Skip to content
DG Exit Exam
Answer Key

CHEMCO exit exam questions and answers — Set 22 — Advanced Training for Chemical Tanker Cargo Operations

Set 22 of the Advanced Training for Chemical Tanker Cargo Operations (CHEMCO) exit exam bank — 33 of 663 questions, with the correct option marked and a one-line explanation for every one. Read it end to end, jump to a single set, or search it — then sit the same bank as a timed paper. The real DG Shipping exit exam is 30 marks with 15 to pass.

These are the bank's original groupings. Practising deals the whole bank out again every time you reshuffle, so a practice “Set 3” is a different 30 questions each time — the set numbers below are the source file's, and are only used here so the key stays navigable. Options are listed in their original order with fixed letters; when you practise, those move too.

Bank last rebuilt .

33 of 33 shown · Set 22

Nothing in this set matches that. Try a shorter word, or search the whole key.

Set 22 — 33 CHEMCO exit exam questions with answers

1. Under MARPOL Annex II, which is designated as a special area for noxious liquid substances?

  • A. The Antarctic area
  • B. The Mediterranean Sea
  • C. The Red Sea
  • D. The Gulf of Aden
Answer: A — The Antarctic area
Annex II regulation 13.8 designates only the Antarctic area (south of latitude 60°S) as a special area, where any discharge into the sea of noxious liquid substances or mixtures containing them is prohibited.

2. After unloading a Category X substance, the prewash residue must be discharged to a reception facility until the concentration of the substance in the effluent is at or below:

  • A. 0.1% by weight
  • B. 1% by weight
  • C. 5% by weight
  • D. 10 ppm
Answer: A — 0.1% by weight
Annex II regulation 13.6.1 requires a prewash for Category X before the ship leaves the unloading port, with the resulting residues discharged ashore until the concentration in the effluent, as shown by surveyor's analysis, is 0.1% by weight or less.

3. Under MARPOL Annex II, cargo residues may be removed from a tank by ventilation instead of washing when the substance has a vapour pressure at 20°C greater than:

  • A. 5 kPa
  • B. 0.5 kPa
  • C. 50 kPa
  • D. 101.3 kPa
Answer: A — 5 kPa
Regulation 13.3 allows residues of substances with a vapour pressure greater than 5 kPa at 20°C to be removed by ventilation following the procedures of Appendix 7 of Annex II and the P&A Manual; any water subsequently introduced is regarded as clean.

4. For how long must the Cargo Record Book be kept on board after the last entry is made?

  • A. Three years
  • B. One year
  • C. Five years
  • D. Until the next renewal survey
Answer: A — Three years
Annex II regulation 15 requires the Cargo Record Book to be kept readily available for inspection and retained on board for a period of three years after the last entry, with each operation entered and signed by the officer in charge and each page by the master.

5. Ballast introduced into a cargo tank that has been washed so that the ballast contains less than what concentration of the previous substance may be discharged without regard to discharge rate, speed and outlet location?

  • A. 1 ppm
  • B. 10 ppm
  • C. 100 ppm
  • D. 0.1%
Answer: A — 1 ppm
Under Annex II regulation 13, ballast water in a tank washed so that it contains less than 1 ppm of the substance previously carried may be discharged without regard to discharge rate, ship speed and discharge outlet location, provided the ship is at least 12 nautical miles from land in water at least 25 m deep.

6. Since the revised MARPOL Annex II entered into force on 1 January 2007, vegetable oils such as palm oil are generally:

  • A. Category Y substances that must be carried in at least ship type 2 chemical tankers
  • B. Category Z substances carried in any tanker
  • C. Oils under MARPOL Annex I
  • D. Other Substances with no carriage requirements
Answer: A — Category Y substances that must be carried in at least ship type 2 chemical tankers
The 2007 revision reassessed vegetable oils as Category Y, with chapter 17 of the IBC Code requiring ship type 2 for most of them. Limited exemptions for certain ship type 3 or non-chemical tankers were allowed only under strict conditions set by the Administration.

