where barriers failed or nearly failed, allowing the company to improve procedures and training and share lessons across the fleet.

32. Under ISM Code element 5, which authority must the company clearly establish in its safety management system?

  • A. The master's overriding authority and responsibility to make decisions on safety and pollution prevention and to request company assistance
  • B. The terminal's authority to command the ship
  • C. The charterer's authority to change the cargo plan
  • D. The chief engineer's authority over cargo operations
Answer: A — The master's overriding authority and responsibility to make decisions on safety and pollution prevention and to request company assistance
ISM Code 5.2 requires the SMS to contain a clear statement emphasising the master's authority, and the company to establish that the master has overriding authority and responsibility to make decisions on safety and pollution prevention and to request assistance as necessary.

33. What is the main purpose of a toolbox talk held before a cargo-related task such as connecting hoses or sampling a toxic cargo?

  • A. To review the task steps, hazards, controls, PPE and each person's role with the team doing the work
  • B. To record the overtime of the crew
  • C. To replace the permit-to-work system
  • D. To brief the terminal on the ship's history
Answer: A — To review the task steps, hazards, controls, PPE and each person's role with the team doing the work
A toolbox talk is a short pre-job meeting where the team confirms the method, identifies hazards from the risk assessment and SDS, checks required PPE and emergency measures, and agrees responsibilities, so everyone starts the task with the same understanding.

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