7. A ship that is not self-propelled may discharge permitted Category Y or Z residue mixtures only if it is proceeding at a speed of at least:

  • A. 4 knots
  • B. 7 knots
  • C. 2 knots
  • D. 12 knots
Answer: A — 4 knots
Regulation 13.2.2 requires self-propelled ships to be en route at not less than 7 knots and ships that are not self-propelled at not less than 4 knots, discharging below the waterline through underwater outlets at no more than the design rate.

8. In which circumstance may a mandatory prewash after unloading a Category X, or a high-viscosity or solidifying Category Y substance, be exempted by the Administration's surveyor?

  • A. When the tank is to be reloaded with the same or a compatible substance and will not be washed or ballasted before loading
  • B. When the ship is in a hurry to sail
  • C. When the next port is within the same country
  • D. When the residue quantity is more than 75 litres
Answer: A — When the tank is to be reloaded with the same or a compatible substance and will not be washed or ballasted before loading
Regulation 13.4 allows exemption from prewash if the unloaded tank is to be reloaded with the same or another compatible substance, or if residues will be removed by ventilation, or if the ship will discharge to a reception facility elsewhere; the surveyor endorses the Cargo Record Book.

9. Amendments to MARPOL Annex II in force from 1 January 2021 require a prewash for certain persistent floating products when unloading in ports of which areas?

  • A. North West European waters, the Baltic Sea, Western European waters and the Norwegian Sea
  • B. The Red Sea and the Gulf of Aden
  • C. The Caribbean Sea and the Gulf of Mexico
  • D. The Arabian Sea and the Bay of Bengal
Answer: A — North West European waters, the Baltic Sea, Western European waters and the Norwegian Sea
Resolution MEPC.315(74) introduced a mandatory prewash and discharge ashore of residues of persistent floating products, high-viscosity or solidifying substances that float and persist on the sea surface, after unloading in ports within these four European sea areas.

10. Under MARPOL Annex II, a Category Z substance is one which, if discharged into the sea from tank cleaning or deballasting operations, is deemed to present:

  • A. A minor hazard to marine resources or human health, justifying less stringent restrictions
  • B. A major hazard justifying a total prohibition of discharge
  • C. No harm at all, so it falls outside all categories
  • D. A hazard only to air quality
Answer: A — A minor hazard to marine resources or human health, justifying less stringent restrictions
Regulation 6 defines Category X as a major hazard with discharge prohibited, Category Y as a hazard justifying limits on quality and quantity, and Category Z as a minor hazard with less stringent restrictions. Other Substances are considered harmless and are not subject to Annex II.

11. A shipper wishes to ship a liquid product that is not yet categorised under MARPOL Annex II or listed in the IBC Code. What is required before it can be carried?

  • A. A provisional assessment agreed between the governments of the producing or shipping country, the flag State and the receiving country (tripartite agreement)
  • B. Only the master's consent
  • C. A certificate from the charterer
  • D. Nothing, as uncategorised products are treated as Other Substances
Answer: A — A provisional assessment agreed between the governments of the producing or shipping country, the flag State and the receiving country (tripartite agreement)
Annex II regulation 6.3 requires unassessed products to be provisionally categorised by the governments concerned under a tripartite agreement, based on the guidelines, before carriage. IMO publishes these agreements annually in the MEPC.2/Circular lists.

12. Which statement about the Procedures and Arrangements Manual is correct?

  • A. It follows the standard format of Appendix 4 of Annex II, is approved by the Administration and identifies the ship's arrangements and operational procedures for cargo handling, tank cleaning, slops and ballasting
  • B. It is prepared by the master and needs no approval
  • C. It is required only on ships trading in special areas
  • D. It replaces the Cargo Record Book
Answer: A — It follows the standard format of Appendix 4 of Annex II, is approved by the Administration and identifies the ship's arrangements and operational procedures for cargo handling, tank cleaning, slops and ballasting
Regulation 14 requires every ship certified to carry noxious liquid substances in bulk to have an approved P&A Manual in the standard format. It describes the equipment and procedures needed to comply with Annex II, including stripping, prewash, ventilation and discharge of residues.

13. Which of these operations must be entered in the Cargo Record Book of a chemical tanker?

  • A. Ballasting of cargo tanks
  • B. Bunkering of fuel oil
  • C. Discharge of sewage
  • D. Disposal of food waste
Answer: A — Ballasting of cargo tanks
The Annex II Cargo Record Book (Appendix 2) covers loading, internal transfer and unloading of cargo, mandatory prewash, tank cleaning, discharge of tank washings, ballasting of cargo tanks and discharge of ballast from them, accidental discharges and surveyor control. Fuel, sewage and garbage are recorded under other annexes.

14. Where a mandatory prewash has been carried out in the unloading port, who verifies it and makes the endorsement in the Cargo Record Book?

  • A. A surveyor appointed or authorised by the Government of the receiving Party
  • B. The terminal loading master
  • C. The ship's chief engineer
  • D. The cargo owner's representative
Answer: A — A surveyor appointed or authorised by the Government of the receiving Party
Annex II regulation 16 makes the receiving Party's appointed or authorised surveyors responsible for verifying that prewash and discharge to reception facilities have been carried out as required, and for endorsing the relevant Cargo Record Book entries or granting exemptions.

15. What is the maximum period of validity of the International Certificate of Fitness for the Carriage of Dangerous Chemicals in Bulk?

  • A. Five years
  • B. Two years
  • C. Three years
  • D. One year
Answer: A — Five years
Under IBC Code 1.5, the Certificate of Fitness is issued for a period specified by the Administration not exceeding five years, subject to annual and intermediate surveys being endorsed on the certificate.

16. Which chemical tankers are required to comply with the IBC Code rather than the older BCH Code?

  • A. Ships constructed on or after 1 July 1986
  • B. Ships constructed before 1 July 1986
  • C. All ships regardless of age, from 1 January 2021 only
  • D. Only ships of 20,000 dwt and above
Answer: A — Ships constructed on or after 1 July 1986
The IBC Code is mandatory under SOLAS chapter VII and MARPOL Annex II for chemical tankers constructed on or after 1 July 1986. Ships built before that date are covered by the BCH Code.

17. In IBC Code chapter 17, what does the letter 'A' in column l (fire protection) indicate?

  • A. Alcohol-resistant foam or multi-purpose foam
  • B. Regular foam only
  • C. Water spray
  • D. Dry chemical powder only
Answer: A — Alcohol-resistant foam or multi-purpose foam
Column l shows the fire-extinguishing media: A for alcohol-resistant or multi-purpose foam, B for regular foam (including all foams not alcohol-resistant), C for water spray and D for dry chemical. Products that destroy ordinary foam, such as alcohols and ketones, need type A.

18. In IBC Code chapter 17, the entry 'C' in column j indicates that the product requires:

  • A. Closed gauging
  • B. Controlled venting
  • C. Category C pollution
  • D. Cofferdam segregation
Answer: A — Closed gauging
Column j gives the gauging requirement: O for open, R for restricted and C for closed gauging. Closed gauging, such as radar or float systems, does not allow any cargo vapour to escape and is required for toxic and certain other hazardous products.

19. In IBC Code chapter 17, the term 'Pad' in column h (tank environmental control) means:

  • A. The ullage space is filled and maintained with a liquid, gas or vapour that separates the cargo from the air
  • B. The tank must be dried to a low dew point
  • C. The tank must be ventilated with fresh air
  • D. The cargo is carried in a padded deck tank
Answer: A — The ullage space is filled and maintained with a liquid, gas or vapour that separates the cargo from the air
Column h may show Inert, Pad, Dry or Vent. Padding means filling the ullage space, and associated piping where required, with a liquid, gas or vapour that separates the cargo from the air and maintains that condition, often using nitrogen.

20. Which chapter of the IBC Code lists products to which the Code does not apply because their safety and pollution hazards are low?

  • A. Chapter 18
  • B. Chapter 17
  • C. Chapter 19
  • D. Chapter 15
Answer: A — Chapter 18
Chapter 17 is the summary of minimum requirements, chapter 18 lists products to which the Code does not apply, though some are still subject to MARPOL Annex II as Category Z or OS, and chapter 19 is the index of product names with their synonyms.

21. For ships carrying products for which column n of chapter 17 shows 'Yes', IBC Code 14.3 requires emergency escape respiratory and eye protection for every person on board. What minimum duration must it provide?

  • A. At least 15 minutes
  • B. At least 5 minutes
  • C. At least 30 minutes
  • D. At least 60 minutes
Answer: A — At least 15 minutes
IBC Code 14.3.1 requires respiratory and eye protection for emergency escape for every person on board, with self-contained sets normally giving at least 15 minutes of service; filter types are accepted only when one filter suits all cargoes listed on the Certificate of Fitness.

22. According to IBC Code chapter 14, where must decontamination showers and an eyewash be provided on chemical tankers carrying products that require them?

  • A. On deck in suitably marked convenient locations, operable in all ambient conditions
  • B. Only in the ship's hospital
  • C. Only in the engine room
  • D. Only inside the accommodation entrance
Answer: A — On deck in suitably marked convenient locations, operable in all ambient conditions
IBC Code 14.3.3 requires suitably marked decontamination showers and an eyewash on deck in convenient locations, depending on the size and layout of the ship, and they must be operable in all ambient conditions so contaminated persons can be washed immediately.

23. What does the attachment to the International Certificate of Fitness of a chemical tanker contain?

  • A. The list of products the ship is permitted to carry with their conditions of carriage and tanks
  • B. The crew list and their certificates
  • C. The cargo manifest of the current voyage
  • D. The ship's radio licence
Answer: A — The list of products the ship is permitted to carry with their conditions of carriage and tanks
The Certificate of Fitness is supplemented by a list of products the ship is certified to carry, with any conditions such as allowed tanks, ship type and special requirements. Only products named in that list may be loaded.

24. Which chapter of the IBC Code contains the criteria for assigning carriage requirements to products, used when evaluating new products?

  • A. Chapter 21
  • B. Chapter 11
  • C. Chapter 16
  • D. Chapter 4
Answer: A — Chapter 21
IBC Code Chapter 21 sets out the criteria for assigning carriage requirements for products subject to the Code.

25. In IBC Code chapter 17, what does 'Yes' in column i''' indicate?

  • A. The product has a flash point exceeding 60°C (closed cup test)
  • B. The product requires electrical equipment of group IIC
  • C. The product is toxic
  • D. The product must be inhibited
Answer: A — The product has a flash point exceeding 60°C (closed cup test)
Column i gives electrical equipment requirements: i' temperature class, i'' apparatus group, and i''' whether the flash point exceeds 60°C closed cup. Where it is 'Yes', the product does not require the electrical equipment provisions for flammable cargoes, unless heated close to its flash point.

26. Under IBC Code 15.13, before a product requiring inhibition is shipped, the manufacturer's certificate of protection must state, among other things:

  • A. The name and amount of inhibitor added, the date added and its normally expected duration of effectiveness, and any temperature limitations
  • B. Only the price of the cargo
  • C. Only the cargo quantity loaded
  • D. The name of the ship's chief officer
Answer: A — The name and amount of inhibitor added, the date added and its normally expected duration of effectiveness, and any temperature limitations
IBC Code 15.13.3 requires a certificate from the manufacturer kept on board giving the name and amount of inhibitor, date added, expected duration of effectiveness, temperature limitations affecting it and the action to be taken if the voyage exceeds its effective lifetime, plus oxygen requirements where relevant.

27. Under the ISM Code, how often must the company carry out internal safety audits on board and ashore?

  • A. At intervals not exceeding 12 months
  • B. Every 5 years
  • C. Every 30 months
  • D. Only after an accident
Answer: A — At intervals not exceeding 12 months
ISM Code element 12.1 requires the company to carry out internal safety audits on board and ashore at intervals not exceeding twelve months to verify that safety and pollution prevention activities comply with the SMS; in exceptional circumstances this may be exceeded by not more than three months.

28. What is the role of the Designated Person Ashore under the ISM Code?

  • A. To provide a link between the company and those on board, with direct access to the highest level of management
  • B. To command the ship in emergencies
  • C. To act as the terminal's representative
  • D. To issue the ship's statutory certificates
Answer: A — To provide a link between the company and those on board, with direct access to the highest level of management
ISM Code element 4 requires the company to designate a person or persons ashore with direct access to the highest level of management, responsible for monitoring the safety and pollution prevention aspects of each ship and ensuring adequate resources and shore support are provided.

29. In the hierarchy of risk controls used in shipboard risk assessment, which control is considered most effective?

  • A. Eliminating the hazard
  • B. Issuing personal protective equipment
  • C. Posting warning signs
  • D. Training the crew to be more careful
Answer: A — Eliminating the hazard
The hierarchy runs from elimination and substitution through engineering controls and administrative controls to PPE as the last line of defence. Removing the hazard altogether, for example avoiding tank entry by remote inspection, is the most effective option.

30. In a positive tanker safety culture, what is the expected response when any crew member sees an unsafe condition during cargo operations?

  • A. Use the stop-work authority, stop the job and report it without fear of blame
  • B. Continue the work and mention it at the next monthly meeting
  • C. Report it only if an accident occurs
  • D. Ignore it if a senior officer is present
Answer: A — Use the stop-work authority, stop the job and report it without fear of blame
Stop-work authority empowers every person on board to halt an operation they believe is unsafe. A just culture supports this by encouraging open reporting without fear of punishment for honest mistakes, so that hazards are corrected before they cause harm.

31. Why does the safety management system encourage the reporting of near misses on chemical tankers?

  • A. Analysing near misses reveals hazards and system weaknesses so corrective action can be taken before an accident happens
  • B. To identify crew members for disciplinary action
  • C. Because near misses must be reported to the flag State within 24 hours
  • D. To reduce the number of drills required
Answer: A — Analysing near misses reveals hazards and system weaknesses so corrective action can be taken before an accident happens
ISM Code element 9 requires reporting and analysis of non-conformities, accidents and hazardous occurrences. Near-miss reports show where barriers failed or nearly failed, allowing the company to improve procedures and training and share lessons across the fleet.

32. Under ISM Code element 5, which authority must the company clearly establish in its safety management system?

  • A. The master's overriding authority and responsibility to make decisions on safety and pollution prevention and to request company assistance
  • B. The terminal's authority to command the ship
  • C. The charterer's authority to change the cargo plan
  • D. The chief engineer's authority over cargo operations
Answer: A — The master's overriding authority and responsibility to make decisions on safety and pollution prevention and to request company assistance
ISM Code 5.2 requires the SMS to contain a clear statement emphasising the master's authority, and the company to establish that the master has overriding authority and responsibility to make decisions on safety and pollution prevention and to request assistance as necessary.

33. What is the main purpose of a toolbox talk held before a cargo-related task such as connecting hoses or sampling a toxic cargo?

  • A. To review the task steps, hazards, controls, PPE and each person's role with the team doing the work
  • B. To record the overtime of the crew
  • C. To replace the permit-to-work system
  • D. To brief the terminal on the ship's history
Answer: A — To review the task steps, hazards, controls, PPE and each person's role with the team doing the work
A toolbox talk is a short pre-job meeting where the team confirms the method, identifies hazards from the risk assessment and SDS, checks required PPE and emergency measures, and agrees responsibilities, so everyone starts the task with the same understanding.

Printing this? Use your browser's Print (Ctrl/⌘ + P) — the buttons, the search box and the site chrome drop out and the questions run on as plain text, so a set fits a few pages. Filter to one set first if you only want that set on paper.

Send this CHEMCO answer key to your batch

Send on WhatsApp

More free tools for seafarers